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Copyright (c) 2014 Muhammad Shoaib, Hassan M. Al-Swaidan*
This work is licensed under a Creative Commons Attribution 4.0 International License.
Effect of CO2 Flow Rate on the Synthesis of Sliced Activated Carbon from Date Palm Tree Fronds (Agro Waste) by Physical Activation
Corresponding Author(s) : Muhammad Shoaib
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
Among all the date producing countries, Saudi Arabia produced around 15 % of the total production around the world. During the pruning process of date palm trees, fronds are considered as a agro waste material. Due to the voluminous availability, the date palm fronds are considered as a starting material for activated carbon (AC) production. The BET surface areas of the activated carbons prepared at a CO2 flow rate of 25, 50, 100, 150, 200 and 250 mL/min after 0.5 h activation time are 610,1094, 854, 877, 866 and 886 m2/g, respectively. The activated carbon prepared at a flow rate of 50 mL/min attains larger surface area 1094 m2/g. Effect of CO2 flow rate on the synthesis strongly affects the BET surface area and pore volume, they both increases at a flow rate from 25 to 50 mL/min from 25 to 50 mL/min, whereas a constant behaviour were observed at a flow rate of CO2 from 100 to 250 mL/min. Moreover by increasing the CO2 flow rate the yield decreases linearly from 23.25 to 14.70 %.
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- A. Al-Abbad, M. Al-Jamal, Z. Al-Elaiw, F. Al-Shreed and H. Belaifa, J. Develop. Agric. Eco., 3, 463 (2011).
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- N.R. Bishnoi, M. Bajaj, N. Sharma and A. Gupta, Bioresour. Technol., 91, 305 (2004).
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- O. Ioannidou and A. Zabaniotou, Renew. Sustain. Energy Rev., 11, 1966 (2007).
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- M. Jagtoyen, M. Thwaites, J. Stencel, B. Mcenaney and F. Derbyshire, Carbon, 30, 1089 (1992).
- J. Pastor-Villegas, V. Gomez-Serrano, C.J. Duran-Valle and F.J. Higes-Rolando, J. Anal. Appl. Pyrolysis, 50, 1 (1999).
References
A. Al-Abbad, M. Al-Jamal, Z. Al-Elaiw, F. Al-Shreed and H. Belaifa, J. Develop. Agric. Eco., 3, 463 (2011).
S.A.J. Radwan, The 6th Saudi Engineering Conference, pp. 217-219 (2002).
W. Li, K. Yang, J. Peng, L. Zhang, S. Guo and H. Xia, Ind. Crops Prod., 28, 190 (2008).
N.H. Phan, S. Rio, C. Faur, L. Le Coq, P. Le Cloirec and T.H. Nguyen, Carbon, 44, 2569 (2006).
C.J. Kirubakaran, K. Krishnaiah and S.K. Seshadri, Ind. Eng. Chem. Res., 30, 2411 (1991).
N.R. Bishnoi, M. Bajaj, N. Sharma and A. Gupta, Bioresour. Technol., 91, 305 (2004).
M. Inyang, B. Gao, W. Ding, P. Pullammanappallil, A.R. Zimmerman and X. Cao, Sep. Sci. Technol., 46, 1950 (2011).
O. Ioannidou and A. Zabaniotou, Renew. Sustain. Energy Rev., 11, 1966 (2007).
B.K. Hamad, A.M. Noor, A.R. Afida and M.N. Mohd Asri, Desalination, 257, 1 (2010).
B.H. Hameed, A.A. Ahmad and N. Aziz, Chem. Eng. J., 133, 195 (2007).
T. Ahmad, M. Danish, M. Rafatullah, A. Ghazali, O. Sulaiman, R. Hashim and M.N.M. Ibrahim, Environ. Sci. Pollut. Res., 19, 1464 (2012).
J. Matos, C. Nahas, L. Rojas and M. Rosales, J. Hazard. Mater., 196, 360 (2011).
M.A. Di´az-Di´ez, V. Go´mez-Serrano, C. Fernández González, E.M. Cuerda-Correa and A. Macías-García, Appl. Surf. Sci., 238, 309 (2004).
M. Danish, R. Hashim, M.N.M. Ibrahim, M. Rafatullah, T. Ahmad and O. Sulaiman, BioResources, 6, 3019 (2011).
M. Danish, R. Hashim, M.N.M. Ibrahim, M. Rafatullah and O. Sulaiman, J. Anal. Appl. Pyrolysis, 97, 19 (2012).
A. El Nemr, A. Khaled, O. Abdelwahab and A. El-Sikaily, J. Hazard. Mater., 152, 263 (2008).
N.M. Haimour and S. Emeish, Waste Manage., 26, 651 (2006).
N. Mohamad Nor, L.C. Lau, K.T. Lee and A.R. Mohamed, J. Environ. Chem. Eng., 1, 658 (2013).
M. Shoaib and H. M. Al-Swaidan, Asian J. Chem., 26, 5295 (2014).
Th. El-Nabarawy, N.Sh. Petro and S. Abdel-Aziz, Adsorp. Sci. Technol., 15, 47 (1997).
V. Gomez-Serrano, J. Pastor-Villegas, A. Perez-Florindo, C. Duran-Valle and C. Valenzuela-Calahorro, J. Anal. Appl. Pyrolysis, 36, 71 (1996).
M. Jagtoyen, M. Thwaites, J. Stencel, B. Mcenaney and F. Derbyshire, Carbon, 30, 1089 (1992).
J. Pastor-Villegas, V. Gomez-Serrano, C.J. Duran-Valle and F.J. Higes-Rolando, J. Anal. Appl. Pyrolysis, 50, 1 (1999).