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Synthesis and Spectroscopic Characterization of Some Novel Schiff Base Complexes of Transition Metals and Their Biological Studies
Corresponding Author(s) : Netra Pal Singh
Asian Journal of Chemistry,
Vol. 26 No. 22 (2014): Vol 26 Issue 22
Abstract
Cobalt(II) and manganese(II) complexes of novel Schiff base derived from 4,5-dimethoxy-1,2-phenylenediamine and 5-substituted salicylaldehyde have been synthesized and characterized by various physico-chemical techniques viz. elemental analysis, magnetic moment, IR, NMR and electronic spectral studies. The complexes have been found to have a stoichiometry of 1:1 (M:L). The probable geometry and biological activity of the complexes also have been reported.
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- K.S. Murray, B.A.M. Van and B.O. West, Aust. J. Chem., 31, 203 (1978); doi:10.1071/CH9780203.
- K. Dey, A.K. Biswas and A. Roy, Indian J. Chem., 20A, 848 (1981).
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- K.S. Murray, B.A.M. Van and B.O. West, Aust. J. Chem., 31, 203 (1978); doi:10.1071/CH9780203.
- H. Doine, F.F. Stephens and R.D. Cannon, Bull. Chem. Soc. Jpn., 58, 1327 (1985); doi:10.1246/bcsj.58.1327.
- K. Nakajima, Y. Ando, H. Mano and M. Kojima, Inorg. Chim. Acta, 274, 184 (1998); doi:10.1016/S0020-1693(97)06048-9.
- B. De Clercq and F. Verpoort, Macromolecules, 35, 8943 (2002); doi:10.1021/ma020307d.
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- T. Opstal and F. Verpoort, Synlett., 935 (2002); doi:10.1055/s-2002-31892.
- S.N. Pal and S. Pal, Inorg. Chem., 40, 4807 (2001); doi:10.1021/ic010310y.
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- B.D. Clercq, F. Lefebvre and F. Verpoor, Appl. Catal. A, 247, 345 (2003); doi:10.1016/S0926-860X(03)00126-1.
- I.M.I. Falhr, N.A. Hamdy, M.A. Radwan and Y.M. Ahmed, Egypt. J. Chem., 201 (2004).
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- S.N. Pandeya, D. Sriram, G. Nath and E. De Clercq, Il Farmaco, 54, 624 (1999); doi:10.1016/S0014-827X(99)00075-0.
- W.M. Singh and W.C. Dash, Pesticides, 22, 33 (1998).
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- P. Pathak, V.S. Jolly and K.P. Sharma, Orient. J. Chem., 16, 161 (2000).
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- E.M. Nour, A.A. Taha and I.S. Alnaimi, Inorg. Chim. Acta, 141, 139 (1988); doi:10.1016/S0020-1693(00)86387-2.
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- W. Wang, F.L. Zeng, X. Wang and M.-Y. Tan, Polyhedron, 15, 1699 (1996); doi:10.1016/0277-5387(95)00403-3.
- P.E. Aranha, J.M. Souza, S. Romera, L.A. Ramos, M.P. dos Santos, E.R. Dockal and E.T.G. Cavalheiro, Thermochim. Acta, 453, 9 (2007); doi:10.1016/j.tca.2006.11.001.
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- X. Tai, X. Yin, Q. Chen and M. Tan, Molecules, 8, 439 (2003); doi:10.3390/80500439.
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- B. Anupama and C.G. Kumari, Int. J. Res. Chem. Environ, 3, 172 (2013).
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- B.K. Sahu and B.K. Mahapatra, J. Indian Chem. Soc., 56, 825 (1979).
- M. Odabasoglu, F. Arslan, H. Olmez and O. Büyükgüngör, Dyes Pigments, 75, 505 (2007); doi:10.1016/j.dyepig.2006.06.033.
- H. Naeimi, J. Safari and A. Heidarnezhad, Dyes Pigments, 73, 251 (2007); doi:10.1016/j.dyepig.2005.12.009.
- K. Singh, M.S. Barwa and P. Tyagi, Eur. J. Med. Chem., 41, 147 (2006); doi:10.1016/j.ejmech.2005.06.006.
- K.-H. Chang, C.-C. Huang, Y.-H. Liu, Y.-H. Hu, P.-T. Chou and Y.-C. Lin, Dalton Trans., 1731 (2004); doi:10.1039/b316281h.
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- C.E. Overton, Studien Uber die Norkose Zugleichein Beitrag Zur allgemeinon Pharmokologi, Gustav Fisher, Jena, Switzerland (1901).
- B.G. Tweedy, Phytopathology, 55, 910 (1901).
References
K.S. Murray, B.A.M. Van and B.O. West, Aust. J. Chem., 31, 203 (1978); doi:10.1071/CH9780203.
K. Dey, A.K. Biswas and A. Roy, Indian J. Chem., 20A, 848 (1981).
Z. Guan, P.M. Cotts, E.F. McCord and S.J. McLain, Science, 283, 2059 (1999); doi:10.1126/science.283.5410.2059.
K.S. Murray, B.A.M. Van and B.O. West, Aust. J. Chem., 31, 203 (1978); doi:10.1071/CH9780203.
H. Doine, F.F. Stephens and R.D. Cannon, Bull. Chem. Soc. Jpn., 58, 1327 (1985); doi:10.1246/bcsj.58.1327.
K. Nakajima, Y. Ando, H. Mano and M. Kojima, Inorg. Chim. Acta, 274, 184 (1998); doi:10.1016/S0020-1693(97)06048-9.
B. De Clercq and F. Verpoort, Macromolecules, 35, 8943 (2002); doi:10.1021/ma020307d.
T. Opstal and F. Verpoort, Angew. Chem. Int. Ed., 42, 2876 (2003); doi:10.1002/anie.200250840.
T. Opstal and F. Verpoort, Synlett., 935 (2002); doi:10.1055/s-2002-31892.
S.N. Pal and S. Pal, Inorg. Chem., 40, 4807 (2001); doi:10.1021/ic010310y.
B. De Clercq and F. Verpoort, Adv. Synth. Catal., 344, 639 (2002); doi:10.1002/1615-4169(200208)344:6/7<639::AID-ADSC639>3.0.CO;2-0.
B.D. Clercq, F. Lefebvre and F. Verpoor, Appl. Catal. A, 247, 345 (2003); doi:10.1016/S0926-860X(03)00126-1.
I.M.I. Falhr, N.A. Hamdy, M.A. Radwan and Y.M. Ahmed, Egypt. J. Chem., 201 (2004).
(a) P.S. Dixit and K. Srinivasan, Inorg. Chem., 27, 4507 (1988); doi:10.1021/ic00297a034; (b) A. Nishinaga, T. Tojo and T. Matsuura, J. Chem. Soc. Chem. Commun., 896 (1974); doi:10.1039/c39740000896.
A. Mohindru, J.M. Fisher and M. Rabinovitz, Nature, 303, 64 (1983); doi:10.1038/303064a0.
P.R. Palet and B.T. Thaker, Indian J. Chem., A38, 563 (1999).
R.E. Hester and E.M. Nour, J. Raman Spectrosc., 11, 39 (1981); doi:10.1002/jrs.1250110112.
K. Drabent, A. Białońska and Z. Ciunik, Inorg. Chem. Commun., 7, 224 (2004); doi:10.1016/j.inoche.2003.11.008.
M.H. Klingele and S. Brooker, Coord. Chem. Rev., 241, 119 (2003); doi:10.1016/S0010-8545(03)00049-3.
V.B. Arion, E. Reisner, M. Fremuth, M.A. Jakupec, B.K. Keppler, V.Y. Kukushkin and A.J.L. Pombeiro, Inorg. Chem., 42, 6024 (2003); doi:10.1021/ic034605i.
M. Mashaly, H.A. Boyoumi and A. Taha, Chem. Papers, 53, 299 (1999).
A.S. Kabeer, M.A. Baseer and N.A. Mote, Asian J. Chem., 13, 496 (2001).
A.H. El-masry, H.H. Fahmy and S.H. Ali Abdelwahed, Molecules, 5, 1429 (2000); doi:10.3390/51201429.
P.G. More, R.B. Bhalvankar and S.C. Patter, J. Indian Chem. Soc., 78, 474 (2001).
S.N. Pandeya, D. Sriram, G. Nath and E. De Clercq, Il Farmaco, 54, 624 (1999); doi:10.1016/S0014-827X(99)00075-0.
W.M. Singh and W.C. Dash, Pesticides, 22, 33 (1998).
S.B. Desai, P.B. Desai and K.R. Desai, Heterocycl. Commun., 7, 83 (2001); doi:10.1515/HC.2001.7.1.83.
P. Pathak, V.S. Jolly and K.P. Sharma, Orient. J. Chem., 16, 161 (2000).
S. Samadhiya and A. Holve, Orient. J. Chem., 17, 119 (2001).
E.M. Nour, A.A. Taha and I.S. Alnaimi, Inorg. Chim. Acta, 141, 139 (1988); doi:10.1016/S0020-1693(00)86387-2.
E.M. Nour, A.M. Al-Kority, S.A. Sadeek and S.M. Teleb, Synth. React. Inorg. Met-org. Chem., 23, 39 (1993); doi:10.1080/15533179308016615.
W. Wang, F.L. Zeng, X. Wang and M.-Y. Tan, Polyhedron, 15, 1699 (1996); doi:10.1016/0277-5387(95)00403-3.
P.E. Aranha, J.M. Souza, S. Romera, L.A. Ramos, M.P. dos Santos, E.R. Dockal and E.T.G. Cavalheiro, Thermochim. Acta, 453, 9 (2007); doi:10.1016/j.tca.2006.11.001.
T.M. Bhagat, D.K. Swamy and M.N. Deshpande, J. Chem. Pharm Res., 4, 100 (2012).
D.A. House and N.F. Curtis, J. Am. Chem. Soc., 86, 1331 (1964); doi:10.1021/ja01061a014.
M. Tümer, C. Çelik, H. Köksal and S. Serin, Transition Met. Chem., 24, 525 (1999); doi:10.1023/A:1006982622965.
X. Tai, X. Yin, Q. Chen and M. Tan, Molecules, 8, 439 (2003); doi:10.3390/80500439.
P.T.T. Wong and D.G. Brewer, Can. J. Chem., 46, 131 (1968); doi:10.1139/v68-024.
B.N. Figgis and J. Lewis, Prog. Inorg. Chem., 6, 37 (1964); doi:10.1002/9780470166079.ch2.
B. Anupama and C.G. Kumari, Int. J. Res. Chem. Environ, 3, 172 (2013).
A.B.P. Lever, Inorganic Electronic Spectroscopy Elsevier, Amsterdem (1968).
B.K. Sahu and B.K. Mahapatra, J. Indian Chem. Soc., 56, 825 (1979).
M. Odabasoglu, F. Arslan, H. Olmez and O. Büyükgüngör, Dyes Pigments, 75, 505 (2007); doi:10.1016/j.dyepig.2006.06.033.
H. Naeimi, J. Safari and A. Heidarnezhad, Dyes Pigments, 73, 251 (2007); doi:10.1016/j.dyepig.2005.12.009.
K. Singh, M.S. Barwa and P. Tyagi, Eur. J. Med. Chem., 41, 147 (2006); doi:10.1016/j.ejmech.2005.06.006.
K.-H. Chang, C.-C. Huang, Y.-H. Liu, Y.-H. Hu, P.-T. Chou and Y.-C. Lin, Dalton Trans., 1731 (2004); doi:10.1039/b316281h.
J. Parekh, P. Inamdhar, R. Nair, S. Baluja and S. Chanda, J. Serb. Chem. Soc., 70, 1155 (2005); doi:10.2298/JSC0510155P.
C.E. Overton, Studien Uber die Norkose Zugleichein Beitrag Zur allgemeinon Pharmokologi, Gustav Fisher, Jena, Switzerland (1901).
B.G. Tweedy, Phytopathology, 55, 910 (1901).