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Vol. 26 No. 22 (2014): Vol 26 Issue 22

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Synthesis and Characterization of New Aromatic Polyesters Derived from New Aromatic Di- and Tri Hydroxyl Monomers with 4-Phenylenediacrylic Acid and Malonic Acid

https://doi.org/10.14233/ajchem.2014.18082
Mohammed A. Mutar
Department of Chemistry, College of Education, University of Al-Qadisyia, Al-Qadisyia, Iraq

Corresponding Author(s) : Mohammed A. Mutar

mohammeddw73@gmail.com

Asian Journal of Chemistry, Vol. 26 No. 22 (2014): Vol 26 Issue 22

Abstract

In the present work, six new aromatic polyesters (PE1-PE6) have been synthesized in high yields from the polycondensation between di- and tri hydroxyl monomers containing methylene unit, Schiff-base linkages and pyridine heterocyclic ring with 4-phenylenediacrylic acid and malonic acid using dibutyltin dilaurate as catalyst. The structure analysis of the polymers has been carried out by using FT-IR and 1H NMR spectroscopy. The monomers were characterized by FTIR and 1H NMR. FT-IR technique confirmed the esterification of di and tri hydroxyl monomers by the acid in all the polymers.

Keywords

Synthesis Aromatic polyesters 4-Phenylenediacrylic acid Malonic acid
A. Mutar, M. (2014). Synthesis and Characterization of New Aromatic Polyesters Derived from New Aromatic Di- and Tri Hydroxyl Monomers with 4-Phenylenediacrylic Acid and Malonic Acid. Asian Journal of Chemistry, 26(22), 7846–7852. https://doi.org/10.14233/ajchem.2014.18082
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