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Synthesis of 1-Bromooctane Catalyzed by Solid Super Acid SO42–/ZrO4-ZnO
Corresponding Author(s) : Guoqin Hu
Asian Journal of Chemistry,
Vol. 26 No. 4 (2014): Vol 26 Issue 4
Abstract
The solid super acid catalyst SO42-/ZrO2-ZnO was prepared by impregnation and characterized by infrared spectroscopy, X-ray diffraction, different scanning calorimetric and thermogravimetric analysis. Their performances were evaluated by the synthesis of 1-bromooctane. Under the condition of n-octanol/hydrobromic acid molar ratio of 1:3, a catalyst amount of 8 wt. %, reaction time of 7 h, temperature of 130 °C, produce 1-bromooctane (yield 70.22 %).
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- S.G. Zhang, Fine Organic Chemical Technical Manual, Science Press, Beijing, p. 327 (1991).
- V. F. Loktev, I. Yu. Morozova, A.K. Tashmukhamedova and V.A. Likholobov, Bull. Acad. Sci, USSR, Div. Chem. Sci., 39, 1128 (1990); doi:10.1007/BF00962368.
- H. Ohmiya, K. Wakabayashi, H. Yorimitsu and K. Oshima, Tetrahedron, 62, 2207 (2006); doi: 10.1016/j.tet.2005.12.013.
- H. Hrudkov and V. Janout, Polym. Bull., 26, 31 (1991); doi:10.1007/BF00299345.
- G. Cainelli, M. Contento, F. Manescalchi and L. Plessi, Synthesis, 306 (1983); doi:10.1055/s-1983-30314.
- Z.G. Song, M. Wang, H. Jiang and H. Gong, Fine Chemical Intermed., 38, 37 (2008).
- O. Kamm and C.S. Marvel, J. Am. Chem. Soc., 42, (1920); doi:10.1021/ja01447a013.
- Y.N. Wu and S.J. Liao, Front. Chem. Eng. China, 3, 330 (2009); doi:10.1007/s11705-009-0208-3.
- M.B. Reddy and P.M. Sreekanth, Tetrahedron Lett., 44, 4447 (2003); doi:10.1016/S0040-4039(03)01034-7.
- B. Ren, M.Q. Fan, J. Wang and X.Y. Jing, Solid State Sci., 13, 1594 (2011); doi:10.1016/j.solidstatesciences.2011.06.006.
- B.S. Fu, L.J. Gao, L. Niu, R.P. Wei and G.M. Xiao, Energy Fuels, 23, 569 (2009); doi:10.1021/ef800751z.
- J.R. Sohn, J.G. Kim, T.D. Kwon and E.H. Park, Langmuir, 18, 1670 (2002); doi:10.1021/la011304h.
- J. Zhao, Y.H. Yue, W.M. Hua, H. He and Z. Gao, Appl. Catal. A, 336, 133 (2008); doi:10.1016/j.apcata.2007.08.014.
- H. Yang, R. Lu, J.Z. Zhao, X.W. Yang, L.C. Shen and Z.C. Wang, Mater. Chem. Phys., 80, 68 (2003); doi:10.1016/S0254-0584(02)00162-1.
- R. Srinivasan, D. Taulbee and B.H. Davis, Catal. Lett., 9, 1 (1991); doi:10.1007/BF00769074.
References
S.G. Zhang, Fine Organic Chemical Technical Manual, Science Press, Beijing, p. 327 (1991).
V. F. Loktev, I. Yu. Morozova, A.K. Tashmukhamedova and V.A. Likholobov, Bull. Acad. Sci, USSR, Div. Chem. Sci., 39, 1128 (1990); doi:10.1007/BF00962368.
H. Ohmiya, K. Wakabayashi, H. Yorimitsu and K. Oshima, Tetrahedron, 62, 2207 (2006); doi: 10.1016/j.tet.2005.12.013.
H. Hrudkov and V. Janout, Polym. Bull., 26, 31 (1991); doi:10.1007/BF00299345.
G. Cainelli, M. Contento, F. Manescalchi and L. Plessi, Synthesis, 306 (1983); doi:10.1055/s-1983-30314.
Z.G. Song, M. Wang, H. Jiang and H. Gong, Fine Chemical Intermed., 38, 37 (2008).
O. Kamm and C.S. Marvel, J. Am. Chem. Soc., 42, (1920); doi:10.1021/ja01447a013.
Y.N. Wu and S.J. Liao, Front. Chem. Eng. China, 3, 330 (2009); doi:10.1007/s11705-009-0208-3.
M.B. Reddy and P.M. Sreekanth, Tetrahedron Lett., 44, 4447 (2003); doi:10.1016/S0040-4039(03)01034-7.
B. Ren, M.Q. Fan, J. Wang and X.Y. Jing, Solid State Sci., 13, 1594 (2011); doi:10.1016/j.solidstatesciences.2011.06.006.
B.S. Fu, L.J. Gao, L. Niu, R.P. Wei and G.M. Xiao, Energy Fuels, 23, 569 (2009); doi:10.1021/ef800751z.
J.R. Sohn, J.G. Kim, T.D. Kwon and E.H. Park, Langmuir, 18, 1670 (2002); doi:10.1021/la011304h.
J. Zhao, Y.H. Yue, W.M. Hua, H. He and Z. Gao, Appl. Catal. A, 336, 133 (2008); doi:10.1016/j.apcata.2007.08.014.
H. Yang, R. Lu, J.Z. Zhao, X.W. Yang, L.C. Shen and Z.C. Wang, Mater. Chem. Phys., 80, 68 (2003); doi:10.1016/S0254-0584(02)00162-1.
R. Srinivasan, D. Taulbee and B.H. Davis, Catal. Lett., 9, 1 (1991); doi:10.1007/BF00769074.