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Vol. 26 No. 3 (2014): Vol 26 Issue 3

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Synthesis and Structures of Mononuclear Co(III) and Cu(II) Complexes Derived from N-[2-(2-Hydroxy-3-methoxybenzylideneamino)cyclohexyl]-2-hydroxybenzamide

https://doi.org/10.14233/ajchem.2014.15501
Hui-Yu Wang
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P.R. China
Yun-Hui Li
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P.R. China
Yu-Qin Ma
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P.R. China
Ying Gao
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P.R. China
Gui-Miao Yu
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P.R. China
Xiu-Yun Yang
School of Chemistry and Environmental Engineering, Changchun University of Science and Technology, Changchun 130022, P.R. China

Corresponding Author(s) : Xiu-Yun Yang

liyh@cust.edu.cn; whyu@ciac.jl.cn

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3

Abstract

Two mononuclear complexes, [Co(HL)2(C8H7O3)]·(CH3OH)2 (1) and [Cu(HL)2] (2) where H2L = N-[2-(2-hydroxy-3-methoxybenzylidene-amino)cyclohexyl]-2-hydroxybenzamide have been synthesized and characterized by IR, elemental analysis and crystal structure analysis. In complexes (1) and (2) the core ion has the six-coordinated N2O4 environment with a distorted octahedral geometry and four-coordinated N2O2 environment with a distorted square-planar geometry, respectively.

Keywords

Cobalt(II) Copper(II) Complexes Crystal structure
Wang, H.-Y., Li, Y.-H., Ma, Y.-Q., Gao, Y., Yu, G.-M., & Yang, X.-Y. (2014). Synthesis and Structures of Mononuclear Co(III) and Cu(II) Complexes Derived from N-[2-(2-Hydroxy-3-methoxybenzylideneamino)cyclohexyl]-2-hydroxybenzamide. Asian Journal of Chemistry, 26(3), 733–735. https://doi.org/10.14233/ajchem.2014.15501
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