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Copyright (c) 2014 Zhifeng Guo*, Xiaoxuan Zhang, Xiaoyang Wu, Jingjing Dong
This work is licensed under a Creative Commons Attribution 4.0 International License.
Application of Non-Newtonian Liquid Membranes to Extract Nicotine from Tobacco
Corresponding Author(s) : Zhifeng Guo*
Asian Journal of Chemistry,
Vol. 26 No. 24 (2014)
Abstract
In the present study, a stable emulsion liquid membrane was prepared through adding polystyrene in a membrane phase. The emulsion liquid membrane extraction system was composed by the membrane phase (kerosene, Span80 and polystyrene) and the strip phase (acidic aqueous solution). The feed phase was nicotine basic aqueous solution or tobacco extractant. A water-in-oil-in-water (abbreviated W/O/W) is formed as dispersing the emulsion liquid membrane with added polystyrene additive in the feed phase, which will be the non-Newtonian. Comparing with the emulsion liquid membranes without polystyrene, the emulsion liquid membranes with polystyrene extended the extraction time from 5 to 8 min, which illustrates that adding polystyrene helps improve the stability of emulsion liquid membranes. The application of using these emulsion liquid membranes for extraction nicotine from tobacco shows the extraction efficiency of nicotine is higher than using liquid-liquid extraction.
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- R. Pal, Ind. Eng. Chem. Res., 37, 2052 (1998).
- N.N. Li, US Patent 3410794 (1968).
- C.C. Chan and C.J. Lee, Chem. Eng. Sci., 42, 83 (1987).
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- R.S. Baird, A.L. Bunge and R.D. Noble, AIChE J., 33, 43 (1987).
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- J.M. Barad, M. Chakraborty and H.J. Bart, Ind. Eng. Chem. Res., 49, 5808 (2010).
- C.J. Lee and C.C. Chan, Ind. Eng. Chem. Res., 29, 96 (1990).
- E. Salazar, M.I. Ortiz, A.M. Urtiaga and J.A. Irabien, Ind. Eng. Chem. Res., 31, 1523 (1992).
- M. Chakraborty, C. Bhattacharya and S. Dutta, J. Membr. Sci., 220, 155 (2003).
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- E.A. Fouad and H.J. Bart, J. Membr. Sci., 307, 156 (2008).
- L. Longquan, J. Membr. Sci., 135, 173 (1997).
- K. Chakrabarty, P. Saha and A.K. Ghoshal, J. Membr. Sci., 360, 34 (2010).
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- K.J. Lissant, Emulsions and Emulsion Technology, Marcel Dekker, New York (1974).
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References
R. Pal, Ind. Eng. Chem. Res., 37, 2052 (1998).
N.N. Li, US Patent 3410794 (1968).
C.C. Chan and C.J. Lee, Chem. Eng. Sci., 42, 83 (1987).
S.C. Lee and H.C. Kim, J. Membr. Sci., 367, 190 (2011).
J.A. Tamada, A.S. Kertes and C.J. King, Ind. Eng. Chem. Res., 29, 1319 (1990).
S.C. Lee and K.S. Hyun, J. Membr. Sci., 350, 333 (2010).
J.Q. Shen, W.P. Yin, Y.X. Zhao and L.J. Yu, J. Membr. Sci., 120, 45 (1996).
M. Teramoto, H. Takihana, M. Shibutani, T. Yuasa, Y. Miyake and H. Teranishi, J. Chem. Eng. Jpn, 14, 122 (1981).
R.S. Baird, A.L. Bunge and R.D. Noble, AIChE J., 33, 43 (1987).
S. Datta, P.K. Bhattacharya and N. Velma, J. Membr. Sci., 226, 185 (2003).
J.M. Barad, M. Chakraborty and H.J. Bart, Ind. Eng. Chem. Res., 49, 5808 (2010).
C.J. Lee and C.C. Chan, Ind. Eng. Chem. Res., 29, 96 (1990).
E. Salazar, M.I. Ortiz, A.M. Urtiaga and J.A. Irabien, Ind. Eng. Chem. Res., 31, 1523 (1992).
M. Chakraborty, C. Bhattacharya and S. Dutta, J. Membr. Sci., 220, 155 (2003).
M. Gameiro, P. Bento, M. Ismael, M. Reis and J. Carvalho, J. Membr. Sci., 293, 151 (2007).
E.A. Fouad and H.J. Bart, J. Membr. Sci., 307, 156 (2008).
L. Longquan, J. Membr. Sci., 135, 173 (1997).
K. Chakrabarty, P. Saha and A.K. Ghoshal, J. Membr. Sci., 360, 34 (2010).
G.C. Sahoo and N.N. Dutta, J. Membr. Sci., 145, 15 (1998).
A.K. Agarwal, C. Das and S. De, J. Membr. Sci., 360, 190 (2010).
A. Dâas and O. Hamdaoui, J. Hazard. Mater., 178, 973 (2010).
A. Dâas and O. Hamdaoui, J. Membr. Sci., 348, 360 (2010).
W. Hou and K.D. Papadopoulos, Chem. Eng. Sci., 51, 5043 (1996).
M.T.A. Reis, O.M.F. de Freitas, L.M. Ferreira and J.M.R. Carvalho, J. Membr. Sci., 269, 161 (2006).
Y. Park, A.H.P. Skelland, L.J. Forney and J.H. Kim, Water Res., 40, 1763 (2006).
H.R. Mortaheb, M.H. Amini, F. Sadeghian, B. Mokhtarani and H. Daneshyar, J. Hazard. Mater., 160, 582 (2008).
J. Yan and R. Pal, J. Membr. Sci., 190, 79 (2001).
A.H.P. Skelland and X. (Michael) Meng, J. Membr. Sci., 158, 1 (1999).
J. Yan and R. Pal, J. Membr. Sci., 213, 1 (2003).
Y. Wan and X. Zhang, J. Membr. Sci., 196, 185 (2002).
Y. Wan, X. Wang, B. Zhu and X. Zhang, J. Membr. Sci., 184, 49 (2001).
J.W. Frankenfeld and N.N. Li, in ed.: in: R.W. Rousseau, Recent Advances in Liquid Membrane Technology, Handbook of Separation Process Technology, Wiley, New York (1987).
S. Tian, Z.F. Guo, X. Zhang and X. Wu, Anal. Methods, 5, 5179 (2013).
K.J. Lissant, Emulsions and Emulsion Technology, Marcel Dekker, New York (1974).
E.C. Hsu and N.N. Li, Sep. Sci. Technol., 20, 115 (1985).
G.J. Hanna and K.M. Larson, Ind. Eng. Chem. Prod. Des. Dev., 24, 269 (1985).
F. Nakashio, M. Goto, M. Matsumoto, J. Irie and K. Kondo, J. Membr. Sci., 38, 249 (1988).
A.B. Metzner, Nature, 208, 267 (1965).