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Vol. 26 No. 23 (2014)

Copyright (c) 2014 Jun-Long Lu, Jian-Wei Xie*, Hai-Yue Liu, Ping Liu, Zhi-Yong Liu, Bin Dai*

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Strontium Chloride Modified Nieuwland Catalyst in the Dimerization of Acetylene to Monovinylacetylene

https://doi.org/10.14233/ajchem.2014.17994
Jun-Long Lu
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, North 4th Road, Shihezi 832003, P.R. China *Corresponding authors: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: cesxjw@gmail.com
Jian-Wei Xie*
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, North 4th Road, Shihezi 832003, P.R. China *Corresponding authors: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: cesxjw@gmail.com
Hai-Yue Liu
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, North 4th Road, Shihezi 832003, P.R. China *Corresponding authors: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: cesxjw@gmail.com
Ping Liu
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, North 4th Road, Shihezi 832003, P.R. China *Corresponding authors: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: cesxjw@gmail.com
Zhi-Yong Liu
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, North 4th Road, Shihezi 832003, P.R. China *Corresponding authors: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: cesxjw@gmail.com
Bin Dai*
School of Chemistry and Chemical Engineering/Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, North 4th Road, Shihezi 832003, P.R. China *Corresponding authors: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: cesxjw@gmail.com

Corresponding Author(s) : Jun-Long Lu

Asian Journal of Chemistry, Vol. 26 No. 23 (2014)

Abstract

SrCl2 was used as a co-catalyst of CuCl in Nieuwland catalyst and CuCl as the main catalyst, NH4Cl as the solubilizer, water as the solvent and a certain amount of hydrochloric acid, thereby forming Sr-Cu bimetallic cooperative catalysis reaction systems for C2H2 dimerization. Under the optimum condition, the acetylene conversion is 13 % and monovinylacetylene selectivity can reach to 94 %.

Keywords

Strontium chloride Nieuwland catalyst Acetylene dimerization Monovinylacetylene.
Lu, J.-L., Xie*, J.-W., Liu, H.-Y., Liu, P., Liu, Z.-Y., & Dai*, B. (2014). Strontium Chloride Modified Nieuwland Catalyst in the Dimerization of Acetylene to Monovinylacetylene. Asian Journal of Chemistry, 26(23), 8211–8214. https://doi.org/10.14233/ajchem.2014.17994
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References
  1. E. Bridgewater, Ind. Eng. Chem., 32, 1155 (1940).
  2. J. Liu, M. Han, Y. Zuo and Z. Wang, Chem. Ind. Eng. Prog., 30, 942 (2011) (in Chinese).
  3. K.I. Nishiwaki, M. Kobayashi, T. Takeuchi, K. Matuoto and K. Osakada, J. Mol. Catal. Chem., 175, 73 (2001).
  4. O.V. Pavlyuk, B.M. Mykhalichko and M.G. Mys'kiv, Russ. J. Coord. Chem., 30, 159 (2004).
  5. Y. Tokita, A. Okamoto, K. Nishiwaki, M. Kobayashi and E. Nakamura, Bull. Chem. Soc. Jpn., 77, 1395 (2004).
  6. J. Liu, Y. Zuo, M. Han, Z. Wang and D. Wang, J. Nat. Gas Chem., 21, 495 (2012).
  7. J. Liu, Y. Zuo, M. Han and Z. Wang, J. Chem. Technol. Biotechnol., 88, 408 (2013).
  8. J. Liu, M. Han and Z. Wang, J. Energ. Chem., 22, 599 (2013).
  9. Z. Liu, Y. Yu, C. Tao, J. Du, R. Liu, X. Fan, M. Peng, D. Sun, Z. Zuo, J. Ma, Z. Xie and Z. Li, CN Patent 102775266A (2012).
  10. Z. Liu, Y. Yu, C. Tao, J. Du, R. Liu, X. Fan, M. Peng, D. Sun, Z. Zuo, J. Ma, Z. Xie and Z. Li, CN Patent 102731241A (2012).
  11. J. Du, Z. Liu and C. Tao, CN Patent 102964198A (2013).
  12. T. Tachiyama, M. Yoshida, T. Aoyagi and S. Fukuzumi, Chem. Lett., 37, 38 (2008).
  13. T. Tachiyama, M. Yoshida, T. Aoyagi and S. Fukuzumi, J. Phys. Org. Chem., 21, 510 (2008).
  14. T. Tachiyama, M. Yoshida, T. Aoyagi and S. Fukuzumi, Appl. Organomet. Chem., 22, 205 (2008).
  15. Z. Liu, Y. Yu, J. Du, X. Fan and C. Tao, J. Chem. Ind. Eng., 65, 1260 (2014) (in Chinese).
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