Fluorimetric Determination of Trace Bisphenol-A Based on its Oxidative Reaction with Fenton-Like Reagent as Oxidant

Jianting Wang; Jian Zhang; Jun Zhu; Renmin Gong

doi:10.14233/ajchem.2014.15578

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Issue Published : January 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Fluorimetric Determination of Trace Bisphenol-A Based on its Oxidative Reaction with Fenton-Like Reagent as Oxidant

https://doi.org/10.14233/ajchem.2014.15578

Jianting Wang

College of Life Science, Anhui Normal University, Wuhu, 241000, P.R. China

Jian Zhang

College of Life Science, Anhui Normal University, Wuhu, 241000, P.R. China

Jun Zhu

College of Life Science, Anhui Normal University, Wuhu, 241000, P.R. China

Renmin Gong

College of Life Science, Anhui Normal University, Wuhu, 241000, P.R. China

Corresponding Author(s) : Renmin Gong

rmgong.nju@163.com

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3
Article Published : January 30, 2014

Abstract

Bisphenol-A (BPA) is an exogenous substance that acts like hormones in the endocrine system and disrupts the physiologic function of endogenous hormones. Due to the widespread human exposure to bisphenol-A and its potential adverse effects on human health, special attention has been paid to the determination of bisphenol-A in the environment. In this paper, a simple, sensitive and selective fluorimetric method for the determination of bisphenol-A, based on the oxidative reaction of bisphenol-A in the presence of hydrochloric acid by Fenton-like reagent (Fe³⁺+H₂O₂), had been developed. The fluorescence came from the oxidation product of bisphenol-A at l_excitation 315 and l_emission 415 nm in pH 8.90 Tris-HCl buffer solution. Under the optimum conditions, a linear relationship had been obtained between the fluorescence intensity and the concentration of bisphenol-A in the range of 0.01-0.5 μg/mL, with detection limit and correlation coefficient being 0.64 ng/mL and 0.9995, respectively. The proposed method had been successfully applied for the determination of trace bisphenol-A in water, beverage bottle and cling wrap film.

Keywords

Fluorimetric determination Bisphenol-A Fenton-like reagent and oxidative reaction

Wang, J., Zhang, J., Zhu, J., & Gong, R. (2014). Fluorimetric Determination of Trace Bisphenol-A Based on its Oxidative Reaction with Fenton-Like Reagent as Oxidant. Asian Journal of Chemistry, 26(3), 809–813. https://doi.org/10.14233/ajchem.2014.15578

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References

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C. Desbrow, E.J. Routledge, G.C. Brighty, J.P. Sumpter and M. Waldock, Environ. Sci. Technol., 32, 1549 (1998); doi:10.1021/es9707973.

A. Laganà, A. Bacaloni, I. De Leva, A. Faberi, G. Fago and A. Marino, Anal. Chim. Acta, 501, 79 (2004); doi:10.1016/j.aca.2003.09.020.

C.A. Staples, P.B. Dome, G.M. Klecka, S.T. Oblock and L.R. Harris, Chemosphere, 36, 2149 (1998); doi:10.1016/S0045-6535(97)10133-3.

Y. Cai, G. Jiang, J. Liu and Q. Zhou, Anal. Chem., 75, 2517 (2003); doi:10.1021/ac0263566.

L. Grumetto, D. Montesano, S. Seccia, S. Albrizio and F. Barbato, J. Agric. Food Chem., 56, 10633 (2008); doi:10.1021/jf802297z.

M. Rezaee, Y. Yamini, S. Shariati, A. Esrafili and M. Shamsipur, J. Chromatogr. A, 1216, 1511 (2009); doi:10.1016/j.chroma.2008.12.091.

H. Sambe, K. Hoshina, K. Hosoya and J. Haginaka, J. Chromatogr. A, 1134, 16 (2006); doi:10.1016/j.chroma.2006.08.072.

N.C. Maragou, E.N. Lampi, N.S. Thomaidis and M.A. Koupparis, J. Chromatogr. A, 1129, 165 (2006); doi:10.1016/j.chroma.2006.06.103.

W. Yan, Y. Li, L. Zhao and J. Lin, J. Chromatogr. A, 1216, 7539 (2009); doi:10.1016/j.chroma.2009.05.002.

R.J.W. Meesters and H.F. Schröder, Anal. Chem., 74, 3566 (2002); doi:10.1021/ac011258q.

N. Casajuana and S. Lacorte, J. Agric. Food Chem., 52, 3702 (2004); doi:10.1021/jf040027s.

C. Sánchez-Brunete, E. Miguel and J.L. Tadeo, J. Chromatogr. A, 1216, 5497 (2009); doi:10.1016/j.chroma.2009.05.065.

M. del Olmo, A. Zafra, A.B. Jurado, J.L. Vilchez, Talanta, 50, 1141 (2000); doi:10.1016/S0039-9140(99)00176-9.

J. Fan, H. Guo, G. Liu and P. Peng, Anal. Chim. Acta, 585, 134 (2007); doi:10.1016/j.aca.2006.12.026.

H. Yin, L. Cui, S. Ai, H. Fan and L. Zhu, Electrochim. Acta, 55, 603 (2010); doi:10.1016/j.electacta.2009.09.020.

J.-H. Li, D.-Z. Kuang, Y.-L. Feng, F.-X. Zhang and M.-Q. Liu, Asian J. Chem., 25, 3147 (2013);doi: /10.14233/ajchem.2013.13560.

A. Motoyama, A. Suzuki, O. Shirota and R. Namba, Rapid Commun. Mass Spectrom., 13, 2204 (1999); doi:10.1002/(SICI)1097-0231(19991115)13:21<2204::AID-RCM776>3.0.CO;2-9.

J. Liu, X. Liang, G. Jiang, Y. Cai, Q. Zhou and G. Liu, Talanta, 60, 1155 (2003); doi:10.1016/S0039-9140(03)00216-9.

S. Nakamura and S. Daishima, J. Chromatogr. A, 1038, 291 (2004); doi:10.1016/j.chroma.2004.03.040.

A. Moral, M.D. Sicilia, S. Rubio and D. Pérez-Bendito, J. Chromatogr. A, 1100, 8 (2005); doi:10.1016/j.chroma.2005.09.019.

M.D. Olmo, A. Zafra, A. Gonzalez-Casado and J.L. Vilchez, Int. J. Environ. Anal. Chem., 69, 99 (1998); doi:10.1080/03067319808032577.

J. Gao, J. Zhou and X. Qu, Anal. Sci., 21, 409 (2005); doi:10.2116/analsci.21.409.

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Fluorimetric Determination of Trace Bisphenol-A Based on its Oxidative Reaction with Fenton-Like Reagent as Oxidant

Corresponding Author(s) : Renmin Gong

Abstract

Keywords

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