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Vol. 26 No. 19 (2014): Vol 26 Issue 19

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Polymerization of C9 Fraction from Ethylene Cracking Catalyzed by Al3+-Loaded Styrenic Cation Exchange Resin

https://doi.org/10.14233/ajchem.2014.17387
Jinghua Yang
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, P.R. China; Changchun University of Technology, Changchun, P.R. China
Zubin Cao
College of Petrochemical Technology, Liaoning Shihua University, Fushun, P.R. China
Yutai Qi
School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, P.R. China ; Sinopec Management Institute, Beijing, P.R. China

Corresponding Author(s) : Yutai Qi

yutaiq123@163.com

Asian Journal of Chemistry, Vol. 26 No. 19 (2014): Vol 26 Issue 19

Abstract

Studies on the chemical, copolymerization and hydrogenation modification of C9 petroleum resin are numerous, whereas those on polymerization process, particularly polymerization catalysts, are rare. The current study aimed to explore the catalyst performance of the Al3+ ion exchange resin catalyst in petroleum resin polymerization. A gel-type solid resin catalyst used for the polymerization of the ethylene cracking byproduct C9 (boiling range, 100-200 °C) was prepared by loading anhydrous AlCl3 onto strong acid styrene-type cation exchange resins. The obtained polymerizates were analyzed using an infrared spectrometer. The results showed that the Al3+-loaded styrene-type cation exchange resin resulted in the absence of elution liquids produced from the reaction system, circumventing the process of catalyst removal. The softening point of the obtained petroleum resin product was higher than the softening point of petroleum resin directly catalyzed by anhydrous AlCl3.

Keywords

C9 fraction Polyene polymerization FTIR analysis Cation exchange resin
Yang, J., Cao, Z., & Qi, Y. (2014). Polymerization of C9 Fraction from Ethylene Cracking Catalyzed by Al3+-Loaded Styrenic Cation Exchange Resin. Asian Journal of Chemistry, 26(19), 6658–6664. https://doi.org/10.14233/ajchem.2014.17387
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References
  1. F. Zongyan, Petrochem. Ind. Technol., 13, 49 (2006).
  2. W. Yinglong, J. Qingdao Univ. Sci. Technol., 24, 65 (2003).
  3. Shell Oil Company, US Patent 5212285, (1993).
  4. Chu Guang Xing Chan Ltd, CN Patent 1726231 (2006).
  5. Y. Lujun, J. Dahao, X. Jiao, M. Lei and L. Xiaonian, Petrochem. Ind. Technol., 41, 1181 (2012).
  6. L. Lanfen, Qilu Petrochem. Technol., 32, 76 (2004).
  7. H. Kai, Guangdong Petrochem. Technol., 39, 89 (2012).
  8. P. Gaocong, L. Baotian, X. Shaoji et al., Coatings Ind., 1, 39 (1998).
  9. Y. Lei, W. Shubin and X. Binglian, Guangdong Petrochem. Technol., 35, 56 (2007).
  10. P. Gaocong, L. Baotian, X. Shaoji, et al., Thermal Decomp. Mechanism Dynamics, 3, 10 (1997).
  11. Z. Qinghuan, W. Yulan, Y. Weizou, et al., J. Daqing Petroleum Institute, 19, 59 (1995).
  12. B. Keqiang, Z. Zhibing, D. Fulong et al., Petrochem. Ind. Technol., 25, 270 (1996).
  13. Z. Dongming, X. Songlin, W. Baohe et al., Ind. Catal., 4, 35 (1997).
  14. H. Junzuo and Z. Shisen, Chinese Polym. Bull., 4, 62 (2010).
  15. M.J. Climent, A. Corma and S. Iborra, RSC Adv., 2, 16 (2012).
  16. D. Kumar, D.N. Kommi, R. Chebolu, S.K. Garg, R. Kumar and A.K. Chakraborti, RSC Adv., 3, 91 (2012); doi:10.1039/c2ra21994h.
  17. F. Xinliang, G. Chuanjin and Z. Chengxue, Chinese J. Org. Chem., 23, 1348 (2003).
  18. T. Matsuura, K. Ohnaka, M. Takagi, M. Ohashi, K. Mibu and A. Yuchi, Anal. Chem., 80, 9666 (2008); doi:10.1021/ac801468f.
  19. I.H. Rhee and D.A. Dzombak, Langmuir, 15, 6875 (1999); doi:10.1021/la970031g.
  20. B. Saha and M. Streat, Ind. Eng. Chem. Res., 44, 8671 (2005); doi:10.1021/ie048848+.
  21. G. Gelbard, Ind. Eng. Chem. Res., 44, 8468 (2005); doi:10.1021/ie0580405.
  22. T. Zhang, L. Yang, Z. Zhu and J. Wu, Mol. Catal., 18, 315 (2002); doi:10.1016/S1381-1177(02)00112-1.
  23. W. Min, C. Wenyi, M. Jun and W. Haiyan, J. Petrochem. Univ., 17, 24 (2004).
  24. S.D. Alexandratos, Ind. Eng. Chem. Res., 48, 388 (2009); doi:10.1021/ie801242v.
  25. J. Tiihonen, M. Laatikainen, I. Markkanen and E. Paatero, Ind. Eng. Chem. Res., 38, 4832 (1999); doi:10.1021/ie990402j.
  26. L. Fuan, Z. Junxiu and H. Huamin, J. Catal., 12, 394 (1991).
  27. P. Botella, A. Corma, J.M. López Nieto, S. Valencia, M.E. Lucas and M. Sergio, Appl. Catal., 203, 251 (2000); doi:10.1016/S0926-860X(00)00482-8.
  28. L. Shixiong, Petroleum Refing Engineering, Petroleum Industry Press, Beijing, China (2009).
  29. A. Kanazawa, S. Shibutani, N. Yoshinari, T. Konno, S. Kanaoka and S. Aoshima, Macromolecules, 45, 7749 (2012); doi:10.1021/ma301505j.
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