Removal of Fe3+ in Citric Acid with Macroporous Amidoxime Chelating Resin

J.W. Zhang; L.L. Fan

doi:10.14233/ajchem.2014.16020

Issue

Vol. 26 No. 4 (2014): Vol 26 Issue 4

Issue Published : February 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Removal of Fe3+ in Citric Acid with Macroporous Amidoxime Chelating Resin

https://doi.org/10.14233/ajchem.2014.16020

J.W. Zhang

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, P.R. China

L.L. Fan

The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, P.R. China

Corresponding Author(s) : J.W. Zhang

zjwseu@126.com

Asian Journal of Chemistry, Vol. 26 No. 4 (2014): Vol 26 Issue 4
Article Published : February 15, 2014

Abstract

Macroporous amidoxime chelating resin was prepared in order to remove Fe³⁺ from citric acid. The key influence factors, kinetics, thermodynamics, mechanism of adsorption were analyzed with macroporous amidoxime chelating resin which was prepared by chemical modification of acrylonitrile polymer. Results indicated that adsorption amount of Fe³⁺ significantly decreased with the increase of citric acid concentration and the saturated adsorption time prolonged with the increase of concentration of citric acid. The adsorption equilibration of macroporous amidoxime chelating resin achieved after 2.5 h in solution without citric acid and the adsorption amount could reach to 14.01 mg/g. Moreover, the absorption isotherm followed the Freundlich model well. DH and DS were more than zero in the range of 303-323 K, whereas DG was less than zero and the adsorption of Fe³⁺ by macroporous amidoxime chelating resin was a spontaneous and decalescence adsorption process. This research will be helpful for providing new methods to deal with organic acid solution containing Fe³⁺.

Keywords

Fe3 Adsorption Macroporous amidoxime chelating resin Citric acid

Zhang, J., & Fan, L. (2014). Removal of Fe3+ in Citric Acid with Macroporous Amidoxime Chelating Resin. Asian Journal of Chemistry, 26(4), 1122–1126. https://doi.org/10.14233/ajchem.2014.16020

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References

B. Duarte, M. Delgado and I. Cacador, Chemosphere, 69, 836 (2007); doi:10.1016/j.chemosphere.2007.05.007.
K.C. Poh, H.S. Lim, H. Pan, J. Lin and J.Y. Lee, J. Power Sources, 176, 70 (2008); doi:10.1016/j.jpowsour.2007.10.049.
Y.M. Jiang, L.T. Pen and J.R. Li, J. Food Eng., 63, 325 (2004); doi:10.1016/j.jfoodeng.2003.08.004.
R.A. Angumeenal and D. Venkappayya, LWT-Food Sci. Technol., 50, 367 (2013); doi: 10.1016/j.lwt.2012.05.016.
X.Y. Chen, Q. Lin, M.Y. Luo, Y.F. He, S.J. Zhen, Y.L. Yu, G.M. Tian and M.H. Wong, Chemosphere, 50, 807 (2003); doi:10.1016/S0045-6535(02)00223-0.
M.Y. Lu, I.S. Maddox and J.D. Brooks, Bioresour. Technol., 54, 235 (1995); doi:10.1016/0960-8524(95)00131-X.
I.-U. Haq, S. Ali and J. Iqbal, Process Biochem., 38, 921 (2003); doi:10.1016/S0032-9592(02)00201-7.
S.Y. Mostafa and A.S. Alamri, Saudi J. Biol. Sci., 19, 241 (2012); doi:10.1016/j.sjbs.2012.01.004.
D. Kumar, K.V. Jain, G. Shanker and A. Srivastava, Process Biochem., 38, 1731 (2003); doi:10.1016/S0032-9592(02)00252-2.
S.M. Lee and J.M. Nicol, Hydrometallurgy, 86, 6 (2007); doi:10.1016/j.hydromet.2006.10.002.
Z. Liu and X. Wang, Chinese J. React. Eng., 7, 87 (1998).
B.R. Liu, Chelating Flotation Agent, Metallurgical Industry Press, Beijing, p. 80 (1982).
A.M. Rahman, H. Hasegawa, K. Kadohashi, T. Maki and K. Ueda, Chemosphere, 77, 207 (2009); doi:10.1016/j.chemosphere.2009.07.032.
H.S. Choi, S.M. Choi, T.Y. Park, K. Lee and H. Kang, Radiat. Phys. Chem., 67, 387 (2003); doi:10.1016/S0969-806X(03)00072-0.
M. Nogami, Y.S. Kim, N. Asanuma and Y. Ikeda, J. Alloys Comp., 374, 269 (2004); doi:10.1016/j.jallcom.2003.11.099.
G. Zong, H. Chen, R. Qu, C. Wang and N. Ji, J. Hazard. Mater., 186, 614 (2011); doi:10.1016/j.jhazmat.2010.11.043.
X. Liu, H. Chen, C. Wang, R. Qu, C. Ji, C. Sun and Q. Xu, Polym. Adv. Technol., 22, 2032 (2011); doi:10.1002/pat.1714.
X. Liu, H. Chen, C. Wang, R. Qu, C. Ji, C. Sun and Y. Zhang, J. Hazard. Mater., 175, 1014 (2010); doi:10.1016/j.jhazmat.2009.10.111.
L. Fan, J. Zhang and Q. Peng, Appl. Chem. Ind., 41, 1263 (2012).
S.Y. Ho and G. Mckay, Process Biochem., 38, 1047 (2003); doi:10.1016/S0032-9592(02)00239-X.
S.A. Özcan, B. Erdem and A. Özcan, Colloids Surf. A, 266, 73 (2005); doi: 10.1016/j.colsurfa.2005.06.001.
V.B.H. Dang, H.D. Doan, T. Dang-Vu and A. Lohi, Bioresour. Technol., 100, 211 (2009); doi:10.1016/j.biortech.2008.05.031.
J. Romero-Gonzalez, J.R. Peralta-Videa, E. Rodrıguez, S.L. Ramirez and J.L. Gardea-Torresdey, J. Chem. Thermodyn., 37, 343 (2005); doi:10.1016/j.jct.2004.09.013.

References

B. Duarte, M. Delgado and I. Cacador, Chemosphere, 69, 836 (2007); doi:10.1016/j.chemosphere.2007.05.007.

K.C. Poh, H.S. Lim, H. Pan, J. Lin and J.Y. Lee, J. Power Sources, 176, 70 (2008); doi:10.1016/j.jpowsour.2007.10.049.

Y.M. Jiang, L.T. Pen and J.R. Li, J. Food Eng., 63, 325 (2004); doi:10.1016/j.jfoodeng.2003.08.004.

R.A. Angumeenal and D. Venkappayya, LWT-Food Sci. Technol., 50, 367 (2013); doi: 10.1016/j.lwt.2012.05.016.

X.Y. Chen, Q. Lin, M.Y. Luo, Y.F. He, S.J. Zhen, Y.L. Yu, G.M. Tian and M.H. Wong, Chemosphere, 50, 807 (2003); doi:10.1016/S0045-6535(02)00223-0.

M.Y. Lu, I.S. Maddox and J.D. Brooks, Bioresour. Technol., 54, 235 (1995); doi:10.1016/0960-8524(95)00131-X.

I.-U. Haq, S. Ali and J. Iqbal, Process Biochem., 38, 921 (2003); doi:10.1016/S0032-9592(02)00201-7.

S.Y. Mostafa and A.S. Alamri, Saudi J. Biol. Sci., 19, 241 (2012); doi:10.1016/j.sjbs.2012.01.004.

D. Kumar, K.V. Jain, G. Shanker and A. Srivastava, Process Biochem., 38, 1731 (2003); doi:10.1016/S0032-9592(02)00252-2.

S.M. Lee and J.M. Nicol, Hydrometallurgy, 86, 6 (2007); doi:10.1016/j.hydromet.2006.10.002.

Z. Liu and X. Wang, Chinese J. React. Eng., 7, 87 (1998).

B.R. Liu, Chelating Flotation Agent, Metallurgical Industry Press, Beijing, p. 80 (1982).

A.M. Rahman, H. Hasegawa, K. Kadohashi, T. Maki and K. Ueda, Chemosphere, 77, 207 (2009); doi:10.1016/j.chemosphere.2009.07.032.

H.S. Choi, S.M. Choi, T.Y. Park, K. Lee and H. Kang, Radiat. Phys. Chem., 67, 387 (2003); doi:10.1016/S0969-806X(03)00072-0.

M. Nogami, Y.S. Kim, N. Asanuma and Y. Ikeda, J. Alloys Comp., 374, 269 (2004); doi:10.1016/j.jallcom.2003.11.099.

G. Zong, H. Chen, R. Qu, C. Wang and N. Ji, J. Hazard. Mater., 186, 614 (2011); doi:10.1016/j.jhazmat.2010.11.043.

X. Liu, H. Chen, C. Wang, R. Qu, C. Ji, C. Sun and Q. Xu, Polym. Adv. Technol., 22, 2032 (2011); doi:10.1002/pat.1714.

X. Liu, H. Chen, C. Wang, R. Qu, C. Ji, C. Sun and Y. Zhang, J. Hazard. Mater., 175, 1014 (2010); doi:10.1016/j.jhazmat.2009.10.111.

L. Fan, J. Zhang and Q. Peng, Appl. Chem. Ind., 41, 1263 (2012).

S.Y. Ho and G. Mckay, Process Biochem., 38, 1047 (2003); doi:10.1016/S0032-9592(02)00239-X.

S.A. Özcan, B. Erdem and A. Özcan, Colloids Surf. A, 266, 73 (2005); doi: 10.1016/j.colsurfa.2005.06.001.

V.B.H. Dang, H.D. Doan, T. Dang-Vu and A. Lohi, Bioresour. Technol., 100, 211 (2009); doi:10.1016/j.biortech.2008.05.031.

J. Romero-Gonzalez, J.R. Peralta-Videa, E. Rodrıguez, S.L. Ramirez and J.L. Gardea-Torresdey, J. Chem. Thermodyn., 37, 343 (2005); doi:10.1016/j.jct.2004.09.013.

Issue

Vol. 26 No. 4 (2014): Vol 26 Issue 4

Removal of Fe3+ in Citric Acid with Macroporous Amidoxime Chelating Resin

Corresponding Author(s) : J.W. Zhang

Abstract

Keywords

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