Synthesis, Thermal and Magnetic Behaviour of Monohydrated Cadmium Selenium(IV) Bromine(V) Oxide [Cd3Se2Br2O12&middot;H2O]

Faiz Rabbani; Humayun Ajaz; K.A. Bhatti

doi:10.14233/ajchem.2014.15470

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Issue Published : January 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Thermal and Magnetic Behaviour of Monohydrated Cadmium Selenium(IV) Bromine(V) Oxide [Cd3Se2Br2O12·H2O]

https://doi.org/10.14233/ajchem.2014.15470

Faiz Rabbani

Department of Chemistry, University of Engineering and Technology, Lahore, Pakistan ;Department of Chemistry, COMSATS Institute of Information Technology, Abbottabad 22060, Pakistan

Humayun Ajaz

Department of Chemistry, COMSATS Institute of Information Technology, Abbottabad 22060, Pakistan

K.A. Bhatti

Department of Physics, University of Engineering and Technology, Lahore, Pakistan

Corresponding Author(s) : Faiz Rabbani

faizqau@yahoo.com

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3
Article Published : January 30, 2014

Abstract

The monohydrated white crystals of nano-material, cadmium selenium(IV) bromine(V) oxide formulated as Cd₃Se₂Br₂O₁₂·H₂O, were obtained at 450 °C. The morphology and elemental analysis of the material were investigated by scanning electron microscopy and energy dispersive X-rays analysis. The new phase was confirmed through unique patterns of powder X-ray diffraction (PXRD) and characteristic melting point. The decomposition temperature and thermal behaviour of the product was studied using differential scanning colorimeter attached with thermal gravimetric analyzer. The bond vibrations and magnetic measurements were performed using fourier transform infra-red spectrophotometer and vibrating sample magnetometer respectively.

Keywords

Composite Materials EDAX DSC FT/IR Cd3Se2Br2O12.H2O

Rabbani, F., Ajaz, H., & Bhatti, K. (2014). Synthesis, Thermal and Magnetic Behaviour of Monohydrated Cadmium Selenium(IV) Bromine(V) Oxide [Cd3Se2Br2O12·H2O]. Asian Journal of Chemistry, 26(3), 681–684. https://doi.org/10.14233/ajchem.2014.15470

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References

B.A. El-Sayed, A.A.A. Emara, F.S.M.Abd El-Hameed and S.M. Shaaban, Mater. Lett., 27, 247 (1996); doi:10.1016/0167-577X(95)00294-4.
M. Johnsson, K.W. Törnroos, P. Lemmens and P. Millet, Chem. Mater., 15, 68 (2003); doi:10.1021/cm0206587.
R. Becker and M. Johnsson, J. Solid State Chem., 180, 1750 (2007); doi:10.1016/j.jssc.2007.03.013.
R. Becker, M. Johnsson, R.K. Kremer and P. Lemmens, Solid State Sci., 5, 1411 (2003); doi:10.1016/j.solidstatesciences.2003.09.010.
R. Becker, M. Johnsson, R. Kremer and P. Lemmens, J. Solid State Chem., 178, 2024 (2005); doi:10.1016/j.jssc.2005.04.011.
R. Becker, H. Berger, M. Johnsson, M. Prester, Z. Marohnic, M. Miljak and M. Herak, J. Solid State Chem., 179, 836 (2006); doi:10.1016/j.jssc.2005.12.007.
R. Takagi, M. Johnsson, V. Gnezdilov, R.K. Kremer, W. Brenig and P. Lemmens, Phys. Rev. B, 74, 014413 (2006); doi:10.1103/PhysRevB.74.014413.
Z. Mayerova´, M. Johnsson and S. Lidin, Angew. Chem. Int. Ed., 45, 5602 (2006); doi:10.1002/anie.200600861.
Y.L. Shen, J.G. Mao and H.L. Jiang, J. Solid State Chem., 178, 2942 (2005); doi:10.1016/j.jssc.2005.07.005.
R.T. Hart, K.-M. Ok, P.S. Halasyamani and J.W. Zwanziger, Appl. Phys. Lett., 85, 938 (2004); doi:10.1063/1.1779957.
M.G. Johnston and W.T.A. Harrison, J. Solid State Chem., 177, 4680 (2004); doi:10.1016/j.jssc.2004.07.057.
M.A. Cooper and F.C. Hawthorne, Can. Mineral., 39, 797 (2001); doi:10.2113/gscanmin.39.3.797.
O. Zaharko, M. Pregelj, D. Arcon, P.J. Brown, D. Chernyshov, U. Stuhr and H. Berger, J. Phys. Conf. Ser., 211, 012002 (2010); doi:10.1088/1742-6596/211/1/012002.
H.L. Jiang and J.G. Mao, Inorg. Chem., 45, 717 (2006); doi:10.1021/ic051703q.
http://winter.group.shef.ac.uk/chemputer/percent.html(04/05/2011, 08:35am).
E. Mirica, G. Kowach, P. Evans and H. Du, Cryst. Growth Des., 4, 147 (2004); doi:10.1021/cg025595j.
M.S. Rafique, M. Khaleeq-ur-Rahman, S. Saif-ur-Rehman, M.S. Anjum, K.A. Anwar, S. Bhatti, Saeed and M.S. Awan, Vaccum, 82, 1233 (2008); doi:10.1016/j.vacuum.2008.01.052.
A. Latif, Ph.D. Thesis, The Diagnostic and Analysis of Optical, Thermal and Electrical Properties of Laser Ablated Materials, Department of Physics, University of Engineering and Technology, Lahore, Pakistan (2011).
N. Matsunami, O. Fukuoka, M. Tazawa and M. Sataka, Surf. Coat. Technol., 196, 50 (2005); doi:10.1016/j.surfcoat.2004.08.093.
W.F. Smith, Principles of Material Science and Engineering, McGraw Hill, Tokyo, edn 2 (1990).
M. Khaleeq-ur-Rahman, K.A. Bhatti, M.S. Rafique, A. Latif, P. Lee and S. Mahmood, Laser Phys., 17, 1382 (2007); doi:10.1134/S1054660X07120080.
H. Ajaz, H.-J. Deiseroth, M. Schlosser and F. Rabbani, Synth. React. Inorg. Metal-Org. Nano-Metal Chem., 39, 209 (2009); doi: 10.1080/15533170902858211.
A. Latif, M. Khaleeq-Ur-Rahman, M.S. Rafique, K.A. Bhatti and M. Imran, Radiation Effects Defects Solids, 164, 68 (2009); doi:10.1080/10420150802163950.
P.S. Berdonosov, A.V. Olenev and V.A. Dolgikh, J. Solid State Chem., 182, 2368 (2009); doi:10.1016/j.jssc.2009.06.020.
P.S. Berdonosov, A.V. Olenev, A.N. Kuznetsov and V.A. Dolgikh, J. Solid State Chem., 182, 77 (2009); doi:10.1016/j.jssc.2008.10.003.
A. Abbasi and M.Y. Skripkin, J. Sci. Univ. Tehran, 33, 1 (2007).
C. Jin, R. Aggarwal, W. Wei, S. Nori, D. Kumar, D. Ponarin, A.I. Smirnov, J. Narayan and R.J. Narayan, Metallurg. Mater. Trans. A, 42, 3250 (2011); doi:10.1007/s11661-010-0479-9.
S. Riaz, S. Naseem and Y.B. Xu, J. Sol-Gel Sci. Technol., 59, 584 (2011); doi:10.1007/s10971-011-2532-6.

References

B.A. El-Sayed, A.A.A. Emara, F.S.M.Abd El-Hameed and S.M. Shaaban, Mater. Lett., 27, 247 (1996); doi:10.1016/0167-577X(95)00294-4.

M. Johnsson, K.W. Törnroos, P. Lemmens and P. Millet, Chem. Mater., 15, 68 (2003); doi:10.1021/cm0206587.

R. Becker and M. Johnsson, J. Solid State Chem., 180, 1750 (2007); doi:10.1016/j.jssc.2007.03.013.

R. Becker, M. Johnsson, R.K. Kremer and P. Lemmens, Solid State Sci., 5, 1411 (2003); doi:10.1016/j.solidstatesciences.2003.09.010.

R. Becker, M. Johnsson, R. Kremer and P. Lemmens, J. Solid State Chem., 178, 2024 (2005); doi:10.1016/j.jssc.2005.04.011.

R. Becker, H. Berger, M. Johnsson, M. Prester, Z. Marohnic, M. Miljak and M. Herak, J. Solid State Chem., 179, 836 (2006); doi:10.1016/j.jssc.2005.12.007.

R. Takagi, M. Johnsson, V. Gnezdilov, R.K. Kremer, W. Brenig and P. Lemmens, Phys. Rev. B, 74, 014413 (2006); doi:10.1103/PhysRevB.74.014413.

Z. Mayerova´, M. Johnsson and S. Lidin, Angew. Chem. Int. Ed., 45, 5602 (2006); doi:10.1002/anie.200600861.

Y.L. Shen, J.G. Mao and H.L. Jiang, J. Solid State Chem., 178, 2942 (2005); doi:10.1016/j.jssc.2005.07.005.

R.T. Hart, K.-M. Ok, P.S. Halasyamani and J.W. Zwanziger, Appl. Phys. Lett., 85, 938 (2004); doi:10.1063/1.1779957.

M.G. Johnston and W.T.A. Harrison, J. Solid State Chem., 177, 4680 (2004); doi:10.1016/j.jssc.2004.07.057.

M.A. Cooper and F.C. Hawthorne, Can. Mineral., 39, 797 (2001); doi:10.2113/gscanmin.39.3.797.

O. Zaharko, M. Pregelj, D. Arcon, P.J. Brown, D. Chernyshov, U. Stuhr and H. Berger, J. Phys. Conf. Ser., 211, 012002 (2010); doi:10.1088/1742-6596/211/1/012002.

H.L. Jiang and J.G. Mao, Inorg. Chem., 45, 717 (2006); doi:10.1021/ic051703q.

http://winter.group.shef.ac.uk/chemputer/percent.html(04/05/2011, 08:35am).

E. Mirica, G. Kowach, P. Evans and H. Du, Cryst. Growth Des., 4, 147 (2004); doi:10.1021/cg025595j.

M.S. Rafique, M. Khaleeq-ur-Rahman, S. Saif-ur-Rehman, M.S. Anjum, K.A. Anwar, S. Bhatti, Saeed and M.S. Awan, Vaccum, 82, 1233 (2008); doi:10.1016/j.vacuum.2008.01.052.

A. Latif, Ph.D. Thesis, The Diagnostic and Analysis of Optical, Thermal and Electrical Properties of Laser Ablated Materials, Department of Physics, University of Engineering and Technology, Lahore, Pakistan (2011).

N. Matsunami, O. Fukuoka, M. Tazawa and M. Sataka, Surf. Coat. Technol., 196, 50 (2005); doi:10.1016/j.surfcoat.2004.08.093.

W.F. Smith, Principles of Material Science and Engineering, McGraw Hill, Tokyo, edn 2 (1990).

M. Khaleeq-ur-Rahman, K.A. Bhatti, M.S. Rafique, A. Latif, P. Lee and S. Mahmood, Laser Phys., 17, 1382 (2007); doi:10.1134/S1054660X07120080.

H. Ajaz, H.-J. Deiseroth, M. Schlosser and F. Rabbani, Synth. React. Inorg. Metal-Org. Nano-Metal Chem., 39, 209 (2009); doi: 10.1080/15533170902858211.

A. Latif, M. Khaleeq-Ur-Rahman, M.S. Rafique, K.A. Bhatti and M. Imran, Radiation Effects Defects Solids, 164, 68 (2009); doi:10.1080/10420150802163950.

P.S. Berdonosov, A.V. Olenev and V.A. Dolgikh, J. Solid State Chem., 182, 2368 (2009); doi:10.1016/j.jssc.2009.06.020.

P.S. Berdonosov, A.V. Olenev, A.N. Kuznetsov and V.A. Dolgikh, J. Solid State Chem., 182, 77 (2009); doi:10.1016/j.jssc.2008.10.003.

A. Abbasi and M.Y. Skripkin, J. Sci. Univ. Tehran, 33, 1 (2007).

C. Jin, R. Aggarwal, W. Wei, S. Nori, D. Kumar, D. Ponarin, A.I. Smirnov, J. Narayan and R.J. Narayan, Metallurg. Mater. Trans. A, 42, 3250 (2011); doi:10.1007/s11661-010-0479-9.

S. Riaz, S. Naseem and Y.B. Xu, J. Sol-Gel Sci. Technol., 59, 584 (2011); doi:10.1007/s10971-011-2532-6.