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Vol. 26 No. 1 (2014): Vol 26 Issue 1

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Synthesis and Crystal Structure of Trinuclear Ni(II) Complex with 5-Methoxy-4'-bromo-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol

https://doi.org/10.14233/ajchem.2014.15867
Yu-Hua Yang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xin-Ying Zhang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Xiu-Yan Dong
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Gang Li
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China
Meng-Meng Zhao
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Xiu-Yan Dong

dxy568@163.com

Asian Journal of Chemistry, Vol. 26 No. 1 (2014): Vol 26 Issue 1

Abstract

A Ni(II) complex with 5-methoxy-4'-bromo-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H2L) has been synthesized, with the formula {[NiL(n-butanol)(μ-OAc)]2Ni}·n-butanol. The crystal of the Ni(II) complex belongs to triclinic, space group P-1 with cell dimensions a = 10.897(1) Å, b = 12.439(1) Å, c =12.518(1) Å and Z = 1. In the Ni(II) complex, there are three Ni(II) atoms, two deprotonated L2- moieties which provide N2O2 donors, two acetate anions, two coordinated and one non-coordinated n-butanol molecules, which result in the formation of a slightly distorted octahedral coordination geometry around each Ni(II) atom, respectively.

Keywords

Asymmetric Salamo-type ligand Ni(II) complex Synthesis Crystal structure
Yang, Y.-H., Zhang, X.-Y., Dong, X.-Y., Li, G., & Zhao, M.-M. (2013). Synthesis and Crystal Structure of Trinuclear Ni(II) Complex with 5-Methoxy-4’-bromo-2,2’-[ethylenedioxybis(nitrilomethylidyne)]diphenol. Asian Journal of Chemistry, 26(1), 269–272. https://doi.org/10.14233/ajchem.2014.15867
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