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Vol. 26 No. 20 (2014)

Copyright (c) 2014 Yuhai Tang*, Xiangju Cui

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Metal Ion-Driven Assembly of Cd(II) Coordination Polymer Constructed by Asymmetric Diphenic acid and Imidazole-Containing Ligand: Syntheses, Crystal Structures and Luminescent Properties

https://doi.org/10.14233/ajchem.2014.17655
Yuhai Tang*
College of Chemical Engineering and Environment, Weifang University of Science and Technology, Weifang 262700, Shandong P.R. China *Corresponding author: E-mail: dzwanggy@163.com
Xiangju Cui
College of Chemical Engineering and Environment, Weifang University of Science and Technology, Weifang 262700, Shandong P.R. China *Corresponding author: E-mail: dzwanggy@163.com

Corresponding Author(s) : Yuhai Tang*

Asian Journal of Chemistry, Vol. 26 No. 20 (2014)

Abstract

A new metal coordination polymer, [Cd(bpdc)(L)0.5](1) [H2bpdc = biphenyl-2,4'-dicarboxylic acid and L = 1,4-bis(2-methyl imidazol-3-ium-1-yl)biphenyl], has been synthesized and characterized by single-crystal X-ray diffraction, elemental analysis and IR spectra. Complex [Cd(bpdc)(L)0.5](1), is, triclinicspace group P-1 with a = 8.673 (5) Å, b = 9.658 (5) Å, c = 11.493 (5) Å, b = 85.169 (5)°,V = 917.1 (8)Å3, Z = 1, Mr = 471.75, Dc = 1.708 g/cm3, F(000) = 470 and μ = 1.221 mm-1. Complex 1 features a 2D sql topological net.

Keywords

Crystal structure Cadmium(II) Coordination polymer.
Tang*, Y., & Cui, X. (2014). Metal Ion-Driven Assembly of Cd(II) Coordination Polymer Constructed by Asymmetric Diphenic acid and Imidazole-Containing Ligand: Syntheses, Crystal Structures and Luminescent Properties. Asian Journal of Chemistry, 26(20), 7081–7082. https://doi.org/10.14233/ajchem.2014.17655
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