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Vol. 26 No. 23 (2014)

Copyright (c) 2014 L. Zhao*, X.-L. Yan, P. Wang, Q. Cheng, H.-X. Guo

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Synthesis, Characterization and Crystal Structure of 1-(4-{[(E)-4-Methoxyl-2- hydroxybenzylidene]amino}phenyl)ethanone Oxime and Its Copper(II) Complex

https://doi.org/10.14233/ajchem.2014.17378
L. Zhao*
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
X.-L. Yan
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
P. Wang
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
Q. Cheng
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com
H.-X. Guo
School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China *Corresponding author: E-mail: zhaoli_72@163.com

Corresponding Author(s) : L. Zhao*

Asian Journal of Chemistry, Vol. 26 No. 23 (2014)

Abstract

A new Cu(II) complex, [Cu(L)2], has been synthesized via the complexation of copper(II) acetate monohydrate with a new oxime-type ligand (HL = 1-(4-{[(E)-4-methoxyl-2- hydroxybenzylidene]amino}phenyl)ethanone oxime). X-ray crystal structure determination of the Cu(II) complex shows that is a mononuclear complex. The Cu(II) atom is four-coordinated by the phenolate O atoms and imine N atoms from two deprotonated oxime-type ligands, in a slightly distorted square-planar geometry. The O- and N-donor atoms are mutually trans and the dihedral angle between the two coordination planes (Cu1N2O2 and Cu1O2N2) is 36.49 (3)º. In the crystal structure, each molecule links two other adjacent molecules into an infinite one-dimensional supramolecular structure along the b axis through intermolecular O1-H1···O2 hydrogen bonds and C16-H16B···O1 hydrogen bonds.

Keywords

Oxime-type ligand Cu(II) complex Synthesis Crystal structure Thermal property.
Zhao*, L., Yan, X.-L., Wang, P., Cheng, Q., & Guo, H.-X. (2014). Synthesis, Characterization and Crystal Structure of 1-(4-{[(E)-4-Methoxyl-2- hydroxybenzylidene]amino}phenyl)ethanone Oxime and Its Copper(II) Complex. Asian Journal of Chemistry, 26(23), 8098–8100. https://doi.org/10.14233/ajchem.2014.17378
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References
  1. C. Adhikary, R. Sen, G. Bocelli, A. Cantoni, M. Solzi, S. Chaudhuri and S. Koner, J. Coord. Chem., 62, 3573 (2009).
  2. M. Rajasekar, R. Sreedaran, R. Prabu, V. Narayanan, R. Jegadeesh,
  3. N. Raaman and A. Kalilur Rahiman, J. Coord. Chem., 63, 136 (2010).
  4. D.D. Qin, Z.Y. Yang, F.H. Zhang, B. Du, P. Wang and T.R. Li, Inorg. Chem. Commun., 13, 727 (2010).
  5. Y.L. Sang and X.S. Lin, J. Coord. Chem., 63, 315 (2010).
  6. J.M. Xiao and W. Zhang, Inorg. Chem. Commun., 12, 1175 (2009).
  7. W.K. Dong, J.G. Duan and G.L. Liu, Transition Met. Chem., 32, 702 (2007).
  8. W.K. Dong and Y.J. Ding, Cryst. Res. Technol., 43, 321 (2008).
  9. M.T.H. Tarafder, K.T. Jin, K.A. Crouse, A.M. Ali, B.M. Yamin and H.K. Fun, Polyhedron, 21, 2547 (2002).
  10. G.T. Musie, X. Li and D.R. Powell, Inorg. Chim. Acta, 348, 69 (2003).
  11. P. A.N. Reddy, R. Datta and A. R. Chakravarty, Inorg. Chem. Commun., 3, 322 (2000).
  12. M.S. Ray, R.B. Bhattacharya, S. Chaudhuri, L. Righi, G. Bocelli,
  13. G. Mukhopadhyay and A. Ghosh, Polyhedron, 22, 617 (2003).
  14. C.P. Raptopoulou, A.N. Papadopoulos, D.A. Malamatari, E. Ioannidis, G. Moisidis, A. Terzis and D.P. Kessissoglou, Inorg. Chim. Acta, 272, 283 (1998).
  15. P.J. Arnold, S.C. Davies, M.C. Durrant, D.V. Griffiths, D.L. Hughes and P.C. Sharpe, Inorg. Chim. Acta, 348, 143 (2003).
  16. L. Zhao and S.W. Ng, Acta Crystallogr., E66, o2474 (2010).
  17. L. Zhao and S.W. Ng, Acta Crystallogr., E66, o2473 (2010).
  18. W.K. Dong, S.S. Gong, J.F. Tong, Y.X. Sun and J.C. Wu, Chinese J. Inorg. Chem., 26, 1868 (2010).
  19. W.K. Dong, X.L. Tang, X.N. He, C.Y. Zhao, H.B. Yan and T.Z. Yu, Chinese J. Inorg. Chem., 25, 528 (2009).
  20. W.K. Dong, J.H. Feng and X.Q. Yang, Synth. React. Inorg. Met-Org. Nano-Met.Chem, 37, 189 (2007).
  21. W.K. Dong, Y. Wang, J.C. Wu and S.T. Zhang, Acta Crystallogr., E67, m91 (2011).
  22. V.H. Kulkarni, B.R. Patil and B.K. Prabhakar, J. Inorg. Nucl. Chem., 43, 17 (1981).
  23. M. Asadi, K.A. Jamshid and A.H. Kyanfar, Inorg. Chim. Acta, 360, 1725 (2007).
  24. W.K. Dong and J.G. Duan, J. Coord. Chem., 61, 781 (2008).
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