Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis, Physico-Chemical and Antimicrobial Studies of Ionic Liquid
Corresponding Author(s) : Mohammad Azam
Asian Journal of Chemistry,
Vol. 26 No. 3 (2014): Vol 26 Issue 3
Abstract
A novel ammonium salt, an ionic liquid (ILs) was synthesized at room temperature. Its structure was elucidated by elemental analyses and various spectroscopic techniques like FT-IR, 1H and 13C NMR and ESI-MS spectrometry. Thermal studies were also carried out to get thermal stability of the ionic compound. X-ray crystallographic study was carried out to ascertain the structure of ammonium cation which is bonded to three anion via O–H…Cl intermolecular hydrogen bonds. Synthesized compound was also investigated for in vitro antimicrobial study against number microbes and results showed excellent results.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- T. Welton, Chem. Rev., 99, 2071 (1999); doi:10.1021/cr980032t.
- J. Dupont, R.F. de Souza and P.A.Z. Suarez, Chem. Rev., 102, 3667 (2002); doi:10.1021/cr010338r.
- H. Weingartner, Angew. Chem., 47, 654 (2008); doi:10.1002/anie.200604951.
- S. Keskin, D. Kayrak-Talay, U. Akman and Ö. Hortaçsu, J. Supercrit. Fluids, 43, 150 (2007); doi:10.1016/j.supflu.2007.05.013.
- K.R. Seddon, A. Stark and J. Torres, Pure Appl. Chem., 72, 2275 (2000); doi:10.1351/pac200072122275.
- are J.G. Huddleston, A.E. Visser, W.M. Reichert, H.D. Willauer, G.A. Broker and R.D. Rogers, Green Chem., 3, 156 (2001); doi:10.1039/b103275p.
- C. Chiappe and D. Pieraccini, J. Phys. Org. Chem., 18, 275 (2005); doi:10.1002/poc.863.
- R.F. de Souza, J.C. Padilha, R.S. Gonçalves and J. Dupont, Electrochem. Commun., 5, 728 (2003); doi:10.1016/S1388-2481(03)00173-5.
- V. Bicak, J. Mol. Liq., 116, 15 (2005); doi:10.1016/j.molliq.2004.03.006.
- X.B. Hu, Q.X. Lin, J.Y. Gao, Y.Y. Wu and Z.B. Zhang, Chem. Phy. Lett., 516, 35 (2011);doi: 10.1016/j.cplett.2011.09.051.
- W.W. Liu, L.Y. Cheng, Y.M. Zhang, H.P. Wang and M.F. Yu, J. Mol. Liq., 140, 68 (2008);doi: 10.1016/j.molliq.2008.01.008.
- J. Gorman, Sci. News, 160, 156 (2001); doi:10.2307/4012654.
- Q. Yang and D.D. Dionysiou, J. Photochem. Photobiol. Chem., 165, 229 (2004); doi:10.1016/j.jphotochem.2004.03.022.
- K.R. Seddon, Kinet. Catal., 37, 693 (1996).
- C. Lagrost, D. Carrié, M. Vaultier and P. Hapiot, J. Phys. Chem. A, 107, 745 (2003); doi:10.1021/jp026907w.
- C. Yue, D. Fang, L. Liu and T.-F. Yi, J. Mol. Liq., 163, 99 (2011); doi:10.1016/j.molliq.2011.09.001.
- S. Murugesan and R. Linhardt, Curr. Org. Synth., 2, 437 (2005); doi:10.2174/157017905774322640.
- N.V. Ignat’ev, U. Welz-Biermann, A. Kucheryna, G. Bissky and H. Willner, J. Fluorine Chem., 126, 1150 (2005).doi:10.1016/j.jfluchem.2005.04.017;
- L. Lu, X. Huang and Y. Qu, Colloids Surf. B, 87, 61 (2011); doi:10.1016/j.colsurfb.2011.04.037.
- D. Wei and A. Ivaska, Anal. Chim. Acta, 607, 126 (2008); doi:10.1016/j.aca.2007.12.011.
- M.J.A. Shiddiky and A.A.J. Torriero, Biosens. Bioelectron., 26, 1775 (2011); doi:10.1016/j.bios.2010.08.064.
- J.L. Anderson, D.W. Armstrong and G.T. Wei, Anal. Chem., 78, 2892 (2006); doi:10.1021/ac069394o.
- J. Pernak, K. Sobaszkiewicz and I. Mirska, Green Chem., 5, 52 (2003); doi:10.1039/b207543c.
- A. Cieniecka-Rosłonkiewicz, J. Pernak, J. Kubis-Feder, A. Ramani, A.J. Robertson and K.R. Seddon, Green Chem., 7, 855 (2005); doi:10.1039/b508499g.
- J. Pernak and P. Chwala, Eur. J. Med. Chem., 38, 1035 (2003); doi:10.1016/j.ejmech.2003.09.004.
- Y. Yu and Y. Nie, Environ. Prog., 2, 298 (2011).
- X.-R.E.D. Version, 1.18. STOE &Cie GmbH, Darmstadt, Germany (1999).
- G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
- W.M.M. Kirby, G.M. Yoshihara, K.S. Sundsted and J.H. Warren, Antibiot. Annu., 892, 1956 (1957).
- G.R. Desiraju and T. Steiner, The Weak Hydrogen Bond in Structural Chemistry and Biology, Oxford University Press, Oxford (1999).
References
T. Welton, Chem. Rev., 99, 2071 (1999); doi:10.1021/cr980032t.
J. Dupont, R.F. de Souza and P.A.Z. Suarez, Chem. Rev., 102, 3667 (2002); doi:10.1021/cr010338r.
H. Weingartner, Angew. Chem., 47, 654 (2008); doi:10.1002/anie.200604951.
S. Keskin, D. Kayrak-Talay, U. Akman and Ö. Hortaçsu, J. Supercrit. Fluids, 43, 150 (2007); doi:10.1016/j.supflu.2007.05.013.
K.R. Seddon, A. Stark and J. Torres, Pure Appl. Chem., 72, 2275 (2000); doi:10.1351/pac200072122275.
are J.G. Huddleston, A.E. Visser, W.M. Reichert, H.D. Willauer, G.A. Broker and R.D. Rogers, Green Chem., 3, 156 (2001); doi:10.1039/b103275p.
C. Chiappe and D. Pieraccini, J. Phys. Org. Chem., 18, 275 (2005); doi:10.1002/poc.863.
R.F. de Souza, J.C. Padilha, R.S. Gonçalves and J. Dupont, Electrochem. Commun., 5, 728 (2003); doi:10.1016/S1388-2481(03)00173-5.
V. Bicak, J. Mol. Liq., 116, 15 (2005); doi:10.1016/j.molliq.2004.03.006.
X.B. Hu, Q.X. Lin, J.Y. Gao, Y.Y. Wu and Z.B. Zhang, Chem. Phy. Lett., 516, 35 (2011);doi: 10.1016/j.cplett.2011.09.051.
W.W. Liu, L.Y. Cheng, Y.M. Zhang, H.P. Wang and M.F. Yu, J. Mol. Liq., 140, 68 (2008);doi: 10.1016/j.molliq.2008.01.008.
J. Gorman, Sci. News, 160, 156 (2001); doi:10.2307/4012654.
Q. Yang and D.D. Dionysiou, J. Photochem. Photobiol. Chem., 165, 229 (2004); doi:10.1016/j.jphotochem.2004.03.022.
K.R. Seddon, Kinet. Catal., 37, 693 (1996).
C. Lagrost, D. Carrié, M. Vaultier and P. Hapiot, J. Phys. Chem. A, 107, 745 (2003); doi:10.1021/jp026907w.
C. Yue, D. Fang, L. Liu and T.-F. Yi, J. Mol. Liq., 163, 99 (2011); doi:10.1016/j.molliq.2011.09.001.
S. Murugesan and R. Linhardt, Curr. Org. Synth., 2, 437 (2005); doi:10.2174/157017905774322640.
N.V. Ignat’ev, U. Welz-Biermann, A. Kucheryna, G. Bissky and H. Willner, J. Fluorine Chem., 126, 1150 (2005).doi:10.1016/j.jfluchem.2005.04.017;
L. Lu, X. Huang and Y. Qu, Colloids Surf. B, 87, 61 (2011); doi:10.1016/j.colsurfb.2011.04.037.
D. Wei and A. Ivaska, Anal. Chim. Acta, 607, 126 (2008); doi:10.1016/j.aca.2007.12.011.
M.J.A. Shiddiky and A.A.J. Torriero, Biosens. Bioelectron., 26, 1775 (2011); doi:10.1016/j.bios.2010.08.064.
J.L. Anderson, D.W. Armstrong and G.T. Wei, Anal. Chem., 78, 2892 (2006); doi:10.1021/ac069394o.
J. Pernak, K. Sobaszkiewicz and I. Mirska, Green Chem., 5, 52 (2003); doi:10.1039/b207543c.
A. Cieniecka-Rosłonkiewicz, J. Pernak, J. Kubis-Feder, A. Ramani, A.J. Robertson and K.R. Seddon, Green Chem., 7, 855 (2005); doi:10.1039/b508499g.
J. Pernak and P. Chwala, Eur. J. Med. Chem., 38, 1035 (2003); doi:10.1016/j.ejmech.2003.09.004.
Y. Yu and Y. Nie, Environ. Prog., 2, 298 (2011).
X.-R.E.D. Version, 1.18. STOE &Cie GmbH, Darmstadt, Germany (1999).
G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
W.M.M. Kirby, G.M. Yoshihara, K.S. Sundsted and J.H. Warren, Antibiot. Annu., 892, 1956 (1957).
G.R. Desiraju and T. Steiner, The Weak Hydrogen Bond in Structural Chemistry and Biology, Oxford University Press, Oxford (1999).