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Vol. 26 No. 4 (2014): Vol 26 Issue 4

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Synthesis and Crystal Structure of Supramolecular Trinuclear Nickel(II) Complex with 5-Methoxy-4'-chloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol

https://doi.org/10.14233/ajchem.2014.16162
Yu-Jie Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xin-Ying Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Gang Li
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Meng-Meng Zhao
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xiu-Yan Dong
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Gang Li

li_gang78@126.com

Asian Journal of Chemistry, Vol. 26 No. 4 (2014): Vol 26 Issue 4

Abstract

A new trinuclear Ni(II) complex has been synthesized through the reaction of an asymmetric Salamo-type ligand of 5-methoxy-4'-chloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H2L) with Ni(II) acetate tetrahydrate in n-butanol/acetonitrile solution and characterized by X-ray diffraction methods. The X-ray crystallography of the Ni(II) complex shows that the unit cell contains two crystallographically independent but chemically identical trinuclear Ni(II) complex (molecules A and B) and each molecule comprises three Ni(II) atoms, two deprotonated L2- units, two acetate anions and two coordinated n-butanol molecules. In the crystal, the complex molecules are linked to form an infinite sandwich supramolecular structure through intermolecular O-H···O and C-H···O hydrogen bond interactions.

Keywords

Asymmetric Salamo-type ligand Ni(II) complex Synthesis Crystal structure
Zhang, Y.-J., Zhang, X.-Y., Li, G., Zhao, M.-M., & Dong, X.-Y. (2014). Synthesis and Crystal Structure of Supramolecular Trinuclear Nickel(II) Complex with 5-Methoxy-4’-chloro-2,2’-[ethylenedioxybis(nitrilomethylidyne)]diphenol. Asian Journal of Chemistry, 26(4), 1174–1178. https://doi.org/10.14233/ajchem.2014.16162
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