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Vol. 26 No. 22 (2014): Vol 26 Issue 22

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Synthesis of Glycerol Monostearate by Esterification on H3PW12O40/MCM-41 Catalyst

https://doi.org/10.14233/ajchem.2014.16867
Yi Gu
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China
Lu Zhou
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China
Lei Niu
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China
Mei Hong
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China
Guomin Xiao
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, P.R. China

Corresponding Author(s) : Guomin Xiao

xiaogm@seu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 22 (2014): Vol 26 Issue 22

Abstract

H3PW12O40/MCM-41 solid-acid catalyst with different phosphotungstic acid (H3PW12O40) loadings was prepared by impregnation method and used in the esterification of glycerol with stearic acid using N,N-dimethyl formamide as solvent. The catalyst was characterized by FT-IR spectroscopy, transmission electron microscopy and scanning electron microscopy. The effects of catalyst preparation and esterification parameters such as reaction time, stearic acid/glycerol ratio and reaction temperature on esterification were investigated simultaneously. The results showed that H3PW12O40/MCM-41 had the best catalytic properties when the H3PW12O40 loading was 30 % and the use of DMF had a significant improvement on the yield of monoglyceride. Under a reaction condition of 6 h, 433 K and glycerol/acid molar ratio 6:1, 91 % selectivity of glycerol monosteatate was achieved with a stearic acid conversion of 98 %.

Keywords

Esterification Glycerol monostearate Tungstophosphoric acid MCM-41
Gu, Y., Zhou, L., Niu, L., Hong, M., & Xiao, G. (2014). Synthesis of Glycerol Monostearate by Esterification on H3PW12O40/MCM-41 Catalyst. Asian Journal of Chemistry, 26(22), 7564–7568. https://doi.org/10.14233/ajchem.2014.16867
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