Copyright (c) 2014 AJC
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Innovative Electrochemistry Technique for Leaching Cobalt from Spent Lithium Ion Batteries
Corresponding Author(s) : Guisheng Zeng
Asian Journal of Chemistry,
Vol. 26 No. 4 (2014): Vol 26 Issue 4
Abstract
This work intends to investigate the possibilities of cobalt leaching from spent lithium ion batteries by electrochemistry technique. A new method was put forward and a self-designed leaching apparatus was made. The series experiments demonstrate that the ferrous ion can improve cobalt leaching from spent lithium ion batteries and the circle of Fe3+/Fe2+ is possible. Higher voltage and appropriate amount of ferric sulfate can get better cobalt leached percentage.
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- J.G. Kang, J. Sohn, H. Chang, G. Senanayake and S.M. Shin, Adv. Powder Technol., 21, 175 (2010); doi:10.1016/j.apt.2009.10.015.
- H. Aral and A. Vecchio-Sadus, Ecotox. Environ. Saf., 70, 349 (2008); doi: 10.1016/j.ecoenv.2008.02.026.
- J.F. Paulino, N.G. Busnardo and J.C. Afonso, J. Hazard. Mater., 150, 843 (2008); doi:10.1016/j.jhazmat.2007.10.048.
- L. Li, J. Ge, F. Wu, R. Chen, S. Chen and B. Wu, J. Hazard. Mater., 176, 288 (2010); doi:10.1016/j.jhazmat.2009.11.026.
- L. Chen, X.C. Tang, Y. Zhang, L. Li, Z. Zeng and Y. Zhang, Hydrometallurgy, 108, 80 (2011); doi:10.1016/j.hydromet.2011.02.010.
- S. Castillo, F. Ansart and C. Laberty-robert, J. Power Sources, 112, 247 (2002); doi:10.1016/S0378-7753(02)00361-0.
- J.Q. Xu, H.R. Thomas, R.W. Francis, K.R. Lum, J. Wang and B. Liang, J. Power Sources, 177, 512 (2008); doi:10.1016/j.jpowsour.2007.11.074.
- D. Mishra, D.-J. Kim, D.E. Ralph, J.-G. Ahn and Y.-H. Rhee, Waste Manag., 28, 333 (2008); doi:10.1016/j.wasman.2007.01.010.
- B. Xin, D. Zhang, X. Zhang, Y. Xia, F. Wu, S. Chen and L. Li, Bioresour. Technol., 100, 6163 (2009); doi:10.1016/j.biortech.2009.06.086.
- A. Ballester, F. González, M.L. Blázquez, C. Gómez and J.L. Mier, Hydrometallurgy, 29, 145 (1992); doi:10.1016/0304-386X(92)90010-W.
- J. Mier, A. Ballester, M. Blazquez, F. González and J.A. Muñoz, Miner. Eng., 8, 949 (1995); doi:10.1016/0892-6875(95)00059-Y.
- M.N. Mahmood and A.K. Turner, Hydrometallury, 14, 317 (1985); doi: 10.1016/0304-386X(85)90042-8.
- L. Zhao, D. Yang and N. Zhu, J. Hazard. Mater., 160, 648 (2008); doi: 10.1016/j.jhazmat.2008.03.048.
- G.J. Olson, J.A. Brierley and C.L. Brierley, Appl. Microbiol. Biol., 63, 249 (2003); doi:10.1007/s00253-003-1404-6.
- J.M. Modak, K.A. Natarajan and S. Mukhopadhyay, Hydrometallurgy, 42, 51 (1996); doi:10.1016/0304-386X(95)00072-O.
- G. Zeng, X. Deng, S. Luo, X. Luo and J. Zou, J. Hazard. Mater., 199-200, 164 (2012); doi:10.1016/j.jhazmat.2011.10.063.
- D. Mishra, D.J. Kim, D.E. Ralph, J.-G. Ahn and Y.-H. Rhee, Waste Manage., 28, 333 (2008); doi:10.1016/j.wasman.2007.01.010.
- L. Li, G.S. Zeng, S.L. Luo, X.- Deng and Q.- Xie, J. Korean Soc. Appl. Biol. Chem., 56, 187 (2013); doi:10.1007/s13765-013-3016-x.
References
J.G. Kang, J. Sohn, H. Chang, G. Senanayake and S.M. Shin, Adv. Powder Technol., 21, 175 (2010); doi:10.1016/j.apt.2009.10.015.
H. Aral and A. Vecchio-Sadus, Ecotox. Environ. Saf., 70, 349 (2008); doi: 10.1016/j.ecoenv.2008.02.026.
J.F. Paulino, N.G. Busnardo and J.C. Afonso, J. Hazard. Mater., 150, 843 (2008); doi:10.1016/j.jhazmat.2007.10.048.
L. Li, J. Ge, F. Wu, R. Chen, S. Chen and B. Wu, J. Hazard. Mater., 176, 288 (2010); doi:10.1016/j.jhazmat.2009.11.026.
L. Chen, X.C. Tang, Y. Zhang, L. Li, Z. Zeng and Y. Zhang, Hydrometallurgy, 108, 80 (2011); doi:10.1016/j.hydromet.2011.02.010.
S. Castillo, F. Ansart and C. Laberty-robert, J. Power Sources, 112, 247 (2002); doi:10.1016/S0378-7753(02)00361-0.
J.Q. Xu, H.R. Thomas, R.W. Francis, K.R. Lum, J. Wang and B. Liang, J. Power Sources, 177, 512 (2008); doi:10.1016/j.jpowsour.2007.11.074.
D. Mishra, D.-J. Kim, D.E. Ralph, J.-G. Ahn and Y.-H. Rhee, Waste Manag., 28, 333 (2008); doi:10.1016/j.wasman.2007.01.010.
B. Xin, D. Zhang, X. Zhang, Y. Xia, F. Wu, S. Chen and L. Li, Bioresour. Technol., 100, 6163 (2009); doi:10.1016/j.biortech.2009.06.086.
A. Ballester, F. González, M.L. Blázquez, C. Gómez and J.L. Mier, Hydrometallurgy, 29, 145 (1992); doi:10.1016/0304-386X(92)90010-W.
J. Mier, A. Ballester, M. Blazquez, F. González and J.A. Muñoz, Miner. Eng., 8, 949 (1995); doi:10.1016/0892-6875(95)00059-Y.
M.N. Mahmood and A.K. Turner, Hydrometallury, 14, 317 (1985); doi: 10.1016/0304-386X(85)90042-8.
L. Zhao, D. Yang and N. Zhu, J. Hazard. Mater., 160, 648 (2008); doi: 10.1016/j.jhazmat.2008.03.048.
G.J. Olson, J.A. Brierley and C.L. Brierley, Appl. Microbiol. Biol., 63, 249 (2003); doi:10.1007/s00253-003-1404-6.
J.M. Modak, K.A. Natarajan and S. Mukhopadhyay, Hydrometallurgy, 42, 51 (1996); doi:10.1016/0304-386X(95)00072-O.
G. Zeng, X. Deng, S. Luo, X. Luo and J. Zou, J. Hazard. Mater., 199-200, 164 (2012); doi:10.1016/j.jhazmat.2011.10.063.
D. Mishra, D.J. Kim, D.E. Ralph, J.-G. Ahn and Y.-H. Rhee, Waste Manage., 28, 333 (2008); doi:10.1016/j.wasman.2007.01.010.
L. Li, G.S. Zeng, S.L. Luo, X.- Deng and Q.- Xie, J. Korean Soc. Appl. Biol. Chem., 56, 187 (2013); doi:10.1007/s13765-013-3016-x.