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Copyright (c) 2014 Majid Muneer1, Ijaz A. Bhatti3, Nosheen Aslam2, Muhammad Asghar Jamal1, Muddassar Zafar4, Muhammad Kaleem Khosa1
This work is licensed under a Creative Commons Attribution 4.0 International License.
Oxidative Degradation of Reactive Violet 1 Dye by Ultraviolet Radiation in Presence of Hydrogen Peroxide
Corresponding Author(s) : Majid Muneer1
Asian Journal of Chemistry,
Vol. 26 No. 24 (2014)
Abstract
Degradation of synthetic dye reactive violet 1 in aqueous media having concentrations 10-50 mg/L has been carried out by UV radiation in presence of H2O2. The change in colour intensity at lmax 545 nm and chemical oxygen demand reduction was examined to evaluate the decrease in organic matter. The decrease in colour intensity was found 18, 25 and 100 % while chemical oxygen demand reduction up to 15, 25 and 55 % when solutions were treated by UV, H2O2 and UV/H2O2, respectively. The radiolytic end products were identified by FTIR and GC-MS, which revealed that advanced oxidation process had achieved the complete mineralization. The effect of different operational parameters such as initial dye concentration, UV irradiation time and concentration of hydrogen peroxide on degradation efficiency has also been evaluated. This treatment can be extended to dye containing industrial wastewater.
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- E. Balanoskyand, F. Herrera, A. Lopez and J. Kiwi, Water Res., 34, 582 (2000).
- M. Vautier, C. Guillard and J.M. Herrmann, J. Catal., 201, 46 (2001).
- E. Rodriguez, R. Peche, J.M. Merino and L.M. Camarero, Environ. Eng. Sci., 24, 363 (2007).
- N. Daneshvar, M. Rabbani, N. Modirshahla and M.A. Behnajadya, Radiat. Phys. Chem., B118, 155 (2005).
- M. Behnajady, A.N. Modirshahla and H. Fathi, J. Hazard. Mater., B136, 816 (2006).
- M. Sanchez, H. Wolfger and N. Getoff, Radiat. Phys. Chem., 65, 611 (2002).
- A.S. Ozen, V. Aviyente and R.A. Klein, J. Phys. Chem. A, 107, 4898 (2003).
- H.Y. Shu and M.C. Chang, Dyes Pigm., 70, 31 (2006).
- A. Uygur and E. Kok, J. Soc. Dyers Colour., 115, 350 (1999).
- A. Uygur, Color. Technol., 117, 111 (2001).
- C.R. Huang and H.Y. Shu, J. Hazard. Mater., 41, 47 (1995).
- G.M. Colonna, T. Caronna and B. Marcandalli, Dyes Pigments, 41, 211 (1999).
- I.A. Alaton, I.A. Balcioglu and D.W. Bahnemann, Water Res., 36, 1143 (2002).
- S. Esplugas, J. Gimenez, S. Contreras, E. Pascual and M. Rodriguez, Water Res., 36, 1034 (2002).
- A. Aleboyeh, Y. Moussa and H. Aleboyeh, Dyes Pigments, 66, 129 (2005).
- E. Rodriguez, R. Peche, J.M. Merino and L.M. Camarero, Environ. Eng. Sci., 24, 363 (2007).
- M. Muneer, I.A. Bhatti, M. Iqbal and M. Ather, J. Chem. Soc. Pak., 34, 787 (2012).
- C. Hu, J.C. Yu, Z. Hao and P.K. Wong, Appl. Catal. B, 42, 47 (2003).
References
E. Balanoskyand, F. Herrera, A. Lopez and J. Kiwi, Water Res., 34, 582 (2000).
M. Vautier, C. Guillard and J.M. Herrmann, J. Catal., 201, 46 (2001).
E. Rodriguez, R. Peche, J.M. Merino and L.M. Camarero, Environ. Eng. Sci., 24, 363 (2007).
N. Daneshvar, M. Rabbani, N. Modirshahla and M.A. Behnajadya, Radiat. Phys. Chem., B118, 155 (2005).
M. Behnajady, A.N. Modirshahla and H. Fathi, J. Hazard. Mater., B136, 816 (2006).
M. Sanchez, H. Wolfger and N. Getoff, Radiat. Phys. Chem., 65, 611 (2002).
A.S. Ozen, V. Aviyente and R.A. Klein, J. Phys. Chem. A, 107, 4898 (2003).
H.Y. Shu and M.C. Chang, Dyes Pigm., 70, 31 (2006).
A. Uygur and E. Kok, J. Soc. Dyers Colour., 115, 350 (1999).
A. Uygur, Color. Technol., 117, 111 (2001).
C.R. Huang and H.Y. Shu, J. Hazard. Mater., 41, 47 (1995).
G.M. Colonna, T. Caronna and B. Marcandalli, Dyes Pigments, 41, 211 (1999).
I.A. Alaton, I.A. Balcioglu and D.W. Bahnemann, Water Res., 36, 1143 (2002).
S. Esplugas, J. Gimenez, S. Contreras, E. Pascual and M. Rodriguez, Water Res., 36, 1034 (2002).
A. Aleboyeh, Y. Moussa and H. Aleboyeh, Dyes Pigments, 66, 129 (2005).
E. Rodriguez, R. Peche, J.M. Merino and L.M. Camarero, Environ. Eng. Sci., 24, 363 (2007).
M. Muneer, I.A. Bhatti, M. Iqbal and M. Ather, J. Chem. Soc. Pak., 34, 787 (2012).
C. Hu, J.C. Yu, Z. Hao and P.K. Wong, Appl. Catal. B, 42, 47 (2003).