Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis and Structural Characterization of Diiron Ethanedithiolate Complex [(μ-SCH2)2Fe2(CO)5]2(Ph2PCH2CH2CH2CH2PPh2) Containing Bridging Diphosphine Ligand
Corresponding Author(s) : Wei Gao
Asian Journal of Chemistry,
Vol. 26 No. 19 (2014): Vol 26 Issue 19
Abstract
A diiron ethanedithiolate complex [(μ-SCH2)2Fe2(CO)5]2(Ph2PCH2CH2CH2CH2PPh2) (1) has been prepared and characterized by spectroscopy. The title complex was synthesized by reaction of [(μ-SCH2)2]Fe2(CO)6 (A) with dppb (Ph2PCH2CH2CH2CH2PPh2) in the presence of the decarbonylating agent Me3NO·2H2O in MeCN at room temperature in 66 % yield. The new complex was characterized by IR, 1H NMR, 31P NMR and 13C NMR spectroscopy.
Keywords
Download Citation
Endnote/Zotero/Mendeley (RIS)BibTeX
- R. Cammack, Nature, 397, 214 (1999); doi:10.1038/16601.
- Y. Nicolet, C. Piras, P. Legrand, C.E. Hatchikian and J.C. Fontecilla-Camps, Structure, 7, 13 (1999); doi:10.1016/S0969-2126(99)80005-7.
- A.L. De Lacey, C. Stadler, C. Cavazza, E.C. Hatchikian and V.M. Fernandez, J. Am. Chem. Soc., 122, 11232 (2000); doi:10.1021/ja002441o.
- P.H. Zhao, Y.Q. Liu and X.A. Li, Asian J. Chem., 25, 5428 (2013).
- X.F. Liu and H.Q. Gao, J. Clust. Sci., 25, 495 (2014); doi:10.1007/s10876-013-0627-7.
- (a) X.H. Liu, J.Q. Weng, C.X. Tan, L. Pan, B.L. Wang and Z.M. Li, Asian J. Chem., 23, 4031 (2011); (b) P.Q. Chen, C.X. Tan, J.Q. Weng and X.H. Liu, Asian J. Chem., 24, 2808 (2012); (c) Y.L. Xue, Y.G. Zhang and X.H. Liu, Asian J. Chem., 24, 5087 (2012); (d) L.J. Luo, X.F. Liu and H.Q. Gao, J. Coord. Chem., 66, 1077 (2013); doi:10.1080/00958972.2013.775431.; (e) X.F. Liu and H.Q. Gao, Polyhedron, 65, 1 (2013); doi:10.1016/j.poly.2013.08.023.
- A. Winter, L. Zsolnai and G. Huttner, Z. Naturforsch. C, 37b, 1430 (1982).
References
R. Cammack, Nature, 397, 214 (1999); doi:10.1038/16601.
Y. Nicolet, C. Piras, P. Legrand, C.E. Hatchikian and J.C. Fontecilla-Camps, Structure, 7, 13 (1999); doi:10.1016/S0969-2126(99)80005-7.
A.L. De Lacey, C. Stadler, C. Cavazza, E.C. Hatchikian and V.M. Fernandez, J. Am. Chem. Soc., 122, 11232 (2000); doi:10.1021/ja002441o.
P.H. Zhao, Y.Q. Liu and X.A. Li, Asian J. Chem., 25, 5428 (2013).
X.F. Liu and H.Q. Gao, J. Clust. Sci., 25, 495 (2014); doi:10.1007/s10876-013-0627-7.
(a) X.H. Liu, J.Q. Weng, C.X. Tan, L. Pan, B.L. Wang and Z.M. Li, Asian J. Chem., 23, 4031 (2011); (b) P.Q. Chen, C.X. Tan, J.Q. Weng and X.H. Liu, Asian J. Chem., 24, 2808 (2012); (c) Y.L. Xue, Y.G. Zhang and X.H. Liu, Asian J. Chem., 24, 5087 (2012); (d) L.J. Luo, X.F. Liu and H.Q. Gao, J. Coord. Chem., 66, 1077 (2013); doi:10.1080/00958972.2013.775431.; (e) X.F. Liu and H.Q. Gao, Polyhedron, 65, 1 (2013); doi:10.1016/j.poly.2013.08.023.
A. Winter, L. Zsolnai and G. Huttner, Z. Naturforsch. C, 37b, 1430 (1982).