Selective Adsorption Behaviour of Mesoporous Silica SBA-15-N-Acetylcysteine Imprinted Polymer Based on Surface Molecular Imprinting Technique

Xiaolan Zhu; Qingsheng Zhu; Jun Yang; Yun Gao

doi:10.14233/ajchem.2014.16442

Issue

Vol. 26 No. 19 (2014): Vol 26 Issue 19

Issue Published : September 16, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Selective Adsorption Behaviour of Mesoporous Silica SBA-15-N-Acetylcysteine Imprinted Polymer Based on Surface Molecular Imprinting Technique

https://doi.org/10.14233/ajchem.2014.16442

Xiaolan Zhu

Research Center of Tobacco and Health, University of Science and Technology of China, Hefei 230052, P.R. China

Qingsheng Zhu

Technique Center of Modern Education, Anhui Jianzhu University, Hefei 230022, P.R. China

Jun Yang

Research Center of Tobacco and Health, University of Science and Technology of China, Hefei 230052, P.R. China

Yun Gao

Research Center of Tobacco and Health, University of Science and Technology of China, Hefei 230052, P.R. China

Corresponding Author(s) : Xiaolan Zhu

zxl8906@ustc.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 19 (2014): Vol 26 Issue 19
Article Published : September 18, 2014

Abstract

A new N-acetylcysteine ion-imprinted polymer (NAC-MIP), which can be used for selective adsorption of N-acetylcysteine from aqueous solutions, was successfully prepared based on the supported material of ordered mesoporous silica SBA-15 with the help of surface molecular imprinting technology. The prepared polymer was characterized by Fourier transmission infrared sepectrometry, X-ray diffraction, scanning electron microscopy and ¹³C NMR spectroscopy. The results showed that the synthesized polymer possessed highly ordered mesoporous structure. The imprinted silica particle showed high selectivity and fast kinetic binding for the template due to its nanosized wall thickness and high surface area.

Keywords

SBA-15 Ordered mesoporous silica Surface molecular imprinting technology N-acetylcysteine

Zhu, X., Zhu, Q., Yang, J., & Gao, Y. (2014). Selective Adsorption Behaviour of Mesoporous Silica SBA-15-N-Acetylcysteine Imprinted Polymer Based on Surface Molecular Imprinting Technique. Asian Journal of Chemistry, 26(19), 6461–6464. https://doi.org/10.14233/ajchem.2014.16442

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G. Eisenbrand, M. Otteneder and W. Tang, Toxicol., 190, 249 (2003); doi:10.1016/S0300-483X(03)00204-X.

K. Karthikeyan, G.T. Arularasu, R. Ramadhas and K.C. Pillai, J. Pharm. Biomed. Anal., 54, 850 (2011); doi:10.1016/j.jpba.2010.10.015.

G. Wulff, Chem. Rev., 102, 1 (2002); doi:10.1021/cr980039a.

D. Zhang, Y. Lv, R. Chen and C.C. Shi, Asian J. Chem., 25, 3922 (2013); doi:10.14233/ajchem.2013.13845.

C.H. Lu, W.H. Zhou, B. Han, H.H. Yang, X. Chen and X.R. Wang, Anal. Chem., 79, 5457 (2007); doi:10.1021/ac070282m.

D.M. Gao, Z.P. Zhang, M.H. Wu, C.G. Xie, G.J. Guan and D.P. Wang, J. Am. Chem. Soc., 129, 7859 (2007); doi:10.1021/ja070975k.

D. Tian, G.P. Yong, H.W. Tong and S.M. Liu, Chin. J. Chem. Phys., 23, 479 (2010); doi:10.1088/1674-0068/23/04/479-483.

W.G. Borghard, D.C. Calabro, F.P. DiSanzo, M.M. Disko, J.W. Diehl, J.C. Fried, M.A. Markowitz, M. Zeinali, B.J. Melde and A.E. Riley, Langmuir, 25, 12661 (2009); doi:10.1021/la901334z.

C.X. Song, X.L. Zhang, C.Y. Jia, P. Zhou, X. Quan and C. Duan, Talanta, 81, 643 (2010); doi:10.1016/j.talanta.2009.12.047.

Y. Wang, Y. Yang, L. Xu and J. Zhang, Electrochim. Acta, 56, 2105 (2011); doi:10.1016/j.electacta.2010.11.077.

Y. Liu, Z.C. Liu, J. Gao, J.D. Dai, J. Han, Y. Wang, J.M. Xie and Y.S. Yan, J. Hazard. Mater., 186, 197 (2011); doi:10.1016/j.jhazmat.2010.10.105.

D.Y. Zhao, J.L. Feng, Q.S. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science, 279, 548 (1998); doi:10.1126/science.279.5350.548.

S. Zheng, L. Gao and J. Guo, J. Solid State Chem., 152, 447 (2000); doi:10.1006/jssc.2000.8708.

R. Ojani, E. Ahmadi, J.B. Raoof and F. Mohamadnia, J. Electroanal. Chem., 626, 23 (2009); doi:10.1016/j.jelechem.2008.10.018.

J.E. Lofgreen, I.L. Moudrakovski and G.A. Ozin, ACS Nano, 5, 2277 (2011); doi:10.1021/nn1035697.

B.M. Jung, M.S. Kim, W.J. Kim and J.Y. Chang, Chem. Commun., 46, 3699 (2010); doi:10.1039/c003173a.

Y. Du, J. Yang, W. Tang, X.L. Zhu, L. Zhang and Y. Gao, Asian J. Chem., 24, 1175 (2012).

L. Chen, S. Xu and J. Li, Chem. Soc. Rev., 40, 2922 (2011); doi:10.1039/c0cs00084a.

Issue

Vol. 26 No. 19 (2014): Vol 26 Issue 19

Selective Adsorption Behaviour of Mesoporous Silica SBA-15-N-Acetylcysteine Imprinted Polymer Based on Surface Molecular Imprinting Technique

Corresponding Author(s) : Xiaolan Zhu

Abstract

Keywords

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