Micelles of Polymeric Ionic Liquid Block Copolymer as Templates for Preparation of Gold Nanoparticles

Junbo Li; Chen Han; Shijie Zhang; Wenlan Wu; Huiyun Zhou; Jinwu Guo

doi:10.14233/ajchem.2014.15920

Issue

Vol. 26 No. 4 (2014): Vol 26 Issue 4

Issue Published : February 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Micelles of Polymeric Ionic Liquid Block Copolymer as Templates for Preparation of Gold Nanoparticles

https://doi.org/10.14233/ajchem.2014.15920

Junbo Li

College of Chemical Engineering and Pharmaceutics, University of Science & Technology, 263 Kaiyuan Road, Luoyang 471023, P.R. China

Chen Han

College of Chemical Engineering and Pharmaceutics, University of Science & Technology, 263 Kaiyuan Road, Luoyang 471023, P.R. China

Shijie Zhang

College of Chemical Engineering and Pharmaceutics, University of Science & Technology, 263 Kaiyuan Road, Luoyang 471023, P.R. China

Wenlan Wu

College of Chemical Engineering and Pharmaceutics, University of Science & Technology, 263 Kaiyuan Road, Luoyang 471023, P.R. China

Huiyun Zhou

College of Chemical Engineering and Pharmaceutics, University of Science & Technology, 263 Kaiyuan Road, Luoyang 471023, P.R. China

Jinwu Guo

College of Chemical Engineering and Pharmaceutics, University of Science & Technology, 263 Kaiyuan Road, Luoyang 471023, P.R. China

Corresponding Author(s) : Junbo Li

lijunbo@haust.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 4 (2014): Vol 26 Issue 4
Article Published : February 15, 2014

Abstract

The ionic liquids block copolymers polystyrene-block-poly(N-ethyl-4-vinyl pyridinium bromide) {PS-b-P[E-VP]Br} was synthesized by one step quaternization of prefabricated polystyrene-block-poly(4-vinylpyridine) and bromoethane. The PS-b-P[E-VP]Br formed the micelles with polystyrene as a core and polymeric ionic liquid P[E-VP]Br as a shell in neutral aqueous solution. The composite of gold nanopartices and polymeric micelles were obtained via in situ reduction of polymeric ionic liquid shell adsorbed AuCl₄^– with NaBH₄ in neutral water. The size and morphology of micelles and outer gold nanopartices were investigated by using dynamic laser scattering, transmission electron microscope and UV-visible spectrum. The obtained gold nanopariticles have been determined to be coated on the surface of micelles and had a small quantum size (6-8 nm) and narrow distribution.

Keywords

Ionic liquids Block copolymers Self-assemble Micelles Gold nanoparticles

Li, J., Han, C., Zhang, S., Wu, W., Zhou, H., & Guo, J. (2014). Micelles of Polymeric Ionic Liquid Block Copolymer as Templates for Preparation of Gold Nanoparticles. Asian Journal of Chemistry, 26(4), 1081–1085. https://doi.org/10.14233/ajchem.2014.15920

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M.-C. Daniel and D. Astruc, Chem. Rev., 104, 293 (2004); doi:10.1021/cr030698+.

Y.-N. Wu, L.-X. Yang, X.-Y. Shi, I.-C. Li, J.M. Biazik, K.R. Ratinac, D.-H. Chen, P. Thordarson, D.-B. Shieh and F. Braet, Biomaterials, 32, 4565 (2011); doi:10.1016/j.biomaterials.2011.03.006.

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P.J. Sun, D.H. Zhou and Z.H. Gan, J. Control. Rel., 155, 96 (2011); doi:10.1016/j.jconrel.2010.11.005.

S. Rana, A. Bajaj, R. Mout and V.M. Rotello, Adv. Drug Deliv. Rev., 64, 200 (2012); doi:10.1016/j.addr.2011.08.006.

B. Raguse, E. Chow, C.S. Barton and L. Wieczorek, Anal. Chem., 79, 7333 (2007); doi:10.1021/ac070887i.

W. Shi, Y. Sahoo, M.T. Swihart and P.N. Prasad, Langmuir, 21, 1610 (2005); doi:10.1021/la047628y.

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D. Mecerreyes, Progr. Polym. Sci., 36, 1629 (2011); doi:10.1016/j.progpolymsci.2011.05.007

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X. Chen, Y. Liu, Y.L. An, J. Lu, J.B. Li, D.A. Xiong and L.Q. Shi, Macromol. Rapid Commun., 28, 1350 (2007); doi:10.1002/marc.200700166.

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J. Xia, X. Zhang and K. Matyjaszewski, Macromolecules, 32, 3531 (1999); doi:10.1021/ma9816968.

M. Ciampolini and N. Nardi, Inorg. Chem., 5, 41 (1966); doi:10.1021/ic50035a010.

J.P. Wilcoxon, J.E. Martin and P. Provincio, J. Chem. Phys., 115, 998 (2001);

X. Chen, D.Y. Zhao, Y.L. An, Y. Zhang, J. Cheng, B.L. Wang and L.Q. Shi, J. Colloid Interface Sci., 322, 414 (2008); doi:10.1016/j.jcis.2008.03.029.

K. Vijayakrishna, D. Mecerreyes, Y. Gnanou and D. Taton, Macromolecules, 42, 5167 (2009); doi:10.1021/ma900549k.

X.J. Huang, Y. Xiao, W. Zhang and M.D. Lang, Appl. Surf. Sci., 258, 2655 (2012); doi:10.1016/j.apsusc.2011.10.113.

C.M. Stancik, A.R. Lavoie, J. Schütz, P.A. Achurra, P. Lindner, A.P. Gast and R.M. Waymouth, Langmuir, 20, 596 (2004); doi:10.1021/la0353632.

P.M. Carrasco, A. Ruiz de Luzuriaga, M. Constantinou, P. Georgopanos, S. Rangou, A. Avgeropoulos, N.E. Zafeiropoulos, H.-J. Grande, G. Cabañero, D. Mecerreyes and I. Garcia, Macromolecules, 44, 4936 (2011); doi:10.1021/ma200213s.

N. Bicak and M. Gazi, J. Macromol. Sci A., 40, 585 (2003); doi:10.1081/MA-120020865.

J.P. Wilcoxon, J.E. Martin and P. Provincio, J. Chem. Phys., 115, 998 (2001) doi:10.1063/1.1380374.

J.Y. Yuan, S. Wunder, F. Warmuth and Y. Lu, Polymer, 53, 43 (2012); doi:10.1016/j.polymer.2011.11.031.

Issue

Vol. 26 No. 4 (2014): Vol 26 Issue 4

Micelles of Polymeric Ionic Liquid Block Copolymer as Templates for Preparation of Gold Nanoparticles

Corresponding Author(s) : Junbo Li

Abstract

Keywords

Full Article

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