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Vol. 26 No. 23 (2014)

Copyright (c) 2014 Y. Liu, X.W. Ma, P. Liu*, J.W. Xie, B. Dai

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Synthesis of 4-Vinylbiphenyl Derivatives by Pd(II)-1,2-Diamino-cyclohexane Complex Catalyzed Suzuki-Miyaura Reaction

https://doi.org/10.14233/ajchem.2014.16972
Y. Liu
School of Chemistry and Chemical Engineering/the Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi City, P.R. China *Corresponding author: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: liuping1979112@aliyun.com
X.W. Ma
School of Chemistry and Chemical Engineering/the Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi City, P.R. China *Corresponding author: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: liuping1979112@aliyun.com
P. Liu*
School of Chemistry and Chemical Engineering/the Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi City, P.R. China *Corresponding author: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: liuping1979112@aliyun.com
J.W. Xie
School of Chemistry and Chemical Engineering/the Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi City, P.R. China *Corresponding author: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: liuping1979112@aliyun.com
B. Dai
School of Chemistry and Chemical Engineering/the Key Laboratory for Green Processing of Chemical Engineering of Xinjiang Bingtuan, Shihezi University, Shihezi City, P.R. China *Corresponding author: Fax: +86 993 2057270; Tel: +86 993 2057213; E-mail: liuping1979112@aliyun.com

Corresponding Author(s) : Y. Liu

Asian Journal of Chemistry, Vol. 26 No. 23 (2014)

Abstract

A series of 4-vinylbiphenyl derivatives were synthesized by Pd(II)-1,2-diaminocyclohexane complex catalyzed Suzuki-Miyaura reactions in the presence of K3PO4·3H2O as base in toluene at 80 °C and the corresponding products achieved 39-95 % yields. According to this efficient C-C bond-forming method, the obtained yields of 4-vinylbiphenyl liquid crystal compounds were up to 89 %.

Keywords

4-Vinylbiphenyl derivatives Synthesis Suzuki-Miyaura reaction Palladium Catalyzed.
Liu, Y., Ma, X., Liu*, P., Xie, J., & Dai, B. (2014). Synthesis of 4-Vinylbiphenyl Derivatives by Pd(II)-1,2-Diamino-cyclohexane Complex Catalyzed Suzuki-Miyaura Reaction. Asian Journal of Chemistry, 26(23), 8022–8024. https://doi.org/10.14233/ajchem.2014.16972
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