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Preparation, Characterization and Physicochemical Behaviour of New Acetylated Schiff Base Ligand and its Metal Complexes
Corresponding Author(s) : Narjis Naz
Asian Journal of Chemistry,
Vol. 26 No. 21 (2014): Vol 26 Issue 21
Abstract
We wish to report herein some new metal complexes of (S)-5-[(E)-3-(2-hydroxybenzylidene)guanidine]-2-acetamido pentanoic acid. Acetylation was successfully executed by the action of acetic anhydride on condensed product of salicylaldehyde and L-arginine named (S)-5-[(E)-3-(2-hydroxybenzylidene)guanidine]-2-amino pentanoic acid. Bidentate ligand was coordinated with Ni(II), Fe(II), Cr(III), Mn(II), Zn(II) and Cu(II) salts to furnish their respective metal complexes. FTIR, UV-visible. and MS spectrum of ligand and metal complexes were studied. TGA analysis showed thermal properties of compounds while their crystal systems were proved by X-ray diffraction technique. The results suggested that the ligand is bonded to metal through hydroxyl oxygen and the imino nitrogen.
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- G.B. Roy, Inorg. Chim. Acta, 362, 1709 (2009); doi:10.1016/j.ica.2008.08.009.
- W.-L. Liu, Y. Zou, C.-L. Ni, Z.-P. Ni, Y.-Z. Li, Y.-G. Yao and Q.-J. Meng, Polyhedron, 23, 849 (2004); doi:10.1016/j.poly.2003.11.049.
- N. Naz, Z. Sadiq and M.Z. Iqbal, Asian J. Chem., 25, 297 (2013); doi:10.14233/ajchem.2013.13005.
- M. Sonmez, A. Levent and M. Sekerci, Russ. J. Coord. Chem., 30, 655 (2004); doi:10.1023/B:RUCO.0000040726.57728.a3.
- M.B. Halli, V.B. Patil and S.R. Bevinamarada, Turk. J. Chem., 35, 393 (2011).
- S. Kumar, D.N. Dhar and P.N. Saxena, J. Sci. Ind. Res. (India), 68, 181 (2009).
- A.M. Atta, N.O. Shaker, M.I. Abdou and M. Abdelfatah, Prog. Org. Coat., 56, 91 (2006); doi:10.1016/j.porgcoat.2005.11.003.
- M.N. Desai, M.B. Desai, C.B. Shah and S.M. Desai, Corros. Sci., 26, 827 (1986); doi:10.1016/0010-938X(86)90066-1.
- S. Bilgiç and N. Çaliskan, Appl. Electrochem., 31, 79 (2001); doi:10.1023/A:1004182329826.
- S. Li, S. Chen, S. Lei, H. Ma, R. Yu and D. Liu, Corros. Sci., 41, 1273 (1999); doi:10.1016/S0010-938X(98)00183-8.
- M. Şekerci and C. Alkan, Synth. React. Inorg. Met-Org. Chem., 29, 1685 (1999); doi:10.1080/00945719909351728.
- M. Sekerci and E. Tas, Heteroatom Chem., 11, 254 (2000); doi:10.1002/1098-1071(2000)11:4<254::AID-HC2>3.0.CO;2-4.
- B. Bosnich, J. Am. Chem. Soc., 90, 627 (1968); doi:10.1021/ja01005a012.
- R.S. Downing and F.L. Urbach, J. Am. Chem. Soc., 91, 5977 (1969); doi:10.1021/ja01050a009.
- M. Sonmez and M. Sekerci, Pol. J. Chem., 76, 907 (2002).
- K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York, NY: John Wiley Interscience, p. 59 (1997).
- N. Raman, S. Ravichandran and A. Kulandaisamy, Asian J. Chem., 14, 1261 (2002).
- R.K. Agarwal, D. Sharma, L. Singh and H. Agarwal, Bioinorg. Chem. Appl., Article ID 29234 (2006); doi:10.1155/BCA/2006/29234.
- N. Raman and S. Ravichandran, Pol. J. Chem., 78, 2005 (2004).
- N. Naz, S. Khatoon, H. Ajaz, Z. Sadiq and M.Z. Iqbal, Asian J. Chem, 25, 2239 (2013); doi:10.14233/ajchem.2013.13413.
References
G.B. Roy, Inorg. Chim. Acta, 362, 1709 (2009); doi:10.1016/j.ica.2008.08.009.
W.-L. Liu, Y. Zou, C.-L. Ni, Z.-P. Ni, Y.-Z. Li, Y.-G. Yao and Q.-J. Meng, Polyhedron, 23, 849 (2004); doi:10.1016/j.poly.2003.11.049.
N. Naz, Z. Sadiq and M.Z. Iqbal, Asian J. Chem., 25, 297 (2013); doi:10.14233/ajchem.2013.13005.
M. Sonmez, A. Levent and M. Sekerci, Russ. J. Coord. Chem., 30, 655 (2004); doi:10.1023/B:RUCO.0000040726.57728.a3.
M.B. Halli, V.B. Patil and S.R. Bevinamarada, Turk. J. Chem., 35, 393 (2011).
S. Kumar, D.N. Dhar and P.N. Saxena, J. Sci. Ind. Res. (India), 68, 181 (2009).
A.M. Atta, N.O. Shaker, M.I. Abdou and M. Abdelfatah, Prog. Org. Coat., 56, 91 (2006); doi:10.1016/j.porgcoat.2005.11.003.
M.N. Desai, M.B. Desai, C.B. Shah and S.M. Desai, Corros. Sci., 26, 827 (1986); doi:10.1016/0010-938X(86)90066-1.
S. Bilgiç and N. Çaliskan, Appl. Electrochem., 31, 79 (2001); doi:10.1023/A:1004182329826.
S. Li, S. Chen, S. Lei, H. Ma, R. Yu and D. Liu, Corros. Sci., 41, 1273 (1999); doi:10.1016/S0010-938X(98)00183-8.
M. Şekerci and C. Alkan, Synth. React. Inorg. Met-Org. Chem., 29, 1685 (1999); doi:10.1080/00945719909351728.
M. Sekerci and E. Tas, Heteroatom Chem., 11, 254 (2000); doi:10.1002/1098-1071(2000)11:4<254::AID-HC2>3.0.CO;2-4.
B. Bosnich, J. Am. Chem. Soc., 90, 627 (1968); doi:10.1021/ja01005a012.
R.S. Downing and F.L. Urbach, J. Am. Chem. Soc., 91, 5977 (1969); doi:10.1021/ja01050a009.
M. Sonmez and M. Sekerci, Pol. J. Chem., 76, 907 (2002).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, New York, NY: John Wiley Interscience, p. 59 (1997).
N. Raman, S. Ravichandran and A. Kulandaisamy, Asian J. Chem., 14, 1261 (2002).
R.K. Agarwal, D. Sharma, L. Singh and H. Agarwal, Bioinorg. Chem. Appl., Article ID 29234 (2006); doi:10.1155/BCA/2006/29234.
N. Raman and S. Ravichandran, Pol. J. Chem., 78, 2005 (2004).
N. Naz, S. Khatoon, H. Ajaz, Z. Sadiq and M.Z. Iqbal, Asian J. Chem, 25, 2239 (2013); doi:10.14233/ajchem.2013.13413.