Synthesis of Polyaniline Composites with Grinded Leaves of Polyalthia longifolia, Syzygium cumini, Alstonia scholaris and Madhuca longifolia and Study of Their Structural, Electrical and Dielectric Properties

Farah Kanwal; Aisha Batool; Sadia Rasool; Shahzad Naseem; Rabia Rehman

doi:10.14233/ajchem.2014.16649

Issue

Vol. 26 No. 22 (2014): Vol 26 Issue 22

Issue Published : November 6, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis of Polyaniline Composites with Grinded Leaves of Polyalthia longifolia, Syzygium cumini, Alstonia scholaris and Madhuca longifolia and Study of Their Structural, Electrical and Dielectric Properties

https://doi.org/10.14233/ajchem.2014.16649

Farah Kanwal

Institute of Chemistry, University of the Punjab, Lahore, Pakistan

Aisha Batool

Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, Pakistan

Sadia Rasool

Institute of Chemistry, University of the Punjab, Lahore, Pakistan

Shahzad Naseem

Centre of Excellence in Solid State Physics, University of the Punjab, Lahore, Pakistan

Rabia Rehman

Institute of Chemistry, University of the Punjab, Lahore, Pakistan

Corresponding Author(s) : Farah Kanwal

farahkchem@yahoo.com

Asian Journal of Chemistry, Vol. 26 No. 22 (2014): Vol 26 Issue 22
Article Published : November 6, 2014

Abstract

Polyaniline composites has successfully been synthesized with well grinded leaves of Polyalthia longifolia, Syzygium cumini, Madhuca longifolia and Alstonia scholaris in an acidic medium by chemical oxidation method at room temperature. Fourier transform infrared (FT-IR) spectroscopy confirmed the formation of composites. All prepared samples were characterized for their electrical and dielectric properties. Polyaniline/Polyalthia longifolia composite offer enhanced dielectric properties with dielectric constant four times greater than pure polyaniline, suitable for its application as passivation layer for thin film transistor.

Keywords

Polyaniline Grinded leaves powder Composites AC conductivity Dielectric constant

Kanwal, F., Batool, A., Rasool, S., Naseem, S., & Rehman, R. (2014). Synthesis of Polyaniline Composites with Grinded Leaves of Polyalthia longifolia, Syzygium cumini, Alstonia scholaris and Madhuca longifolia and Study of Their Structural, Electrical and Dielectric Properties. Asian Journal of Chemistry, 26(22), 7519–7522. https://doi.org/10.14233/ajchem.2014.16649

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References

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References

J. Huang, Pure Appl. Chem., 78, 15 (2006); doi:10.1351/pac200678010015.

J. Aguilar-Hernández and K. Potje-Kamloth, J. Phys. D Appl. Phys., 34, 1700 (2001); doi:10.1088/0022-3727/34/11/323.

Q. Tang, X. Sun, Q. Li, J. Lin and J. Wu, J. Mater. Sci., 44, 849 (2009); doi:10.1007/s10853-008-3137-5.

J. Jiang, L. Ai and L. Li, J. Phys. Chem. B, 113, 13 (2009).

R. Khan, P. Khare, B.P. Baruah, A.K. Hazarika and N.C. Dey, Adv. Chem. Eng. Sci., 1, 37 (2011), 1, 37 (2011); doi:10.4236/aces.2011.12007.

S.A. Ghani and H.C. Young, J. Physiol. Sci., 21, 81 (2010).

S. Sen, A. Gok and H. Gulce, J. Appl. Polym. Sci., 106, 3852 (2007); doi:10.1002/app.26932.

D. Muller, J.S. Mandelli, J.A. Marins, B.G. Soares, L.M. Porto, C.R. Rambo and G.M.O. Barra, Cellulose, 19, 1645 (2012); doi:10.1007/s10570-012-9754-9.

M. G-Balcázar, R. Ortega, F. Castaneda, L.G. Arriaga and J.L. Garcia, Int. J. Electrochem. Soc., 6, 4667 (2011).

C.S.S. Sangeeth, P. Jiménez, A.M. Benito, W.K. Maser and R. Menon, J. Appl. Phys., 107, 103719 (2010); doi:10.1063/1.3374628.

T.B. Phan, T.T. Pham and T.T.T. Mai, Adv. Nat. Sci.: Nanosci. Nanotechnol., 4, 015015 (2013); doi:10.1088/2043-6262/4/1/015015.

X.-X. Xu, Z.-P. Cui, J. Qi and X.-X. Liu, J. Chem. Soc., Dalton Trans., 42, 4031 (2013); doi:10.1039/c2dt32636a.

Y.-N. Koh, K.P. Sambasevam, R. Yahya and S.-W. Phang, Polym. Composites, 34, 1186 (2013); doi:10.1002/pc.22528.

M. Rahaman, T.K. Chaki and D. Khastgir, Polym. Eng. Sci., 54, 1632 (2014); doi:10.1002/pen.23714.

S.H. Shumaila, S. Parveen, J. Ali, A. Kumar and M. Husain, Polym. Composites, 34, 1298 (2013); doi:10.1002/pc.22542.

X.J. Yang, J.Y. Li and Y.P. Lei, Adv. Mater. Res., 668, 17 (2013); doi:10.4028/www.scientific.net/AMR.668.17.

P.S. Kalsi, Spectroscopy of Organic Compounds, Wiley Eastern Limited, New Delhi, edn 6, pp. 66–68 (2006).

T.-H. Hsieh, K.-S. Ho, C.-H. Huang, Y.-Z. Wang and Z.-L. Chen, Synth. Metals, 156, 1355 (2006); doi:10.1016/j.synthmet.2006.10.005.

D. Zhang, Polym. Test., 26, 9 (2007); doi:10.1016/j.polymertesting.2006.07.010.

G. Zhang, X. Li, H. Jia, X. Pang, H. Yang, Y. Wang and K. Ding, Int. J. Electrochem. Sci., 7, 819 (2012).

A. Batool, F. Kanwal, M. Imran, T. Jamil and S.A. Siddiqi, Synth. Met., 161, 2753 (2012); doi:10.1016/j.synthmet.2011.10.016.

R. Gangopadhyay and A. De, Eur. Polym. J., 35, 1985 (1999); doi:10.1016/S0014-3057(99)00008-7.

T.K. Vishnuvardhan, V.R. Kulkarni, C. Basavaraja and S.C. Raghavendra, Bull. Mater. Sci., 29, 77 (2006); doi:10.1007/BF02709360.

J. Xu, K.-S. Moon, C. Tison and C.P. Wong, IEEE Trans. Adv. Packag., 29, 295 (2006); doi:10.1109/TADVP.2006.874701.

Issue

Vol. 26 No. 22 (2014): Vol 26 Issue 22

Synthesis of Polyaniline Composites with Grinded Leaves of Polyalthia longifolia, Syzygium cumini, Alstonia scholaris and Madhuca longifolia and Study of Their Structural, Electrical and Dielectric Properties

Corresponding Author(s) : Farah Kanwal

Abstract

Keywords

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