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Vol. 26 No. 5 (2014): Vol 26 Issue 5

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Low-Power Upconversion in Anthracene Derivatives Doped with Pd(II) Tetraphenylporphyrin

https://doi.org/10.14233/ajchem.2014.17244
Bin Sun
Jiangsu Key Laboratory for Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, P.R. China
Chang-Qing Ye
Jiangsu Key Laboratory for Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, P.R. China
Zuo-Qin Liang
Jiangsu Key Laboratory for Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, P.R. China
Ping Ding
Jiangsu Key Laboratory for Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, P.R. China
Xiao-Mei Wang
Jiangsu Key Laboratory for Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, P.R. China
Zhi-Gang Chen
Jiangsu Key Laboratory for Environmental Functional Materials, School of Chemistry, Biology and Material Engineering, Suzhou University of Science and Technology, Suzhou 215009, P.R. China
Xu-Tang Tao
State Key Laboratory of Crystal Materials, Shandong University, Jinan 250100, P.R. China
Qin-Hua Wang
Institute of Modern Optical Technologies, Key Lab of Advanced Optical Manufacturing Technologies of Jiangsu Province and Key Lab of Modern Optical Technologies of Education Ministry of China, Soochow University, Suzhou 215006, Jiangsu Province, P.R. China

Corresponding Author(s) : Zuo-Qin Liang

wangxiaomei@mail.usts.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 5 (2014): Vol 26 Issue 5

Abstract

Selective low energy excitation of Pd(II) tetraphenylporphyrin in the presence of anthracene and anthracene-2-carboxylic acid, respectively, can yield easily visualized upconversion fluorescence at low excitation power. Anthracene-2-carboxylic acid shows about a two-fold increase in the upconversion quantum yield, relative to anthracene under the identical conditions. The higher fluorescence quantum of anthracene-2-carboxylic acid plays a crucial role in its effective upconversion fluorescence.

Keywords

Low-power Upconversion Sensitizer Emitter Quantum efficiency Pd(II) tetraphenylporphyrin
Sun, B., Ye, C.-Q., Liang, Z.-Q., Ding, P., Wang, X.-M., Chen, Z.-G., … Wang, Q.-H. (2014). Low-Power Upconversion in Anthracene Derivatives Doped with Pd(II) Tetraphenylporphyrin. Asian Journal of Chemistry, 26(5), 1413–1416. https://doi.org/10.14233/ajchem.2014.17244
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