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Copyright (c) 2014 Li Yang1, Guoxi Xi1, Tianjun Lou2, Guangri Xu2
This work is licensed under a Creative Commons Attribution 4.0 International License.
Measurement and Analysis of Metal Element Contents in Lithium Battery Separator by ICP-OES
Corresponding Author(s) : Li Yang1
Asian Journal of Chemistry,
Vol. 26 No. 23 (2014)
Abstract
This work presents a quantitative method for determining metal contents by inductively coupled plasma optical emission spectrometer (ICP-OES) in lithium battery separator. For comparison, common drying ash and microwave digestion methods were also studied. The parameters of microwave digestion and ICP-OES were optimized, the accuracy and precision of methods was confirmed by spike and recovery experiments. Concentrations of zinc, iron, magnesium, calcium, copper, sodium, manganese, lead and cadmium were measured. The results indicated that the order of the levels of metal element in the two samples was Ca > Na > Mg > Fe > Mn, Pb, Cr in lithium battery separator, the contents of Ca and Na were the highest, Mg and Fe were the second, Cu and Zn contents were the lowest.
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References
P. Arora and Z. Zhang, Chem. Rev., 104, 4419 (2004).
W.H. Seol, Y.M. Lee and J.-K. Park, J. Power Sources, 163, 247 (2006).
H. Li, Y.M. Chen, X.T. Ma, J.L. Shi, B.K. Zhu and L.P. Zhu, J. Membr. Sci., 379, 397 (2011).
T.H. Cho, M. Tanaka, H. Ohnishi, Y. Kondo, M. Yoshikazu, T. Nakamura, T. Sakai and T. Sakai, J. Power Sources, 195, 4272 (2011).
J.Y. Kim and D.Y. Lim, Energies, 3, 866 (2010).
D. Djian, F. Alloin, S. Martinet and H. Lignier, J. Power Sources, 187, 575 (2009).
V. De Luca, P. Digiamberardino, G. Di Pasquale, S. Graziani, A. Pollicino, E. Umana and M.G. Xibilia, J. Polym. Sci., B, Polym. Phys., 51, 699 (2013).
L. Ren, L. Wang, H. An and F. Zhang, Rare Metals, 26, 591 (2007).
X. Zhang, L. Ji, O. Toprakci, Y. Liang and M. Alcoutlabi, Polym. Rev., 51, 239 (2011).
C. J. Orendorff, The Electrochemical Society Interface, Summer, 61 (2012).
K. Ghanemi, Y. Nikpour, O. Omidvar and A. Maryamabadi, Talanta, 85, 763 (2011).
D. Citak and M. Tuzen, Food Chem. Toxicol., 48, 1399 (2010).
S. Nazari, J. Hazard. Mater., 165, 200 (2009).
M.M. Rahman, S.B. Khan, H.M. Marwani, A.M. Asiri and K.A. Alamry, Chem. Cent. J., 6, 158 (2012).
M. Banno, E. Tamiya and Y. Takamura, Anal. Chim. Acta, 634, 153 (2009).
L. Yang, Q.H. Yan, Y.P. Cao and H.R. Zhang, E-J. Chem., 9, 93 (2012).
L. Balcaen, L. Moens and F. Vanhaecke, Spectrochim. Acta B, 65, 769 (2009).
Z. Xing, J. Wang, G. Han, B. Kuermaiti, S. Zhang and X. Zhang, Anal. Chem., 82, 5872 (2010).
E.P. Nardi, F.S. Evangelista, L. Tormen, T.D.S. Pierre, A.J. Curtius, S.S. de Souza and F. Barbosa Jr, Food Chem., 112, 727 (2009).