Synthesis and Characterization of Copper(II) Complexes with Salen-Type Bisoxime Chelating Ligand

Yin-Xia Sun; Xin-Ran Li; Rui-E Lu; Wei-Sheng Meng

doi:10.14233/ajchem.2014.15549

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Issue Published : January 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Copper(II) Complexes with Salen-Type Bisoxime Chelating Ligand

https://doi.org/10.14233/ajchem.2014.15549

Yin-Xia Sun

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xin-Ran Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Rui-E Lu

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Wei-Sheng Meng

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Yin-Xia Sun

sun_yinxia@163.com

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3
Article Published : January 30, 2014

Abstract

Two Cu(II) complexes 1 and 2 have been synthesized by the reaction of copper(II) picrate tetrahydrate and copper(II) perchlorate hexahydrate with a Salen-type bisoxime chelating ligand (H₂L = 6,6'-dimethoxy-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol) and characterized by elemental analyses, IR spectra, UV-visible spectra, TG-DTA analyses and molar conductances. The Salen-type bisoxime is a good tetradentate N₂O₂-donating ligand and the likely formula of the Cu(II) complexes may be suggested as CuL·(HPic)₂ (1) and CuL·2H₂O (2).

Keywords

Cu(II) complex Bisoxime ligand Synthesis

Sun, Y.-X., Li, X.-R., Lu, R.-E., & Meng, W.-S. (2014). Synthesis and Characterization of Copper(II) Complexes with Salen-Type Bisoxime Chelating Ligand. Asian Journal of Chemistry, 26(3), 799–801. https://doi.org/10.14233/ajchem.2014.15549

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References

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References

S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002); doi:10.1002/anie.200290011.

S. Akine, A. Akimoto, T. Shiga, H. Oshio and T. Nabeshima, Inorg. Chem., 47, 875 (2008); doi:10.1021/ic701525c.

S. Akine, T. Taniguchi and T. Nabeshima, Inorg. Chem., 43, 6142 (2004); doi:10.1021/ic049282k.

(a) W.-K. Dong, J.-G. Duan, L.-Q. Chai, G.-L. Liu and H.-L. Wu, J. Coord. Chem., 61, 1306 (2008); doi:10.1080/00958970701573178.; (b) W.K. Dong, J.Y. Shi, L. Xu, J.K. Zhong, J.G. Duan and Y.P. Zhang, Appl. Organomet. Chem., 22, 89 (2008); doi:10.1002/aoc.1355.; (c) W.K. Dong and J.G. Duan, J. Coord. Chem., 61, 781 (2008); doi:10.1080/00958970701376291.; (d) W.K. Dong, J.H. Feng, L. Wang, L. Xu, L. Zhao, X.Q. Yang and T.-Z. Yu, Transition Met. Chem., 32, 1101 (2007); doi:10.1007/s11243-007-0292-5.; (e) W.K. Dong, J.G. Duan and G.L. Liu, Transition Met. Chem., 32, 702 (2007); doi:10.1007/s11243-007-0240-4.; (f) W.K. Dong, J.Y. Shi, J.K. Zhong, Y.Q. Tian and J.G. Duan, Chin. J. Inorg. Chem, 24, 10 (2008); (g) W.K. Dong, J.Y. Shi, J.K. Zhong, Y.Q. Tian and J.G. Duan, Chin. J. Inorg. Chem., 24, 10 (2008); (h) W.K. Dong, C.E. Zhu, H.L. Wu, Y.J. Ding and T.Z. Yu, Synth. React. Inorg. Met.-Org. Nano-Met. Chem, 37, 61 (2007); doi:10.1080/15533170601172492.; (i) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (j) W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009); doi:10.1016/j.ica.2008.05.028.; (k) W.K. Dong, L. Li, C.F. Li, L. Xu and J.G. Duan, Spectrochimica Acta Part A, 71, 650 (2008); doi:10.1016/j.saa.2008.01.020.

N.S. Venkataramanan, G. Kuppuraj and S. Rajagopal, Coord. Chem. Rev., 249, 1249 (2005); doi:10.1016/j.ccr.2005.01.023.

M.F. Summers, L.G. Marzilli, N. Bresciani-Pahor and L. Randaccio, J. Am. Chem. Soc., 106, 4478 (1984); doi:10.1021/ja00328a030.

P.G. Lacroix, Eur. J. Inorg. Chem., 339 (2001); doi:10.1002/1099-0682(200102)2001:2<339::AID-EJIC339>3.0.CO;2-Z.

S.S. Sun, C.L. Stern, S.T. Nguyen and J.T. Hupp, J. Am. Chem. Soc., 126, 6314 (2004); doi:10.1021/ja037378s.

X.Q. Song, J.R. Zheng, W.S. Liu and Z.H. Ju, Spectrochim. Acta Part A, 69, 49 (2008); doi:10.1016/j.saa.2007.03.007.

S.X. Liu, W.S. Liu, M.Y. Tan and K.B. Yu, J. Coord. Chem., 39, 105 (1996);doi: 10.1080/00958979608022714.

X.Q. Song, W.S. Liu, W. Dou, Y.W. Wang, J.R. Zheng and Z.P. Zang, Eur. J. Inorg. Chem., 2008, 1901 (2008); doi:10.1002/ejic.200701279.

T. Ghosh, B. Mondal, T. Ghosh, M. Sutradhar, G. Mukherjee and M.G.B. Drew, Inorg. Chim. Acta, 360, 1753 (2007); doi:10.1016/j.ica.2006.10.003.

H.E. Smith, Chem. Rev., 83, 359 (1983); doi:10.1021/cr00056a001.

S. Akine, T. Taniguchi and T. Nabeshima, Chem. Lett., 30, 682 (2001); doi:10.1246/cl.2001.682.

L. Gomes, E. Pereira and B. de Castro, J. Chem. Soc., Dalton Trans., 1373 (2000); doi:10.1039/a908330h.

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Synthesis and Characterization of Copper(II) Complexes with Salen-Type Bisoxime Chelating Ligand

Corresponding Author(s) : Yin-Xia Sun

Abstract

Keywords

Full Article

Download Citation

References

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