Simultaneous Determination of Mercury and Antimony in Lead-Base Alloys by Hydride Generation-Double Channel Atomic Fluorescence Spectrometry with Solid-phase Extraction Using Amberlite XAD-16 Resin Micro-column

Weina Zhang; Taicheng Duan

doi:10.14233/ajchem.2014.15704

Issue

Vol. 26 No. 1 (2014): Vol 26 Issue 1

Issue Published : December 26, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Simultaneous Determination of Mercury and Antimony in Lead-Base Alloys by Hydride Generation-Double Channel Atomic Fluorescence Spectrometry with Solid-phase Extraction Using Amberlite XAD-16 Resin Micro-column

https://doi.org/10.14233/ajchem.2014.15704

Weina Zhang

College of Chemistry, Jilin Normal University, Siping, P.R. China

Taicheng Duan

State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, P.R. China

Corresponding Author(s) : Weina Zhang

nana820616@yahoo.com.cn

Asian Journal of Chemistry, Vol. 26 No. 1 (2014): Vol 26 Issue 1
Article Published : December 26, 2013

Abstract

The simultaneous determination of inorganic mercury and antimony was evaluated by the application in lead-base alloys through solid-phase extraction (SPE) coupled with hydride generation-double channel atomic fluorescence spectrometry (HG-DC-AFS) using a separation/preconcentration step on an Amberlite XAD-16 resin packed column. The high selective SPE was based on the similar properties between non-polar resins and molecular covalent compounds e.g., HgBr₂ and SbBr₃ formed in concentrated H₂SO₄ and HBr media. Various experimental conditions affecting the solid-phase extraction and determination of the analytes had been investigated. Under the optimized conditions, the limits of detection of 0.17 μg L^-1 for Hg(II) and 1.66 μg L^-1 for Sb(III) were obtained. The precisions (RSD) for seven replicate measurements of 20 μg L^-1 Hg(II) and Sb(III) were 0.37 and 2.9 %, respectively. The developed method was validated by spike test and was applied to the separation/preconcentration of Hg and Sb from two lead-base alloys matrices.

Keywords

Hydride generation Solid-phase extraction Atomic fuorescence spectrometry XAD-16 resin

Zhang, W., & Duan, T. (2013). Simultaneous Determination of Mercury and Antimony in Lead-Base Alloys by Hydride Generation-Double Channel Atomic Fluorescence Spectrometry with Solid-phase Extraction Using Amberlite XAD-16 Resin Micro-column. Asian Journal of Chemistry, 26(1), 219–223. https://doi.org/10.14233/ajchem.2014.15704

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C.S. Zhou, Chemical Separation-Concentration and Their Application, Central South University of Technology Press, Changsha, p. 255 (1997).

M. Elsayed, E. Bjorn and W. Frech, J. Anal. At. Spectrom., 15, 697 (2000); doi:10.1039/a908635h.

L. Pszonicki and J. Dudek, J. Anal. At. Spectrom., 14, 1755 (1999); doi:10.1039/a905984i.

R.M. Camero and R.E. Sturgeon, Spectrochim. Acta, B, 54, 753 (1999); doi:10.1016/S0584-8547(98)00260-2.

C.M. Andrle, N. Jakubowski and J.A.C. Broekaert, Spectrochim. Acta B, 52, 189 (1997); doi:10.1016/S0584-8547(96)01586-8.

X.H. Shang and X.P. Yan, J. Anal. At. Spectrom., 22, 1284 (2007); doi:10.1039/b702675g.

V. Camel, Spectrochim. Acta, B, 58, 1177 (2003); doi:10.1016/S0584-8547(03)00072-7.

B.B. Chen, S.J. Heng, H.Y. Peng, B. Hu, X. Yu, Z. Zhang, D. Pang, X. Yue and Y. Zhu, J. Anal. At. Spectrom., 25, 1931 (2010); doi:10.1039/c0ja00003e.

L. Zhang, D. Ishi, K. Shitou, Y. Morita and A. Isozaki, Talanta, 68, 336 (2005); doi:10.1016/j.talanta.2005.08.072.

H. Wu, X.C. Wang, B. Liu, Y.L. Liu, S.S. Li, J.S. Lu, J.Y. Tian, W.F. Zhao and Z.H. Yang, Spectrochimi. Acta Part B, 66, 74 (2011); doi:10.1016/j.sab.2010.12.002.

H. Zheng, T.M. Geng and L.M. Hu, Chem. Anal., 53, 673 (2008).

S. Arpadjan, L. Vuchkova and E. Kostadinova, Analyst, 122, 243 (1997); doi:10.1039/a606917g. (London).

L. Vuchkova and S. Arpadjan, Talanta, 43, 479 (1996); doi:10.1016/0039-9140(95)01780-1.

Y.W. Liu, X.J. Chang, D. Yang, Y. Guo and S. Meng, Anal. Chim. Acta, 538, 85 (2005); doi:10.1016/j.aca.2005.02.017.

L. Elçi, M. Soylak, A. Uzun, E. Büyükpatır and M. Doğan, Fresenius J. Anal. Chem., 368, 358 (2000); doi:10.1007/s002160000448.

X.L. Liu, T.C. Duan, Y. Han, X.Y. Jia and H.T. Chen, J. Anal. At. Spectrom., 25, 206 (2010); doi:10.1039/b915054d.

Z.X. Li and Y.A. Guo, Talanta, 65, 1318 (2005); doi:10.1016/j.talanta.2004.09.021.

H. Wu, H.Y. Wen, B.P. Han, B.X. Du, J.S. Lu and J.Y. Tian, Mikrochim. Acta, 166, 41 (2009); doi:10.1007/s00604-009-0161-3.

M.L. Chen, Y.M. Huo and J.H. Wang, Talanta, 78, 88 (2009); doi:10.1016/j.talanta.2008.10.060.

A.N. Anthemidis and E.K. Martavaltzoglou, Anal. Chim. Acta, 573–574, 413 (2006); doi:10.1016/j.aca.2005.12.055.

X.P. Yan, X.B. Yin, X.W. He and Y. Jiang, Anal. Chem., 74, 2162 (2002); doi:10.1021/ac0157019.

H. Wu, Y. Jin, Y. Tian, X.C. Tao and S.P. Bi, At. Spectrosc., 28, 220 (2007).

Z.X. Li and Y.A. Guo, Talanta, 65, 1318 (2005); doi:10.1016/j.talanta.2004.09.021.

Z.X. Li, X.M. Yang, Y.A. Guo, H.T. Li and Y.H. Feng, Talanta, 74, 915 (2008); doi:10.1016/j.talanta.2007.07.028.

Issue

Vol. 26 No. 1 (2014): Vol 26 Issue 1

Simultaneous Determination of Mercury and Antimony in Lead-Base Alloys by Hydride Generation-Double Channel Atomic Fluorescence Spectrometry with Solid-phase Extraction Using Amberlite XAD-16 Resin Micro-column

Corresponding Author(s) : Weina Zhang

Abstract

Keywords

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