Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Template Synthesis and Characterization of Macrocyclic Complexes of Trivalent Metal Ions Derived from Oxalyldihydrazide and Isatin
Asian Journal of Chemistry,
Vol. 26 No. 2 (2014): Vol 26 Issue 2
Abstract
A new series of complexes of the type [M(C20H14N10O4)X]X2; where M = Cr(III), Fe(III) and X = Cl–, NO3–, CH3COO– have been synthesised by template condensation reaction of oxalyldihydrazide and isatin resulting into the formation of the macrocyclic complexes. The complexes has been characterized with the help of elemental analyses and conductance measurements, electronic, IR, Far IR, mass spectral studies and these metal complexes were also tested for their in vitro antimicrobial activities to assess their inhibiting potential.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- S. Ilhan and H. Temel, Transition Met. Chem., 32, 1039 (2007); doi:10.1007/s11243-007-0276-5.
- W. Ma, Y.-P. Tian, S.-Y. Zhang, J.-Y. Wu, H.-K. Fun and S. Chantrapromma, Transition Met. Chem., 31, 97 (2006); doi:10.1007/s11243-005-6336-9.
- D. Swallow, J.M. McInnes and P. Mountford, J. Chem. Soc., Dalton Trans., 2253 (1998); doi:10.1039/a802686f.
- G. Cerchiaro and A.M.C. Ferreira, J. Braz. Chem. Soc., 17, 1473 (2006); doi:10.1590/S0103-50532006000800003.
- I. Ahmad and A.J. Beg, J. Ethnopharmacol., 74, 113 (2001); doi:10.1016/S0378-8741(00)00335-4.
- W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); doi:10.1016/S0010-8545(00)80009-0.
- A.K. Singh, A. Panwar, R. Singh and S. Baniwal, Transition Met. Chem., 28, 160 (2003); doi:10.1023/A:1022916620211.
- D.P. Singh, R. Kumar and P. Tyagi, Transition Met. Chem., 31, 970 (2006); doi:10.1007/s11243-006-0096-z.
- D.P. Singh, N. Shishodia, B.P. Yadav and V.B. Rana, Polyhedron, 16, 2229 (1997); doi:10.1016/S0277-5387(96)00544-X.
- S. Chandra and S.D. Sharma, Transition Met. Chem., 27, 732 (2002); doi:10.1023/A:1020309322470.
- A. Chaudhary and R.V. Singh, Indian J. Chem., 43A, 2529 (2004).
- K. Nakamoto, Infrared & Raman Spectra of Inorganic & Coordination Compounds, Part-B, Wiley Interscience Publication, edn. 5 (1997).
- M. Shakir, O.S.M. Nasman and S.P. Varkey, Polyhedron, 15, 309 (1996); doi:10.1016/0277-5387(95)00189-Y.
- D.P. Singh, V. Malik, R. Kumar, K. Kumar and J. Singh, Russ. J. Coord. Chem., 35, 740 (2009); doi:10.1134/S1070328409100054.
- M. Shakir, K.S. Islam, A.K. Mohamed, M. Shagufta and S.S. Hasan, Transition Met. Chem., 24, 577 (1999); doi:10.1023/A:1006900222831.
- S. Chandra and R. Kumar, Transition Met. Chem., 29, 269 (2004); doi:10.1023/B:TMCH.0000020359.84853.72.
- B.N. Figgis and J. Lewis, The Magnetochemistry of Chelates in Modern Coordination Chemistry, Interscience, New York (1960).
- D.P. Singh and R. Kumar, J. Serb. Chem. Soc., 72, 1069 (2007); doi:10.2298/JSC0711069S.
- A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, (1984).
- Z.H. Chohan, Mahmood-ul-Hassan, K.M. Khan and C.T. Supuran, J. Enzyme Inhib. Med. Chem., 20, 183 (2005); doi:10.1080/14756360500043257.
References
S. Ilhan and H. Temel, Transition Met. Chem., 32, 1039 (2007); doi:10.1007/s11243-007-0276-5.
W. Ma, Y.-P. Tian, S.-Y. Zhang, J.-Y. Wu, H.-K. Fun and S. Chantrapromma, Transition Met. Chem., 31, 97 (2006); doi:10.1007/s11243-005-6336-9.
D. Swallow, J.M. McInnes and P. Mountford, J. Chem. Soc., Dalton Trans., 2253 (1998); doi:10.1039/a802686f.
G. Cerchiaro and A.M.C. Ferreira, J. Braz. Chem. Soc., 17, 1473 (2006); doi:10.1590/S0103-50532006000800003.
I. Ahmad and A.J. Beg, J. Ethnopharmacol., 74, 113 (2001); doi:10.1016/S0378-8741(00)00335-4.
W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); doi:10.1016/S0010-8545(00)80009-0.
A.K. Singh, A. Panwar, R. Singh and S. Baniwal, Transition Met. Chem., 28, 160 (2003); doi:10.1023/A:1022916620211.
D.P. Singh, R. Kumar and P. Tyagi, Transition Met. Chem., 31, 970 (2006); doi:10.1007/s11243-006-0096-z.
D.P. Singh, N. Shishodia, B.P. Yadav and V.B. Rana, Polyhedron, 16, 2229 (1997); doi:10.1016/S0277-5387(96)00544-X.
S. Chandra and S.D. Sharma, Transition Met. Chem., 27, 732 (2002); doi:10.1023/A:1020309322470.
A. Chaudhary and R.V. Singh, Indian J. Chem., 43A, 2529 (2004).
K. Nakamoto, Infrared & Raman Spectra of Inorganic & Coordination Compounds, Part-B, Wiley Interscience Publication, edn. 5 (1997).
M. Shakir, O.S.M. Nasman and S.P. Varkey, Polyhedron, 15, 309 (1996); doi:10.1016/0277-5387(95)00189-Y.
D.P. Singh, V. Malik, R. Kumar, K. Kumar and J. Singh, Russ. J. Coord. Chem., 35, 740 (2009); doi:10.1134/S1070328409100054.
M. Shakir, K.S. Islam, A.K. Mohamed, M. Shagufta and S.S. Hasan, Transition Met. Chem., 24, 577 (1999); doi:10.1023/A:1006900222831.
S. Chandra and R. Kumar, Transition Met. Chem., 29, 269 (2004); doi:10.1023/B:TMCH.0000020359.84853.72.
B.N. Figgis and J. Lewis, The Magnetochemistry of Chelates in Modern Coordination Chemistry, Interscience, New York (1960).
D.P. Singh and R. Kumar, J. Serb. Chem. Soc., 72, 1069 (2007); doi:10.2298/JSC0711069S.
A.B.P. Lever, Inorganic Electronic Spectroscopy, Elsevier, Amsterdam, (1984).
Z.H. Chohan, Mahmood-ul-Hassan, K.M. Khan and C.T. Supuran, J. Enzyme Inhib. Med. Chem., 20, 183 (2005); doi:10.1080/14756360500043257.