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Vol. 26 No. 19 (2014): Vol 26 Issue 19

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Thermal Degradation Kinetics and Stability Study of Chrysin by Thermal Analysis

https://doi.org/10.14233/ajchem.2014.16393
Bingli Jiang
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China
Faquan Lin
Department of Hematology, the First Affiliated Hospital of Guangxi Medical University, Nanning, Guangxi Province, P.R. China
Chengjin Huang
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China
Cheng Cai
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China
Jianrong Qian
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China
Mi Zhang
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China
Weigao Pan
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China; Guangxi Botanical Garden of Medicinal Plants, Nanning, Guangxi Province, P.R. China
Cuiwu Lin
School of Chemistry & Chemical Engineering, Guangxi University, Nanning, Guangxi Province, P.R. China

Corresponding Author(s) : Cuiwu Lin

cuiwulin@163.com

Asian Journal of Chemistry, Vol. 26 No. 19 (2014): Vol 26 Issue 19

Abstract

Chrysin is one of the natural flavonoids possessing many biological activities. Research in thermal decomposition of chrysin is of great interest in developing its derivants. thermal analysis study was carried out by thermogravimetric analyser unit, microscopic melting point apparatus and differential scanning calorimetry instrument. The results showed chrysin began melting at 558 K and then evaporate. The evaporation process was analyzed by the Ozaw-Flynn-Wall (OFW) equation, Kissinger-Akahira-Sunose (KAS) equation, Tang equation, Starink equation, iterative Ozaw-Flynn-Wall equation and iterative Kissinger-Akahira-Sunose equation. The evaporation process of chrysin was a single-step kinetic process. The average value of activation energies, pre-exponential A and thermodynamic functions (DS¹, DH¹ and DG¹) of the transition state were calculated. The most probable mechanism for the thermal decomposition stage also was found.

Keywords

Chrysin Thermal degradation kinetics Ozaw-Flynn-Wall equation Kissinger-Akahira-Sunose equation
Jiang, B., Lin, F., Huang, C., Cai, C., Qian, J., Zhang, M., … Lin, C. (2014). Thermal Degradation Kinetics and Stability Study of Chrysin by Thermal Analysis. Asian Journal of Chemistry, 26(19), 6404–6408. https://doi.org/10.14233/ajchem.2014.16393
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