Synthesis and Structural Characterization of N-Amino Compounds

Ya-Nan Li; Ning Liu; Peng-Fei Su; Ying-Lei Wang; Zhong-Xue Ge; Hui Li; Bo-Zhou Wang

doi:10.14233/ajchem.2014.16529

Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Issue Published : September 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Structural Characterization of N-Amino Compounds

https://doi.org/10.14233/ajchem.2014.16529

Ya-Nan Li

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Ning Liu

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Peng-Fei Su

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Ying-Lei Wang

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Zhong-Xue Ge

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Hui Li

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Bo-Zhou Wang

Xi'an Modern Chemistry Research Institute, Xi'an 710065, P.R. China

Corresponding Author(s) : Ya-Nan Li

lyn2003080094@126.com

Asian Journal of Chemistry, Vol. 26 No. 21 (2014): Vol 26 Issue 21
Article Published : September 30, 2014

Abstract

Seven N-amino compounds were successfully synthesized via N-amination reaction. The structures of target compounds and intermediates were characterized by ¹H NMR, ¹³C NMR, IR, elementary analysis, MS and X-ray single-crystal diffraction analysis. The single crystals of 3,5-diamino-1,2,4-triazole and 3,5-dinitro-1,2,4-triazole were obtained. Crystal data of 3,5-diamino-1,2,4-triazole: C₂H₅N₅, M_r = 99.11, Monoclinic, P2(1)/c, a = 10.652(4), b = 4.3411(14), c = 10.822(4) Å, a = 90(4), b = 118.714(4), g = 90°, V = 0.4389(2) nm³, Z = 4, Dc = 1.500 g cm^-3, μ = 0.113 mm^-1, F(000) = 208, R = 0.0354 and wR = 0.0936. Crystal data of 3,5-dinitro-1,2,4-triazole: C₂H₃N₅O₅, M_r = 177.09, Orthorhombic, P2(1)2(1)2(1), a = 4.937(3), b = 9.344(5), c = 140447(7) Å, a = 90, b = 90, g = 90°, V = 0.6665(6) nm³, Z = 4, Dc = 1.765 g cm^-3, μ = 0.171 mm^-1, F(000) = 360, R = 0.0555 and wR = 0.1772.

Keywords

N-amination reaction N-amino compounds Synthesis Characterization Crystal Structure

Li, Y.-N., Liu, N., Su, P.-F., Wang, Y.-L., Ge, Z.-X., Li, H., & Wang, B.-Z. (2014). Synthesis and Structural Characterization of N-Amino Compounds. Asian Journal of Chemistry, 26(21), 7151–7156. https://doi.org/10.14233/ajchem.2014.16529

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R.P. Singh, H.X. Gao, D.T. Meshri and J.M. Shreeve, Struct. Bond., 125, 35 (2007); doi:10.1007/430_2006_055.

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T.M. Klapötke and D.G. Piercey, Inorg. Chem., 50, 2732 (2011); doi:10.1021/ic200071q.

Y.-L. Wang, F.-Q. Zhao, Y.-P. Ji, Q. Pan, J.-H. Yi, T. An, W. Wang, T. Yu and X.-M. Lu, J. Anal. Appl. Pyrolysis, 98, 231 (2012); doi:10.1016/j.jaap.2012.08.014.

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Issue

Vol. 26 No. 21 (2014): Vol 26 Issue 21

Synthesis and Structural Characterization of N-Amino Compounds

Corresponding Author(s) : Ya-Nan Li

Abstract

Keywords

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