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Copyright (c) 2014 Xiaoniu Yu1, Chunxiang Qian1, Xin Wang1
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis of Barium Hydrogen Phosphate by Biomimetic Method in Beef Extract and Typtone Matrix
Corresponding Author(s) : Xiaoniu Yu1
Asian Journal of Chemistry,
Vol. 26 No. 23 (2014)
Abstract
Barium hydrogen phosphate precipitate was induced using organic templates. The structure, morphology, size and thermal properties of the precipitates were characterized by energy dispersive X-ray spectroscopy, X-ray techniques, scanning electron microscope, particle size analyzer, thermogravimetric-differential scanning calorimetry analysis. Particle size analyzer furnish evidence for the formation of BaHPO4 with average crystallite size 11.99 and 30.47 μm. Thermogravimetric-differential scanning calorimetry curves showed that barium hydrogen phosphate precipitate induced in pure water was more thermal stability than one induced in organic templates. The results display that organic matrix play an important roles in the process of crystal nucleation, growth and accumulation of barium hydrogen phosphate.
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References
S. Mann, Nature, 332, 119 (1988).
X.R. Xu, J.T. Han and K. Cho, Chem. Mater., 16, 1740 (2004).
F. Wang, G.Y. Xu and Z.Q. Zhang, Mater. Lett., 59, 808 (2005).
Y.F. Ma, L. Qiao and Q.L. Feng, Mater. Sci. Eng. C, 32, 1963 (2012).
Y. Yao, D. Wang, L. Han and S.N. Che, Chem. Eur. J., 19, 15489 (2013).
X.D. Zhang, W. He, Y.Z. Yue, R.M. Wang, J.X. Shen, S.J. Liu, J.Y. Ma, M. Li and F.X. Xu, J. Mater. Chem., 22, 19948 (2012).
J.P. Xie, J.Y. Lee and D.I.C. Wang, J. Phys. Chem. C, 111, 10226 (2007).
D.Z. Qin, L. Zhang, G.X. He and Q.X. Zhang, Mater. Res. Bull., 48, 3644 (2013).
J. Chen, Y.F. Kong, J.J. Ji, J. Ruan, K. Wang, F. Gao and D.X. Cui, Nanoscale, 4, 4455 (2012).
S. Mann, B.R. Heywood, S. Rajam and J.D. Birchall, Nature, 334, 692 (1988).
J. Lin, E. Cates and P.A. Bianconi, J. Am. Chem. Soc., 116, 4738 (1994).
S.K. Arora, A.T. Oza, T.R. Trivedi and V.A. Patel, Mater. Sci. Eng. B, 77, 131 (2000).
T.R. Trivedi, A.T. Oza, V.A. Patel and S.K. Arora, Cryst. Res. Technol., 35, 615 (2000).
D. Nallamuthu, P. Selvarajan and T.H. Freeda, Physica B, 405, 4908 (2010).
Y.G. Chen, B.L. Luan, G.L. Song, Q. Yang, D.M. Kingston and F. Bensebaa, Surf. Coat. Technol., 210, 156 (2012).