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Copyright (c) 2014 Jun Qiao, Meilan Chen, Feilin Hao, Xianghong Huang*
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Photocatalytic Degradation of Acidic Black 10B of Aqueous Solution Using BaxSr1-xFe0.5Co0.5O3-d
Corresponding Author(s) : Jun Qiao
Asian Journal of Chemistry,
Vol. 26 No. 20 (2014)
Abstract
Two kinds of perovskite BaxSr1-xFe0.5Co0.5O3-d (x = 0.2, 0.4) were prepared by citrate method and were sintered at 850 °C for 8 h. The obtained products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM). The photocatalytic degradation efficiency of acidic black 10B of aqueous solution was evaluated in different reaction conditions under the irradiation of UV. Several operational parameters affecting the photocatalytic degradation of acidic black 10B under the irradiation of UV were studied systematically,including irradiation time, photocatalyst dose, acidic black 10B initial concentration, pH value of initial acidic black 10B solution and amount of H2O2 (1 %) added. The results showed that perovskite-type BaxSr1-xFe0.5Co0.5O3-d exhibited excellent photocatalytic properties.
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S.A. Ong, K. Uchiyama, D. Inadama and K. Yamagiwa, J. Hazard. Mater., 165, 696 (2009).
F. Han, V.S.R. Kambala, M. Srinivasan, D. Rajarathnam and R. Naidu, Appl. Catal. A, 359, 25 (2009).
W.J. Lau and A.F. Ismail, Desalination, 245, 321 (2009).
F. Herrera, A. Lopez, G. Mascolo, P. Albers and J. Kiwi, Water Res., 35, 750 (2001).
W.Z. Tang and H. An, Chemosphere, 31, 157 (1995).
V. Meshko, L. Markovska, M. Mincheva and A.E. Rodrigues, Water Res., 35, 3357 (2001).
W.S. Kuo and P.H. Ho, Chemosphere, 45, 77 (2001).
C. Galindo, P. Jacques and A. Kalt, Chemosphere, 45, 997 (2001).
J. Tang, Z. Zou, J. Yin and J. Ye, Chem. Phys. Lett., 382, 175 (2003).
W.F. Yao, X.H. Xu, H. Wang, J.T. Zhou, X.N. Yang, Y. Zhang, S.X. Shang and B.B. Huang, Appl. Catal. B, 52, 109 (2004).
P. Wongkalasin, S. Chavadej and T. Sreethawong, Colloids Surf. A, 384, 519 (2011).
J.H. Bi, L. Wu, J. Li, Z.H. Li, X.X. Wang and X.Z. Fu, Acta Mater., 55, 4699 (2007).
T.K. Ghorai, D. Dhak, S. Dalai and P. Pramanik, Mater. Res. Bull., 43, 1770 (2008).
T.K. Ghorai, D. Dhak, S. Dalai and P. Pramanik, J. Alloys Comp., 463, 390 (2008).
Y.N. Huo, Y. Jin and Y. Zhang, J. Mol. Catal. Chem., 331, 15 (2010).
S.O. Alfaro and A. Martínez-de la Cruz, Appl. Catal. A, 383, 128 (2010).
D.R. Liu, Y.S. Jiang and G.M. Gao, Chemosphere, 83, 1546 (2011).
Y. Ku, L.C. Wang, C.M. Ma and Y.C. Chou, Water Air Soil Pollut., 215, 97 (2011).
W.M. Hou and Y. Ku, J. Alloys Comp., 509, 5913 (2011).
K. Onozuka, Y.H. Kawakami, H. Imai, T. Yokoi, T. Tatsumi and J.N. Kondo, J. Solid State Chem., 192, 87 (2012).
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X.H. Huang, L.Z. Pei, C.G. Fan and Q.F. Zhang, Inorg. Mater., 46, 1225 (2010).
A. Martínez-de la Cruz and S. Obregón Alfaro, J. Mol. Catal. A, 320, 85 (2010).
X.H. Huang, J. Qiao and Q.F. Zhang, Adv. Mater. Res., 549, 141 (2012).
M.R. Hoffmann, S.T. Martin, W. Choi and D.W. Bahnemann, Chem. Rev., 95, 69 (1995).