Highly Sensitive Cobalt Porphyrin Biomimetic Catalyzed Flow Injection Chemiluminescence Determination of Diethylstilbestrol in Pharmaceuticals

Shichao Xu; Xindi Lu; Bingcheng Hu; Zhendong Zhao

doi:10.14233/ajchem.2014.16571

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Issue Published : September 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Highly Sensitive Cobalt Porphyrin Biomimetic Catalyzed Flow Injection Chemiluminescence Determination of Diethylstilbestrol in Pharmaceuticals

https://doi.org/10.14233/ajchem.2014.16571

Shichao Xu

Institute of Chemical Industry of Forestry Products, CAF; National Engineering Lab. for Biomass Chemical Utilization; Key and Open Lab. on Forest Chemical Engineering, SFA; Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, P.R. China

Xindi Lu

Zhuzhou Sonbon Forest Chemical Co. LTD, Zhuzhou 412001, P.R.China

Bingcheng Hu

College of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P.R. China

Zhendong Zhao

Corresponding Author(s) : Shichao Xu

toughxu@163.com

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21
Article Published : September 30, 2014

Abstract

The great inhibition of diethylstilbestrol to cobalt deuteroporphyrin catalyzed luminol-H₂O₂ chemiluminescence reaction, has been exploited to develop a novel and sensitive flow-injection chemiluminescence detection method for the determination of diethylstilbestrol. The optimum experimental conditions and the possible mechanism have been investigated. Under the optimized parameters, the relative chemiluminescence intensity is linearly related to the concentration of diethylstilbestrol in the range of 6 × 10^-10 – 1.0 × 10^-8 g mL^-1 and 1 × 10^-8 – 1 × 10^-7 g mL^-1 with a detection limit of 3.83 × 10^-10 g mL^-1. The proposed method could be successfully applied to the determination of diethylstilbestrol in pharmaceuticals.

Keywords

Luminol Cobalt porphyrin Diethylstilbestrol determination Chemiluminescence

Xu, S., Lu, X., Hu, B., & Zhao, Z. (2014). Highly Sensitive Cobalt Porphyrin Biomimetic Catalyzed Flow Injection Chemiluminescence Determination of Diethylstilbestrol in Pharmaceuticals. Asian Journal of Chemistry, 26(21), 7229–7234. https://doi.org/10.14233/ajchem.2014.16571

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J. Wang, H. Ye, Z. Jiang, N. Chen and J. Huang, Anal. Chim. Acta, 508, 171 (2004); doi:10.1016/j.aca.2003.12.003.

Y. Zhao, Y. Liang, J. Qian, L. Li and S. Wang, Anal. Lett., 42, 216 (2009); doi:10.1080/00032710802585683.

J. Odum and P.A. Lefevre, Toxicol. Sci., 68, 147 (2002); doi:10.1093/toxsci/68.1.147.H

J. Shamash, T. Powles, S.J. Sarker, A. Protheroe, N. Mithal, R. Mills, R. Beard, P. Wilson, N. Tranter, N. O’Brien, S. McFaul and T. Oliver, Br. J. Cancer, 104, 620 (2011); doi:10.1038/bjc.2011.7.

E.N. Barkatina, S.V. Volkovich, O.N. Venger, V.I. Murokh, N.D. Kolomiets and O.V. Shulyakovskaya, J. Anal. Chem., 56, 740 (2001); doi:10.1023/A:1016737727787.

M.J. López de Alda and D. Barceló, J. Chromatogr. A, 892, 391 (2000); doi:10.1016/S0021-9673(00)00068-6.

S. Kanimozhi, C. Basheer, K. Narasimhan, L. Liu, S. Koh, F. Xue, M. Choolani and H.K. Lee, Anal. Chim. Acta, 687, 56 (2011); doi:10.1016/j.aca.2010.12.007.

M.J. López de Alda and D. Barceló, J. Chromatogr. A, 938, 145 (2001); doi:10.1016/S0021-9673(01)01223-7.

F.J. Lara, A.M. García-Campaña and J. Aaron, Anal. Chim. Acta, 679, 17 (2010); doi:10.1016/j.aca.2010.09.001.

L. Wang, Y. Tang and Y. Liu, J. Pharm. Anal., 1, 51 (2011); doi:10.1016/S2095-1779(11)70009-0.

S. Xu, W. Liu, B. Hu, W. Cao and Z.L. Liu, J. Photochem. Photobiol. Chem., 227, 32 (2012); doi:10.1016/j.jphotochem.2011.10.021.

T. Yamaguchi, K. Tsukamoto, O. Ikeda, R. Tanaka, T. Kuwabara and K. Takahashi, Electrochim. Acta, 55, 6042 (2010); doi:10.1016/j.electacta.2010.05.064.

J.F. van Staden and R.I. Stefan-van Staden, Talanta, 80, 1598 (2010); doi:10.1016/j.talanta.2009.10.016.

D. Wu, Y. Han, Q. Wei, Y. Zhao, K. Mao, Y. Cai, R. Li and Y. Dai, Luminescence, 26, 629 (2011); doi:10.1002/bio.1286.

W. Zhou, B. Hu and Z. Liu, Appl. Catal. A, 358, 136 (2009); doi:10.1016/j.apcata.2009.02.003.

R.K. Dinello and D.H. Dolphin, J. Org. Chem., 46, 3498 (1981); doi:10.1021/jo00330a023.

C. Sun, B. Hu, W. Zhou, S. Xu and Z.L. Liu, Ultrason. Sonochem., 18, 501 (2011); doi:10.1016/j.ultsonch.2010.08.010.

E.S. Ribeiro, S.L.P. Dias, Y. Gushikem and L.T. Kubota, Electrochim. Acta, 49, 829 (2004); doi:10.1016/j.electacta.2003.10.001.

H. Chen, F. Gao, R. He and D. Cui, J. Colloid Interf. Sci., 315, 158 (2007); doi:10.1016/j.jcis.2007.06.052.

E.L. Bastos, P. Romoff, C.R. Eckert and W.J. Baader, J. Agric. Food Chem., 51, 7481 (2003); doi:10.1021/jf0345189.

J. Lee, J.A. Hunt and J.T. Groves, J. Am. Chem. Soc., 120, 6053 (1998); doi:10.1021/ja9801036.

İ. Biryol, B. Salci and E. Erdik, J. Pharm. Biomed. Anal., 32, 1227 (2003); doi:10.1016/S0731-7085(03)00217-6.

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Highly Sensitive Cobalt Porphyrin Biomimetic Catalyzed Flow Injection Chemiluminescence Determination of Diethylstilbestrol in Pharmaceuticals

Corresponding Author(s) : Shichao Xu

Abstract

Keywords

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