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Copyright (c) 2014 Y.M. Al-Angari1, M.A. Gabal1, F.A. Al-Agel2
This work is licensed under a Creative Commons Attribution 4.0 International License.
Characterization of Zn-Substituted Nano-Sized CoAl2O4 Powder Synthesized by Egg-White Method
Corresponding Author(s) : Y.M. Al-Angari1
Asian Journal of Chemistry,
Vol. 26 No. 24 (2014)
Abstract
In the present study, a simple and environmental friendly egg-white was utilized for the preparation of nano-crystalline Co0.5Zn0.5Al2O4. The decomposition process of the precursor was followed through TG measurement. XRD, FT-IR and TEM techniques to characterize the produced aluminate. The obtained XRD pattern indicates the formation of single-phase cubic structure. FT-IR exhibited two characteristic bands of aluminate structure. TEM image showed cubic agglomerated particles with an average size of about 20 nm. Ac-conductivity measurements indicates the semiconducting properties of the obtained aluminate with room temperature conductivity of 3.4 × 10-4 W-1 cm-1.
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References
D. Visinescu, C. Paraschiv, A. Ianculescu, B. Jurca, B. Vasile and O. Carp, Dyes Pigments, 87, 125 (2010).
W. Li, J. Li and J. Guo, J. Eur. Ceram. Soc., 23, 2289 (2003).
P. Thormählen, E. Fridell, N. Cruise, M. Skoglundh and A. Palmqvist, Appl. Catal. B, 31, 1 (2001).
D.M.A. Melo, J.D. Cunha, J.D.G. Fernandes, M.I. Bernardi, M.A.F. Melo and A.E. Martinelli, Mater. Res. Bull., 38, 1559 (2003).
T. Suzuki, H. Nagai, M. Nohara and H. Takagi, J. Phys. Condens. Matter, 19, 145265 (2007).
D. Rangappa, S. Ohara, T. Naka, A. Kondo, M. Ishii and T. Adschiri, J. Mater. Chem., 17, 4426 (2007).
Z.Z. Chen, E.W. Shi, Y.Q. Zheng, B. Xiao and J.Y. Zhuang, J. Am. Ceram. Soc., 86, 1058 (2003).
L. Desouza, J. Zamian, G. Darochafilho, L. Soledade, I. Dossantos, A. Souza, T. Scheller, R. Angelica and C. Dacosta, Dyes Pigments, 81, 187 (2009).
C. Suciu, I. Mindru, G. Marinescu, L. Patron, O. Carp and V.S. Teodorescu, J. Optoelectron. Adv. Mater., 10, 2703 (2008).
C. Wang, S. Liu, L. Liu and X. Bai, Mater. Chem. Phys., 96, 361 (2006).
R.K. Mason, Bull. Am. Ceram. Soc., 40, 5 (1961).
M.N. Barroso, M.F. Gomez, L.A. Arrúa and M.C. Abello, Chem. Eng. J., 158, 225 (2010).
M.A. Gabal, Mater. Lett., 64, 1887 (2010).
M.A. Gabal, A.M. Asiri and Y.M. Al Angari, Ceram. Int., 37, 2625 (2011).
M.A. Gabal, R.M. El-Shishtawy and Y.M. Al Angari, J. Magn. Magn. Mater., 324, 2258 (2012).
B. Ismail, S.T. Hussain and S. Akram, Chem. Eng. J., 219, 395 (2013).
D. Dhak and P. Pramanik, J. Am. Ceram. Soc., 89, 1014 (2006).
K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compound, Chemical Industry Press, Beijing, edn 4 (1991).
L.K.C. de Souza, J.R. Zamian, G.N. da Rocha Filho, L.E.B. Soledade, I.M.G. dos Santos, A.G. Souza, T. Scheller, R.S. Angélica and C.E.F. da Costa, Dyes Pigments, 81, 187 (2009).
M. Zawadzki, W. Staszak, F.E. Lopez-Suarez, M.J. Illan-Gomez and A. Bueno-Lopez, App. Catal. A, 371, 92 (2009).
Z. Chen, E. Shi, W. Li, Y. Zheng and W. Zhong, Mater. Lett., 55, 281 (2002).
M.A. Gabal, J. Magn. Magn. Mater., 321, 3144 (2009).
A.K. Nikumbh, R.A. Pawar, D.V. Nighot, G.S. Gugale, M.D. Sangale, M.B. Khanvilkar and A.V. Nagawade, J. Magn. Magn. Mater., 355, 201 (2014).
M.A. Dar, K.M. Batoo, V. Verma, W.A. Siddiqui and R.K. Kotnala, J. Alloys Comp., 493, 553 (2010).