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Vol. 26 No. 24 (2014)

Copyright (c) 2014 Sami Klaib

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Synthesis and Crystal Structure of Diaquodiformatodi(4-methyl pyridine)copper(II)

https://doi.org/10.14233/ajchem.2014.18354
Sami Klaib
Department of Chemistry, Tafila Technical University, Tafila 66110, Jordan Corresponding author: E-mail: samiklaib@yahoo.com

Corresponding Author(s) : Sami Klaib

Asian Journal of Chemistry, Vol. 26 No. 24 (2014)

Abstract

Ternary complex i.e., diaquodiformatodi(4-methyl pyridine)copper(II) has been prepared and the solid state structure was determined using X-Ray structure analysis. The molecule crystallizes in monoclinic space group P21/c with a = 9.6070 (5) Å, b = 11.5441 (5) Å, c = 7.7163 (5) Å, a = 90, b = 98.045 (4), g = 90, V = 847.348 A3. The structural data are consistent with the presence of Jahn-Teller distortion in the overall hexacoordinate octahedral geometry of the molecule. The crystal packing is through an extensive hydrogen bonding and ring-ring p-p interactions resulting in a supra molecular frame work.

Keywords

Synthesis Crystal structure.
Klaib, S. (2014). Synthesis and Crystal Structure of Diaquodiformatodi(4-methyl pyridine)copper(II). Asian Journal of Chemistry, 26(24), 8566–8568. https://doi.org/10.14233/ajchem.2014.18354
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