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Copyright (c) 2014 Haitao Zhao1, Ruiping Liu1, Shaohong Liu2, Ruiting Ma1
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation and Properties of TiO2 Microparticles and its Composites with Polypyrrole
Corresponding Author(s) : Haitao Zhao1
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
Spherical anatase TiO2 microparticles with good crystallinity were successfully synthesized by the homogeneous precipitation under mild conditions with ammonium fluorotitanate as the titanium source and urea as the precipitant. Then the TiO2 microparticles were used as nucleus for the preparation of TiO2/polypyrrole(TiO2/PPy) composite. TiO2/PPy composite was prepared by in situ polymerization of pyrrole on TiO2 microparticles. The structural characteristics, morphology and dielectric properties of the composite powders were obtained by X-ray diffraction, scanning electron microscope and network analyzer. The results show that TiO2 microspheres obtained in this work are anatase-type. The higher reaction temperature leads to smaller anatase microspheres. The morphologies of the final particles change into irregular with the increase of the reaction time. The e¢, e¢¢ and tande value for TiO2/PPy composite are higher than polypyrrole in the frequency range of 8.2-12.4 GHz. The tande value for TiO2/PPy has achieved a maximum of 0.57 at 11.9 GHz.
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- J. Jiang, L. Ai and L. Liu, Mater. Lett., 64, 888 (2010).
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- M. Ferenets and A. Harlin, Thin Solid Films, 515, 5324 (2007).
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- Y.X. Zhang, G.H. Li, Y.X. Jin, Y. Zhang, J. Zhang and L.D. Zhang, Chem. Phys. Lett., 365, 300 (2002).
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References
J. Jiang, L. Ai and L. Liu, Mater. Lett., 64, 888 (2010).
J. Stejskal, M. Trchová, J. Brodinová, P. Kalenda, S.V. Fedorova, J. Prokeš and J. Zemek, J. Colloid Interf. Sci., 298, 87 (2006).
S.M. Abbas, A.K. Dixit, R. Chatterjee and T.C. Goel, J. Magn. Magn. Mater., 309, 20 (2007).
S. Kumar, V. Singh, S. Aggarwal, U.K. Mandal and R.K. Kotnala, Compos. Sci. Technol., 70, 249 (2010).
S.A. Joshi, S.A. Gangal and S.K. Gupta, Sens. Actuators B, 156, 938 (2011).
M. Ferenets and A. Harlin, Thin Solid Films, 515, 5324 (2007).
C. Yang, P. Liu, J. Guo and Y. Wang, Synth. Met., 160, 592 (2010).
B.K. Sharma, N. Khare, R. Sharma, S.K. Dhawan, V.D. Vankar and H.C. Gupta, Compos. Sci. Technol., 69, 1932 (2009).
C. Yang, Y. Gung, W. Hung, T.H. Ting and K.H. Wu, Compos. Sci. Technol., 70, 466 (2010).
X. Zhang, L. Song, X. Zeng and M. Li, Energy Procedia, 17, 422 (2012).
M. Afuyoni, G. Nashed and I.S.S.M. Nasser, Energy Procedia., 6, 11 (2011).
H. Song, M. Dai, Y. Guo and Y.-J. Zhang, Fuel Process. Technol., 96, 228 (2012).
J. Zhou, Y. Cheng and J. Yu, J. Photochem. Photobiol. Chem., 223, 82 (2011).
Q. Li, C. Zhang and J. Li, J. Alloys Comp., 509, 1953 (2011).
J. Du, W. Chen, C. Zhang, Y. Liu, C. Zhao and Y. Dai, Chem. Eng. J., 170, 53 (2011).
Y.X. Zhang, G.H. Li, Y.X. Jin, Y. Zhang, J. Zhang and L.D. Zhang, Chem. Phys. Lett., 365, 300 (2002).
J.G. Li, T. Ishigaki and X. Sun, J. Phys. Chem. C, 111, 4969 (2007).
F. Deng, Y. Li, X. Luo, L. Yang and X. Tu, Colloids Surf. A, 395, 183 (2012).
P. Su and L. Huang, Sens. Actuators B, 123, 501 (2007).
E. Turac and E. Sahmetlioglu, Synth. Met., 160, 169 (2010).
S. Liu, X. Sun, J. Li, X. Li, Z. Xiu and D. Huo, Eur. J. Inorg. Chem., 1214 (2009).