Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
FTIR of Soils from Different Areas of China
Corresponding Author(s) : Gang Liu
Asian Journal of Chemistry,
Vol. 26 No. 22 (2014): Vol 26 Issue 22
Abstract
Fourier transform infrared spectroscopy (FTIR) was used to study five different types of soil. The results showed that the infrared spectra of soil were mainly composed of the absorption band of inorganic salts, such as carbonate, nitrate, phosphate, manganatem, etc., clay minerals and the organic matter. FTIR spectra of five types of soils are similar on the whole, but they present obvious difference in the range of 1600-750 cm-1. According to the first derivative spectra of five types of soils, the differences were mainly found displaying in the range of 1440, 875 and 798-780 cm-1. The first derivative data of the range of 1600-750 cm-1 were selected to use the Matlab 2010 to implement the principal component analysis, the contributing rates of the first two principal components had reached 90.14 %, which can reflect the main information in the spectra. The two-dimensional distribution was made by plotting these two principal components as scores plots, which provided a reliable and rapid method for the identification of soil type. It is demonstrated that FTIR technique is rapid, nondestructive, convenient, accurate and has a great potential for application.
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- C.W. Du, The Principle and Application of Fourier Transform Infrared Photoacoustic spectroscopy for Soil, Science Press, Beijing, p. 25 (2011).
- H.Z. Gao, Spectrosc. Spectr. Anal., 31, 1245 (2011).
- R.A. Viscarra Rossel, R.N. McGlynn and A.B. McBratney, Geoderma, 137, 70 (2006); doi:10.1016/j.geoderma.2006.07.004.
- C. Du, J. Zhou, H. Wang, X. Chen, A. Zhu and J. Zhang, Vib. Spectrosc., 49, 32 (2009); doi:10.1016/j.vibspec.2008.04.009.
- R.L. Frost, Y. Xi, R. Scholz, A. López and F.M. Belotti, J. Mol. Struct., 1042, 1 (2013); doi:10.1016/j.molstruc.2013.03.036.
- R. Linker, I. Shmulevich, A. Kenny and A. Shaviv, Chemosphere, 61, 652 (2005); doi:10.1016/j.chemosphere.2005.03.034.
- J. Reeves III, Geoderma, 189-190, 508 (2012); doi:10.1016/j.geoderma.2012.06.008.
- R. Frost, Y.F. Xi, R. Scholz, A. López, R.M.F. Lima and C.M. Ferreira, Vib. Spectrosc., 67, 14 (2013); doi:10.1016/j.vibspec.2013.03.005.
- J.G. Wu, Technique and Application of Modern Fourier Transform Infrared Spectroscopy. Science and Technology Beijing, Literature Press, pp. 640 (1994).
- Y. Wang, Y.P. Zhang and S.G. Chen, J. Northwest Sci.-Tech. Univ. Agric. For., 31, 57 (2003).
- M. Forouzangohar, D. Cozzolino, R. Smernik, J.A. Baldock, S.T. Forrester, D.J. Chittleborough and R.S. Kookana, Vib. Spectrosc., 66, 76 (2013); doi:10.1016/j.vibspec.2013.02.002.
- F. Liu, Acta Pedolog. Sinica, 33, 59 (1996).
- Z.Y. Li, G. Liu and L. Li, Agric. Sci. Technol., 13, 2363 (2012).
References
C.W. Du, The Principle and Application of Fourier Transform Infrared Photoacoustic spectroscopy for Soil, Science Press, Beijing, p. 25 (2011).
H.Z. Gao, Spectrosc. Spectr. Anal., 31, 1245 (2011).
R.A. Viscarra Rossel, R.N. McGlynn and A.B. McBratney, Geoderma, 137, 70 (2006); doi:10.1016/j.geoderma.2006.07.004.
C. Du, J. Zhou, H. Wang, X. Chen, A. Zhu and J. Zhang, Vib. Spectrosc., 49, 32 (2009); doi:10.1016/j.vibspec.2008.04.009.
R.L. Frost, Y. Xi, R. Scholz, A. López and F.M. Belotti, J. Mol. Struct., 1042, 1 (2013); doi:10.1016/j.molstruc.2013.03.036.
R. Linker, I. Shmulevich, A. Kenny and A. Shaviv, Chemosphere, 61, 652 (2005); doi:10.1016/j.chemosphere.2005.03.034.
J. Reeves III, Geoderma, 189-190, 508 (2012); doi:10.1016/j.geoderma.2012.06.008.
R. Frost, Y.F. Xi, R. Scholz, A. López, R.M.F. Lima and C.M. Ferreira, Vib. Spectrosc., 67, 14 (2013); doi:10.1016/j.vibspec.2013.03.005.
J.G. Wu, Technique and Application of Modern Fourier Transform Infrared Spectroscopy. Science and Technology Beijing, Literature Press, pp. 640 (1994).
Y. Wang, Y.P. Zhang and S.G. Chen, J. Northwest Sci.-Tech. Univ. Agric. For., 31, 57 (2003).
M. Forouzangohar, D. Cozzolino, R. Smernik, J.A. Baldock, S.T. Forrester, D.J. Chittleborough and R.S. Kookana, Vib. Spectrosc., 66, 76 (2013); doi:10.1016/j.vibspec.2013.02.002.
F. Liu, Acta Pedolog. Sinica, 33, 59 (1996).
Z.Y. Li, G. Liu and L. Li, Agric. Sci. Technol., 13, 2363 (2012).