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Copyright (c) 2014 K. Özdemir1, I. Toröz2, V. Uyak3
This work is licensed under a Creative Commons Attribution 4.0 International License.
Relationship Among Chlorine Dose, Reaction Time and Bromide Ions on Trihalomethane Formation in Drinking Water Sources in Istanbul, Turkey
Corresponding Author(s) : K. Özdemir1
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
We investigate the effects of factors such as chlorine dose, reaction time and bromide ions on the formation and speciation of trihalomethanes during the chlorination of Istanbul reservoirs such as Terkos lake water, Büyükçekmece lake water and Ömerli lake water. The experimental results showed that approximately 50 % of trihalomethane formation was observed in the first 4 h of reaction time in chlorinated Terkos lake water, Büyükçekmece lake water and Ömerli lake water, respectively. Trihalomethane concentrations increased with increasing chlorine dosage and reaction time. Chloroform was the major trihalomethane species forming as a result of the chlorinated raw water samples. On the other hand, bromide ions play a great significant role in the distribution of trihalomethane species. The bromine and chlorine incorporation ratios were strongly related to natural organic matter precursors and bromide levels in Terkos lake water, Büyükçekmece lake water and Ömerli lake water. The percentage of bromine incorporation was much higher than that of chlorine in all chlorinated water samples.
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- W.E. Elshorbagy, H. Abu-Qadais and M.K. Elsheamy, Water Res., 34, 3431 (2000).
- S.K. Golfinopoulos and G.B. Arhonditsis, Chemosphere, 47, 107 (2000).
- M. Palacios, J.F. Pampillon and M.E. Rodriguez, Water Res., 34, 1002 (2000).
- R. Sadiq and M.J. Rodriguez, Sci. Total Environ., 321, 21 (2004).
- G. Hua and D.A. Reckhow, Water Res., 46, 4208 (2012).
- R.J. Bull, L.S. Birnbaum, K.P. Cantor, J.B. Rose, B.E. Butterworth, R. Pegram and J. Tuomisto, Appl. Toxicol., 28, 155 (1995).
- V. Uyak, I. Toroz and S. Meric, Desalination, 176, 91 (2005).
- M.I. Cedergren, A.J. Selbing, O. Löfman and A.J. Bengt, Environ. Res., 89, 124 (2002).
- I. Ivancev-Tumbas, B. Dalmacija, Z. Tamas and E. Karlovic, Water Res., 33, 3715 (2002).
- C.Y. Yang, B.H. Cheng, S.S. Tsai, T.N. Wu, M.C. Lin and K.C. Lin, Environ. Health Perspect., 108, 765 (2000).
- WHO, Environmental Health Criteria 216: Disinfectants and Disinfectant By-products, World Health Organization, Geneva (2000).
- S.D. Richardson, M.J. Plewa, E.D. Wagner, R. Schoeny and D.M. Demarini, Mutat. Res., 636, 178 (2007).
- TMH, Regulation Concerning Water Intended for Human Consumption, Turkish Ministry of Health, Official News Paper, No: 25730, Ankara, (2012).
- A. Adin, J. Katzhendler, D. Alkaslassy and C. Rav-Acha, Water Res., 25, 797 (1991).
- G.A. Cowman and P.C. Singer, Environ. Sci. Technol., 30, 16 (1996).
- J.P. Croue G.V. Korshin and M.M. Benjamin, Characterization of Natural Organic Matter in Drinking Water, American Water Works Association Research Foundation, Denver, CO (2000).
- B.G. Oliver and J. Lawrance, J. Am. Water Works Assoc., 71, 161 (1979).
- S.J. Fleischacker and S.J. Randtke, J. Am. Water Works Assoc., 50, 132 (1983).
- D.L. Norwood, J.D. Johnson, R.F. Christman, J.R. Hass and M.J. Bobenrieth, Environ. Sci. Technol., 14, 187 (1980).
- J.J. Rook, Water Treat. Exam., 2, 234 (1974).
- D.A. Reckhow and P.C. Singer, Environ., Impact Health Effects, 5, 1229 (1985).
- J.D. Johnson and J.N. Jensen, J. Am. Water Works Assoc., 78, 156 (1986).
- G.L. Amy, P.A. Chadik and Z. Chowdhury, J. Am. Water Works Assoc., 79, 89 (1987).
- I. Toroz and V. Uyak, Desalination, 176, 127 (2005).
- J.C. Morris, in ed.: R.L. Jolley, The Chemistry of Aqueous Chlorine in Relation to Water Chlorination, Ann Arbor Science, Ann Arbor, MI (1978).
- A. Kampioti, Water Res., 36, 2596 (2002).
- J.M. Symons, S.W. Krasner, L.A. Simms and M.J. Sclimenti, J. Am. Water Works Assoc., 85, 51 (1993).
- T.V. Luong, C.J. Peters and R. Perry, Environ. Sci. Technol., 16, 473 (1982).
- S. Hu, F. Yang, S. Liu and L. Yu, Water Res., 43, 381 (2009).
- V. Uyak and I. Toroz, J. Hazard. Mater., 149, 445 (2007).
- G.A. Cowman and P.C. Singer, Environ. Sci. Technol., 30, 16 (1996).
- J. Sohn, G. Amy and Y. Yoon, Water Air Soil Pollut., 174, 265 (2006).
- R.E. Rathbun, Sci. Total Environ., 192, 111 (1996).
- I.N. Najm and S.W. Krasner, J. Am. Water Works Assoc., 87, 106 (1995).
- T.D. Lekkas and A.D. Nikolaou, Water Qual. Res. J. Canada, 39, 149 (2004).
- APHA, AWWA, WEF, Standard Methods for the Examination of Water and Wastewater, Washington, DC, edn 21 (2005).
- S.W. Krasner, M.J. McGuire, N.L. Jacangelo, K.M. Patania and E.M. Aieta, J. Am. Water Works Assoc., 81, 41 (1989).
- X. Yang, C. Shang and J.C. Huang, Water Res., 39, 4755 (2005).
- X. Yang and C. Shang, Environ. Sci. Technol., 38, 4995 (2004).
- J.W. Huang and H.H. Yeh, J. Environ. Sci. Health A, 32, 2311 (1997).
- G.H. Hua and D.A. Reckhow, Environ. Sci. Technol., 41, 3309 (2007).
- L. Heller-Grossman, J. Manka, B. Limoni-Relis and M. Rebhun, Water Res., 27, 1323 (1993).
References
W.E. Elshorbagy, H. Abu-Qadais and M.K. Elsheamy, Water Res., 34, 3431 (2000).
S.K. Golfinopoulos and G.B. Arhonditsis, Chemosphere, 47, 107 (2000).
M. Palacios, J.F. Pampillon and M.E. Rodriguez, Water Res., 34, 1002 (2000).
R. Sadiq and M.J. Rodriguez, Sci. Total Environ., 321, 21 (2004).
G. Hua and D.A. Reckhow, Water Res., 46, 4208 (2012).
R.J. Bull, L.S. Birnbaum, K.P. Cantor, J.B. Rose, B.E. Butterworth, R. Pegram and J. Tuomisto, Appl. Toxicol., 28, 155 (1995).
V. Uyak, I. Toroz and S. Meric, Desalination, 176, 91 (2005).
M.I. Cedergren, A.J. Selbing, O. Löfman and A.J. Bengt, Environ. Res., 89, 124 (2002).
I. Ivancev-Tumbas, B. Dalmacija, Z. Tamas and E. Karlovic, Water Res., 33, 3715 (2002).
C.Y. Yang, B.H. Cheng, S.S. Tsai, T.N. Wu, M.C. Lin and K.C. Lin, Environ. Health Perspect., 108, 765 (2000).
WHO, Environmental Health Criteria 216: Disinfectants and Disinfectant By-products, World Health Organization, Geneva (2000).
S.D. Richardson, M.J. Plewa, E.D. Wagner, R. Schoeny and D.M. Demarini, Mutat. Res., 636, 178 (2007).
TMH, Regulation Concerning Water Intended for Human Consumption, Turkish Ministry of Health, Official News Paper, No: 25730, Ankara, (2012).
A. Adin, J. Katzhendler, D. Alkaslassy and C. Rav-Acha, Water Res., 25, 797 (1991).
G.A. Cowman and P.C. Singer, Environ. Sci. Technol., 30, 16 (1996).
J.P. Croue G.V. Korshin and M.M. Benjamin, Characterization of Natural Organic Matter in Drinking Water, American Water Works Association Research Foundation, Denver, CO (2000).
B.G. Oliver and J. Lawrance, J. Am. Water Works Assoc., 71, 161 (1979).
S.J. Fleischacker and S.J. Randtke, J. Am. Water Works Assoc., 50, 132 (1983).
D.L. Norwood, J.D. Johnson, R.F. Christman, J.R. Hass and M.J. Bobenrieth, Environ. Sci. Technol., 14, 187 (1980).
J.J. Rook, Water Treat. Exam., 2, 234 (1974).
D.A. Reckhow and P.C. Singer, Environ., Impact Health Effects, 5, 1229 (1985).
J.D. Johnson and J.N. Jensen, J. Am. Water Works Assoc., 78, 156 (1986).
G.L. Amy, P.A. Chadik and Z. Chowdhury, J. Am. Water Works Assoc., 79, 89 (1987).
I. Toroz and V. Uyak, Desalination, 176, 127 (2005).
J.C. Morris, in ed.: R.L. Jolley, The Chemistry of Aqueous Chlorine in Relation to Water Chlorination, Ann Arbor Science, Ann Arbor, MI (1978).
A. Kampioti, Water Res., 36, 2596 (2002).
J.M. Symons, S.W. Krasner, L.A. Simms and M.J. Sclimenti, J. Am. Water Works Assoc., 85, 51 (1993).
T.V. Luong, C.J. Peters and R. Perry, Environ. Sci. Technol., 16, 473 (1982).
S. Hu, F. Yang, S. Liu and L. Yu, Water Res., 43, 381 (2009).
V. Uyak and I. Toroz, J. Hazard. Mater., 149, 445 (2007).
G.A. Cowman and P.C. Singer, Environ. Sci. Technol., 30, 16 (1996).
J. Sohn, G. Amy and Y. Yoon, Water Air Soil Pollut., 174, 265 (2006).
R.E. Rathbun, Sci. Total Environ., 192, 111 (1996).
I.N. Najm and S.W. Krasner, J. Am. Water Works Assoc., 87, 106 (1995).
T.D. Lekkas and A.D. Nikolaou, Water Qual. Res. J. Canada, 39, 149 (2004).
APHA, AWWA, WEF, Standard Methods for the Examination of Water and Wastewater, Washington, DC, edn 21 (2005).
S.W. Krasner, M.J. McGuire, N.L. Jacangelo, K.M. Patania and E.M. Aieta, J. Am. Water Works Assoc., 81, 41 (1989).
X. Yang, C. Shang and J.C. Huang, Water Res., 39, 4755 (2005).
X. Yang and C. Shang, Environ. Sci. Technol., 38, 4995 (2004).
J.W. Huang and H.H. Yeh, J. Environ. Sci. Health A, 32, 2311 (1997).
G.H. Hua and D.A. Reckhow, Environ. Sci. Technol., 41, 3309 (2007).
L. Heller-Grossman, J. Manka, B. Limoni-Relis and M. Rebhun, Water Res., 27, 1323 (1993).