Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex

Chenglu Bi; Weihua Li; Hui Lu; Hui Zhang; Jianhua Sun

doi:10.14233/ajchem.2014.15525

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Issue Published : January 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex

https://doi.org/10.14233/ajchem.2014.15525

Chenglu Bi

Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, P.R. China

Weihua Li

Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, P.R. China

Hui Lu

Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, P.R. China

Hui Zhang

Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, P.R. China

Jianhua Sun

Jiangsu Key Laboratory of Precious Metals Chemistry, School of Chemistry and Environmental Engineering, Jiangsu University of Technology, Changzhou 213001, P.R. China

Corresponding Author(s) : Jianhua Sun

sunjh@jsut.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3
Article Published : January 30, 2014

Abstract

A dinuclear zinc complex [Zn₂(qnal)₂(CH₃COO)₂] (Hqnal: N-(8'-quinolyl)-2-hydroxy-1-naphthaldimine) was synthesized and characterized by X-ray crystallography. The complex crystallizes in monoclinic system, space group C2/c with a = 40.00(3), b = 7.690(5), c = 27.492(16) Å, b = 120.446(11)°, V = 17290(8) Å³, Z = 8. D_c = 1.537 g/cm³, M_r = 843.48, F(000) = 3456, μ(MoK_a) = 1.374 mm^-1, S = 1.033, R = 0.0403 and wR = 0.1049 for 4454 observed reflections (I > 2s(I)). It exhibits a 3D supramolecular architecture constructing by p-p stacking interactions between quinolyl and naphthyl rings and shows luminescent property in the yellow region.

Keywords

Zinc complex Crystal structure Dinuclear Fluorescence

Bi, C., Li, W., Lu, H., Zhang, H., & Sun, J. (2014). Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex. Asian Journal of Chemistry, 26(3), 761–763. https://doi.org/10.14233/ajchem.2014.15525

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References

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References

M. Eddaoudi, D.B. Moler, H. Li, B. Chen, T.M. Reineke, M. O’Keeffe and O.M. Yaghi, Acc. Chem. Res., 34, 319 (2001); doi:10.1021/ar000034b.

G. Peng, Y.-C. Qiu, Z.-H. Liu, B. Liu and H. Deng, Cryst. Growth Des., 10, 114 (2010); doi:10.1021/cg900571v.

U.M. Rabie, A.S.A. Assran and M.H.M. Abou-El-Wafa, J. Mol. Struct., 872, 113 (2008); doi:10.1016/j.molstruc.2007.02.023.

P.-H. Lin, T.J. Burchell, L. Ungur, L.F. Chibotaru, W. Wernsdorfer and M. Murugesu, Angew. Chem. Int. Ed., 48, 9489 (2009); doi:10.1002/anie.200903199.

E.M. Nolan, J. Jaworski, K.-I. Okamoto, Y. Hayashi, M. Sheng and S.J. Lippard, J. Am. Chem. Soc., 127, 16812 (2005); doi:10.1021/ja052184t.

L. Canovese, F. Visentin, G. Chessa, C. Levi and P. Nikolov, Inorg. Chim. Acta, 362, 3925 (2009); doi:10.1016/j.ica.2009.05.017.

H.M. Park, B.N. Oh, J.H. Kim, W. Qiong, I.H. Hwang, K.-D. Jung, C. Kim and J. Kim, Tetrahedron Lett., 52, 5581 (2011); doi:10.1016/j.tetlet.2011.08.045.

C.-L. Fan, X. Dai, W.-M. Yang, X.-F. Wang and Y.-X. Yang, Chem. Res. Chin. Univ., 25, 620 (2009).

H. Wang, F. He and C. Jiang, Analyst, 126, 1164 (2001); doi:10.1039/b100814p.

Bruker, Smart, Saint, Sadabs and Shelxtl, Bruker AXS Inc., Madison, WI, USA (2000).

C.-B. Li, Y. Yang, S.-C. Zhang, L. Yan, J. Li, L.-J. Sun, W.-C. Li and J.-J. Wang, Chinese J. Struct. Chem., 30, 1233 (2011).

L.-Y. Qiao, X. Zhang, J.-X. Yang, Z.-J. Li and Y.-G. Yao, Chinese. Struct. Chem., 30, 1006 (2011).

U. Kumar, J. Thomas and N. Thirupathi, Inorg. Chem., 49, 62 (2010); doi:10.1021/ic901100z.

K. Takahashi, H.-B. Cui, Y. Okano, H. Kobayashi, H. Mori, H. Tajima, Y. Einaga and O. Sato, J. Am. Chem. Soc., 130, 6688 (2008); doi:10.1021/ja801585r.

Z. Yu, T. Kuroda-Sowa, H. Kume, T. Okubo, M. Maekawa and M. Munakata, Bull. Chem. Soc. Jpn., 82, 333 (2009); doi:10.1246/bcsj.82.333.

P. Fita, E. Luzina, T. Dziembowska, C. Radzewicz and A. Grabowska, J. Chem. Phys., 125, 184508 (2006); doi:10.1063/1.2371058.

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Synthesis, Crystal Structure and Fluorescent Properties of Dinuclear Zinc Complex

Corresponding Author(s) : Jianhua Sun

Abstract

Keywords

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