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Vol. 26 No. 20 (2014)

Copyright (c) 2014 Janardhan Reddy Koduru1, Lakshmi Prasanna Lingamdinne2, Yoon-Young Chang2, C. Ramach

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Enhanced Extraction and Separation of Zr(IV) and Hf(IV) from Acidic Chloride Solutions Using 4-Sebacoylbis(1-phenyl-3-methyl-5-pyrazolone) in Presence of Crown Ethers

https://doi.org/10.14233/ajchem.2014.17140
Janardhan Reddy Koduru1
1Graduate School of Environmental Studies, Kwangwoon University, Seoul, 139-701, Republic of Korea 2Department of Environmental Engineering, Kwangwoon University, Seoul, 139-701, Republic of Korea 3Srikalahastheeswara Institute of Technology, Srikalahasti-517 640, India *Corresponding author: Fax: +82 2 9185774; Tel: +82 2 9405496; E-mail: reddyjchem@gmail.com
Lakshmi Prasanna Lingamdinne2
1Graduate School of Environmental Studies, Kwangwoon University, Seoul, 139-701, Republic of Korea 2Department of Environmental Engineering, Kwangwoon University, Seoul, 139-701, Republic of Korea 3Srikalahastheeswara Institute of Technology, Srikalahasti-517 640, India *Corresponding author: Fax: +82 2 9185774; Tel: +82 2 9405496; E-mail: reddyjchem@gmail.com
Yoon-Young Chang2
1Graduate School of Environmental Studies, Kwangwoon University, Seoul, 139-701, Republic of Korea 2Department of Environmental Engineering, Kwangwoon University, Seoul, 139-701, Republic of Korea 3Srikalahastheeswara Institute of Technology, Srikalahasti-517 640, India *Corresponding author: Fax: +82 2 9185774; Tel: +82 2 9405496; E-mail: reddyjchem@gmail.com
C. Ramach
1Graduate School of Environmental Studies, Kwangwoon University, Seoul, 139-701, Republic of Korea 2Department of Environmental Engineering, Kwangwoon University, Seoul, 139-701, Republic of Korea 3Srikalahastheeswara Institute of Technology, Srikalahasti-517 640, India *Corresponding author: Fax: +82 2 9185774; Tel: +82 2 9405496; E-mail: reddyjchem@gmail.com

Corresponding Author(s) : Janardhan Reddy Koduru1

Asian Journal of Chemistry, Vol. 26 No. 20 (2014)

Abstract

Synergistic extraction behaviour and selectivity in the separation of Zr(IV) and Hf(IV) were examined using synthesized 4-sebacoylbis(1-phenyl-3-methyl-5-pyrazolone) (H2SbBP) in presence of various crown ethers (CEs), such as 18-crown-6 (18C6), dicylohexano-18-crown-6 (DC18C6) and benzo-15-crown-5 (B15C5) from acidic chloride solutions. The preceding results demonstrate that Zr(IV) and Hf(IV) were synergistically extracted into chloroform with H2SbBP and crown ethers as ZrO(HSbBP)2-CE and HfO-(HSbBP)2-CE, respectively. The synergistic complexation strength of Zr(IV) and Hf(IV) was follows in order DC18C6 > 18C6 > B15C5. The addition of crown ethers to H2SbBP in chloroform not only enhance the extraction but also improves the selectivity in the separation of Zr(IV) and Hf(IV), especially, in presence of B15C5 (Zr(IV)/Hf(IV) = 13.18), where compared to H2SbBP alone (Zr(IV)/Hf(IV) =1.17) and other typical reports in literature. On the other hand the selectivity moderately decreased by the addition of DC18C6 and 18C6 to the synergistic solvent system.

Keywords

Zr(IV) and Hf(IV) separation Extraction Synergistic solvent extraction Pyrazolones Crown ethers.
Reddy Koduru1, J., Prasanna Lingamdinne2, L., Chang2, Y.-Y., & Ramach, C. (2014). Enhanced Extraction and Separation of Zr(IV) and Hf(IV) from Acidic Chloride Solutions Using 4-Sebacoylbis(1-phenyl-3-methyl-5-pyrazolone) in Presence of Crown Ethers. Asian Journal of Chemistry, 26(20), 6885–6890. https://doi.org/10.14233/ajchem.2014.17140
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References
  1. A.B.V. Da Silva and P.A. Distin, CIM Bull., 91, 221 (1998).
  2. S. Besoluk, M. Küçükislamoglu, M. Zengin, M. Arslan and M. Nebioglu, Turk. J. Chem., 34, 411 (2010).
  3. P.I. Ivanov, G.A. Bojikov, A.N. Priemyshev, G.D. Bontchev, O.D. Maslov, M.V. Milanov and S.N. Dmitriev, J. Radioanal. Nucl. Chem., 258, 639 (2003).
  4. S. Osváth, N. Vajda, Z. Stefánka, É. Széles and Z. Molnár, J. Radioanal. Nucl. Chem., 287, 459 (2011).; G.H. Zohuri, S. Damavandi, R. Sandaroos and S. Ahmadjo, Polym. Bull., 66, 1051 (2011).
  5. D. Sathiyamoorthy, S.M. Shetty, D.K. Bose and C.K. Gupta, High Temp. Mater. Process., 18, 213 (1999).
  6. X.M. Zhong and Y.H. Wu, J. Radioanal. Nucl. Chem., 292, 355 (2012).
  7. K.J. Reddy, J.R. Kumar, M.L.P. Reddy, A.V. Reddy, H.-S. Park and K.-H. Choo, Sep. Sci. Technol., 44, 2022 (2009).
  8. A.D. Silva, E.E. Ammouri and P.A. Distin, Can. Metall. PQ, 39, 37 (2000).
  9. K.J. Reddy, J.R. Kumar, A.V. Reddy and M.L.P. Reddy, Solvent Extr. Ion Exch., 24, 419 (2006).
  10. B. Nandi, N.R. Das and S.N. Bhattacharyya, Solvent Extr. Ion Exch. Rev., 1, 141 (1983).
  11. N.R. Das and S. Lahiri, Solvent Extr. Ion Exch., 9, 337 (1991).
  12. K.J. Reddy, A.V. Reddy, B.S. Shaibu and M.L.P. Reddy, Radiochim. Acta, 95, 289 (2007).
  13. R. Pavithran and M.L.P. Reddy, Anal. Chim. Acta, 536, 219 (2005).
  14. Y. Wei-fan, Y. Shuanggui, X. Yanbing, X. Yonghou, F. Ke-ming and X. Bing, J. Radioanal. Nucl. Chem., 256, 149 (2003).
  15. R. Bose and D.S.R. Murty, J. Radioanal. Nucl. Chem., 258, 373 (2003).
  16. B. Mokhtari, K. Pourabdollah and N. Dallali, J. Radioanal. Nucl. Chem., 287, 921 (2011).
  17. S.R. Sabale, D.V. Jadhav and B.S. Mohite, J. Radioanal. Nucl. Chem., 284, 273 (2010).
  18. M. Ashram and N. Al-ghezawi, Turk. J. Chem., 33, 647 (2009).
  19. G. Uysal, S. Aslan, F. F. Taktak and S. Memon, Turk. J. Chem., 32, 635 (2008).
  20. H.- Rehman, A. Ali, J. Anwar and W. Yawar, J. Radioanal. Nucl. Chem., 267, 421 (2006).
  21. K. Saberyan, A.H. Meysami, F. Rashchi and E. Zolfonoun, Chin. J. Chem., 26, 2067 (2008).
  22. A.M. Donia, A.A. Atia, A.M. Daher and E.A. Elshehy, J. Dispersion Sci. Tech., 32, 193 (2011).
  23. A. Favre-Re'guillon, K. Fiaty, P. Laurent, L. Poriel, S. Pellet-Rostaing and M. Lemaire, Ind. Eng. Chem. Res., 46, 1286 (2007).
  24. M. Taghizadeh, M. Ghanadi and E. Zolfonoun, J. Nucl. Mater., 412, 334 (2011).
  25. M. Smolik, A. Jakóbik-Kolon and M. Poranski, Hydrometallurgy, 95, 350 (2009).
  26. S. Banerjee and S. Basu, J. Radioanal. Nucl. Chem., 262, 733 (2004).
  27. Z. Marczenko, Spectrophotometric Determination of Elements, John Wiley & Sons, New Yark (1976).
  28. C.J. Pedersen, J. Am. Chem. Soc., 89, 7017 (1967).
  29. S.K. Sahu, V. Chakravortty, M.L.P. Reddy and T.R. Ramamohan, Talanta, 51, 523 (2000).
  30. P.K. Mohapatra and V.K. Manchanda, Radiochim. Acta, 55, 193 (1991).
  31. Y. Hasegawa, T. Nakano, Y. Odori and Y. Ishikawa, Bull. Chem. Soc. Jpn., 57, 8 (1984).
  32. J.N. Mathur and G.R. Choppin, Solvent Extr. Ion Exch., 11, 1 (1993).
  33. T. Sekine, T. Saitou and H. Iga, Bull. Chem. Soc. Jpn., 56, 700 (1983).
  34. K. Torkestani, G.J. Goetz-Grandmont and J.P. Brunette, Analusis, 28, 324 (2000).
  35. Y. Liu, B.H. Han and Y.T. Chen, Coord. Chem. Rev., 200-202, 53 (2000).
  36. R.M. Izatt, J.S. Bradshaw, S.A. Nielsen, J.D. Lamb, J.J. Christensen and D. Sen, Chem. Rev., 85, 271 (1985).
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