Issue

Vol. 26 No. 23 (2014)

Copyright (c) 2014 L. Zhao*, P. Wang, Q. Cheng, H.-X. Guo, X.-L. Yan

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization and Crystal Structure of New Oxime-Type Mononuclear Nickel(II) Complex with 1-[4-((E)-4-Methoxyl-2-hydroxybenzylidene)]oxime

https://doi.org/10.14233/ajchem.2014.17563
L. Zhao*
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
P. Wang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
Q. Cheng
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
H.-X. Guo
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
X.-L. Yan
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com

Corresponding Author(s) : L. Zhao*

Asian Journal of Chemistry, Vol. 26 No. 23 (2014)

Abstract

A new Ni(II) complex, [Ni(L)2], has been synthesized via the complexation of nickel(II) acetate monohydrate with a new oxime-type ligand (HL =1-[4-((E)-4-methoxyl-2-hydroxybenzylidene)]oxime). X-ray crystal structure determination of the Ni(II) complex shows that the Ni(II) complex is mononuclear, the Ni(II) atom is four-coordinated by the phenolate O atoms and imine N atoms from two deprotonated oxime-type ligands L-, in a square-planar geometry.

Keywords

Oxime-type compound Synthesis Crystal structure.
Zhao*, L., Wang, P., Cheng, Q., Guo, H.-X., & Yan, X.-L. (2014). Synthesis and Characterization and Crystal Structure of New Oxime-Type Mononuclear Nickel(II) Complex with 1-[4-((E)-4-Methoxyl-2-hydroxybenzylidene)]oxime. Asian Journal of Chemistry, 26(23), 8107–8109. https://doi.org/10.14233/ajchem.2014.17563
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. S.S. Sun, C.L. Stern, S.T. Nguyen and J.T. Hupp, J. Am. Chem. Soc., 126, 6314 (2004).
  2. (a) W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); (b) W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch, 67b, 197 (2012); (c) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); (d) W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); (e) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); (f) W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); (g) W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013).
  3. S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002).
  4. D.A. Atwood and M.J. Harvey, Chem. Rev., 101, 37 (2001).
  5. W.K. Dong, G. Wang, S.S. Gong, J.F. Tong, Y.X. Sun and X.H. Gao, Transit. Met. Chem., 37, 271 (2012).
  6. P.A.N. Reddy, R. Datta and A.R. Chakravarty, Inorg. Chem. Commun., 3, 322 (2000).
  7. M.S. Ray, R. Bhattacharya, S. Chaudhuri, L. Righi, G. Bocelli, G. Mukhopadhyay and A. Ghosh, Polyhedron, 22, 617 (2003).
  8. V.H. Kulkarni, B.R. Patil and B.K. Prabhakar, J. Inorg. Nucl. Chem., 43, 17 (1981).
  9. M. Asadi, K.A. Jamshid and A.H. Kyanfar, Inorg. Chim. Acta, 360, 1725 (2007).
  10. S. Akine, Y. Morita, F. Utsuno and T. Nabeshima, Inorg. Chem., 48, 10670 (2009).
Read More
Author biographies is not available.
Download
Statistic
Read Counter : 0