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Vol. 26 No. 20 (2014)

Copyright (c) 2014 Ahmed Belhakem1, Samia A. Ghomari2, Fawzi Taleb1

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This work is licensed under a Creative Commons Attribution 4.0 International License.

Carbon Monoxide Conversion Using Functionalized Clay Material with Ptn+, H+ and (Ptn+/H+) Cations

https://doi.org/10.14233/ajchem.2014.16710
Ahmed Belhakem1
1Laboratoire Synthèse Elaboration et Applications des Matériaux Minéraux, F.S.E&I/U, Mostaganem, B.P 1001, 27000 Mostaganem, Algeria 2Laboratoire M.B.A.F.S/F.S.N.V/U. Mostaganem, B.P 1001, 27000 Mostaganem, Algeria *Corresponding author: E-mail: ahmedbel39@hotmail.com; abelhakem65@yahoo.fr
Samia A. Ghomari2
1Laboratoire Synthèse Elaboration et Applications des Matériaux Minéraux, F.S.E&I/U, Mostaganem, B.P 1001, 27000 Mostaganem, Algeria 2Laboratoire M.B.A.F.S/F.S.N.V/U. Mostaganem, B.P 1001, 27000 Mostaganem, Algeria *Corresponding author: E-mail: ahmedbel39@hotmail.com; abelhakem65@yahoo.fr
Fawzi Taleb1
1Laboratoire Synthèse Elaboration et Applications des Matériaux Minéraux, F.S.E&I/U, Mostaganem, B.P 1001, 27000 Mostaganem, Algeria 2Laboratoire M.B.A.F.S/F.S.N.V/U. Mostaganem, B.P 1001, 27000 Mostaganem, Algeria *Corresponding author: E-mail: ahmedbel39@hotmail.com; abelhakem65@yahoo.fr

Corresponding Author(s) : Ahmed Belhakem1

Asian Journal of Chemistry, Vol. 26 No. 20 (2014)

Abstract

Sodium acetate intercalated halloysites, functionalized with Ptn+, H+ and (Ptn+/H+) cations, were used as catalysts in the carbon monoxide conversion reaction. Experiments were carried out at 3.5 103 torr, 523 K and H2/CO ratio (about 2) or (H2/CO = 67 %/33 % v/v). Platinum ionic species, their distribution and average size particle were determined by X-Ray absorption near edge structure (XANES) and titration of adsorbed H2 by O2 techniques, respectively. The obtained results showed that CO conversions were higher with (Ptn+/H+) than with H+ or Ptn+ cations used as catalysts. These results were in accordance with the fact that H+ and Ptn+ combination generates a higher level of acidity. The activation/deactivation process showed that catalysts could be easily regenerated after each reaction by heating at 250 °C for 5 h. For the present study, a higher selectivity toward light hydrocarbons (C1-C4) was noticed. The catalysts nature, structure and texture played a major role on the quality and quantity of the final products.

Keywords

Halloysite structure and texture Platinum oxidation states CO hydrogenation.
Belhakem1, A., A. Ghomari2, S., & Taleb1, F. (2014). Carbon Monoxide Conversion Using Functionalized Clay Material with Ptn+, H+ and (Ptn+/H+) Cations. Asian Journal of Chemistry, 26(20), 6745–6750. https://doi.org/10.14233/ajchem.2014.16710
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