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Vol. 26 No. 24 (2014)

Copyright (c) 2014 Y.N. Zhang*, Y.J. Zhang, D. Li, L. Zhang, M. Yang, H. Liu

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Hydrothermal Syntheses and Crystal Structure of Hybrid Material Based on Keggin Cluster Modified by Nickel Complex

https://doi.org/10.14233/ajchem.2014.18521
Y.N. Zhang*
College of Pharmacy, Jiamusi University, Jiamusi 154007, Heilongjiang Province, P.R. China *Corresponding author: Tel/Fax: +86 454 8610678; E-mail: zhangyunan79@163.com
Y.J. Zhang
College of Pharmacy, Jiamusi University, Jiamusi 154007, Heilongjiang Province, P.R. China *Corresponding author: Tel/Fax: +86 454 8610678; E-mail: zhangyunan79@163.com
D. Li
College of Pharmacy, Jiamusi University, Jiamusi 154007, Heilongjiang Province, P.R. China *Corresponding author: Tel/Fax: +86 454 8610678; E-mail: zhangyunan79@163.com
L. Zhang
College of Pharmacy, Jiamusi University, Jiamusi 154007, Heilongjiang Province, P.R. China *Corresponding author: Tel/Fax: +86 454 8610678; E-mail: zhangyunan79@163.com
M. Yang
College of Pharmacy, Jiamusi University, Jiamusi 154007, Heilongjiang Province, P.R. China *Corresponding author: Tel/Fax: +86 454 8610678; E-mail: zhangyunan79@163.com
H. Liu
College of Pharmacy, Jiamusi University, Jiamusi 154007, Heilongjiang Province, P.R. China *Corresponding author: Tel/Fax: +86 454 8610678; E-mail: zhangyunan79@163.com

Corresponding Author(s) : Y.N. Zhang*

Asian Journal of Chemistry, Vol. 26 No. 24 (2014)

Abstract

A new organic-inorganic hybrid compound based on the Keggin polyoxometalates modified by nickel and N-ligand organic moiety: [Ni(phen)3]2[PMo11VIMoVO40] (1) (phen = 1,10-phenanthroline) has been hydrothermally synthesized and characterized structurally. It crystallizes in the triclinic space group P-1 with a = 12.203(2), b = 13.907(2), c = 14.438(3) Å; a = 104.859(2), b = 108.777(2), g = 93.376(2), V = 2215.3(7)Å3, C72H48N12O40PMo12Ni2, Mr = 3020.85, Z = 1, Dc = 2.264 g/cm3, m = 2.164 mm-1, F(000) = 1459, R = 0.0355 and wR = 0.0937 for 6948 observed reflections with I > 2s(I). The compound 1 consists of discrete polyoxoanions [PMo11VIMoVO40]4- and counter cations [Ni(phen)3]2+. The electrochemical property of compound 1 has been studied in the paper.

Keywords

Keggin structure Polyoxometalates Nickel Hydrothermal synthesis Electrochemical property.
Zhang*, Y., Zhang, Y., Li, D., Zhang, L., Yang, M., & Liu, H. (2014). Hydrothermal Syntheses and Crystal Structure of Hybrid Material Based on Keggin Cluster Modified by Nickel Complex. Asian Journal of Chemistry, 26(24), 8617–8620. https://doi.org/10.14233/ajchem.2014.18521
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