Magnetic Properties of Manganese-Iron Multi-Metal Cyanide Compound Ni1.15Mn0.35[Fe(CN)6]&middot;6H2O

Yun He; Zhimin Ji; Qing Lin; Haifu Huang; Wenjie Kong

doi:10.14233/ajchem.2014.18136

Issue

Vol. 26 No. 17 (2014): Vol 26 Issue 17

Issue Published : August 27, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Magnetic Properties of Manganese-Iron Multi-Metal Cyanide Compound Ni1.15Mn0.35[Fe(CN)6]·6H2O

https://doi.org/10.14233/ajchem.2014.18136

Yun He

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China

Zhimin Ji

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China

Qing Lin

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China ; Department of Information Technology, Hainan Medical College, Haikou 571101, P.R. China

Haifu Huang

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China ; Department of Physics, Nanjing University, Nanjing 210093, P.R. China

Wenjie Kong

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China

Corresponding Author(s) : Qing Lin

hy@gxnu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 17 (2014): Vol 26 Issue 17
Article Published : August 12, 2014

Abstract

A multi-metal prussian blue compound Ni_1.15Mn_0.35[Fe(CN)₆]·6H₂O has been synthesized. The IR spectrum of the compound shows two bands at 2096.42 and 2162.13 cm^-1 indicating the existence of two types of cyanide groups.It undergoes a paramagnetic to ferromagnetic transition at 21 K. These results indicate that there exist a ferromagnetic exchange interaction in the complexes. According to Curie-Weiss law,paramagnetic Curie temperature (Q) is 13.81 K and the Curie-Weiss constant (C) is 2.21 cm³ K mol^-1. In addition, the c’(T) and c’’ (T) show clear peak around 18-20 K. The behaviour of c’ and c’’ is typical of a spin glass state go through a maximum with strong frequency dependence. The observed value of coercive field (H_c) and remanent magnetization (M_r) for the compound are 1.72 KOe and 0.682 μ_b, respectively.

Keywords

Prussian blue analogue Magnetic transition Infrared spectroscopy Ferromagnetic Spin-glass

He, Y., Ji, Z., Lin, Q., Huang, H., & Kong, W. (2014). Magnetic Properties of Manganese-Iron Multi-Metal Cyanide Compound Ni1.15Mn0.35[Fe(CN)6]·6H2O. Asian Journal of Chemistry, 26(17), 5473–5477. https://doi.org/10.14233/ajchem.2014.18136

Download Citation

References

S. Ohkoshi, T. Iyoda, A. Fujishima and K. Hashimoto, Phys. Rev. B, 56, 11642 (1997); doi:10.1103/PhysRevB.56.11642.
O. Sato, Acc. Chem. Res., 36, 692 (2003); doi:10.1021/ar020242z.
S. Ohkoshi, O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Inorg. Chem., 36, 268 (1997); doi:10.1021/ic960978q.
S. Ohkoshi, T. Hozumi and K. Hashimoto, Phys. Rev. B, 64, 132404 (2001); doi:10.1103/PhysRevB.64.132404.
S. Ohkoshi, Y. Abe, A. Fujishima and K. Hashimoto, Rev. Lett., 82, 1285 (1999); doi:10.1103/PhysRevLett.82.1285.
V. Gadet, T. Mallah, I. Castro, M. Verdaguer and P. Veillet, J. Am. Chem. Soc., 114, 9213 (1992); doi:10.1021/ja00049a078.
M. Verdaguer and G. Girolami, Magnetic Prussian Blue Analogs, Wiley-VCH Verlag GmbH and Co. (2004).
S. Juszczyk, C. Johansson, M. Hanson, A. Ratuszna and G. Malecki, J. Phys. Condens. Matter, 6, 5697 (1994); doi:10.1088/0953-8984/6/29/012.
S. Ferlay, T. Mallah, R. Ouahès, P. Veillet and M. Verdaguer, Nature, 378, 701 (1995); doi:10.1038/378701a0.
A. Kumar and S.M. Yusuf, Physica B, 362, 278 (2005); doi:10.1016/j.physb.2005.02.024.
D. Gatteschi, O. Kahn, J.S. Miller and F. Palacio, NATO ASI Series E: Applied Science, p. 198 (1991).
D. Zhang, Z. Zhao and X. Chen, Asian J. Chem., 25, 3509 (2013); doi:10.14233/ajchem.2013.13622.
O. Sato, Y. Einaga, A. Fujishima and K. Hashimoto, Inorg. Chem., 38, 4405 (1999); doi:10.1021/ic980741p.
M. Ohba and H. Okawa, Coord. Chem. Rev., 198, 313 (2000); doi:10.1016/S0010-8545(00)00233-2.
A. Kumar, S.M. Yusuf and L. Keller, Physica B, 385–386, 444 (2006); doi:10.1016/j.physb.2006.05.147.
J.S. Miller, A.J. Epstein and W.M. Reiff, Chem. Rev., 88, 201 (1988); doi:10.1021/cr00083a010.
S.M. Holmes and G.S. Girolami, J. Am. Chem. Soc., 121, 5593 (1999); doi:10.1021/ja990946c.
J.S. Miller and A.J. Epstein, Angew. Chem. Int. Ed. Engl., 33, 385 (1994); doi:10.1002/anie.199403851.
S. Ohkoshi and K. Hashimoto, Phys. Rev. B, 60, 12820 (1999); doi:10.1103/PhysRevB.60.12820.
D. Sherrington and S. Kirkpatrick, Phys. Rev. Lett., 35, 1792 (1975); doi:10.1103/PhysRevLett.35.1792.
A. Kumar, S.M. Yusuf and L. Keller, Phys. Rev. B, 71, 054414 (2005); doi:10.1103/PhysRevB.71.054414.
K. Binder and A.P. Young, Rev. Mod. Phys., 58, 801 (1986); doi:10.1103/RevModPhys.58.801.

References

S. Ohkoshi, T. Iyoda, A. Fujishima and K. Hashimoto, Phys. Rev. B, 56, 11642 (1997); doi:10.1103/PhysRevB.56.11642.

O. Sato, Acc. Chem. Res., 36, 692 (2003); doi:10.1021/ar020242z.

S. Ohkoshi, O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Inorg. Chem., 36, 268 (1997); doi:10.1021/ic960978q.

S. Ohkoshi, T. Hozumi and K. Hashimoto, Phys. Rev. B, 64, 132404 (2001); doi:10.1103/PhysRevB.64.132404.

S. Ohkoshi, Y. Abe, A. Fujishima and K. Hashimoto, Rev. Lett., 82, 1285 (1999); doi:10.1103/PhysRevLett.82.1285.

V. Gadet, T. Mallah, I. Castro, M. Verdaguer and P. Veillet, J. Am. Chem. Soc., 114, 9213 (1992); doi:10.1021/ja00049a078.

M. Verdaguer and G. Girolami, Magnetic Prussian Blue Analogs, Wiley-VCH Verlag GmbH and Co. (2004).

S. Juszczyk, C. Johansson, M. Hanson, A. Ratuszna and G. Malecki, J. Phys. Condens. Matter, 6, 5697 (1994); doi:10.1088/0953-8984/6/29/012.

S. Ferlay, T. Mallah, R. Ouahès, P. Veillet and M. Verdaguer, Nature, 378, 701 (1995); doi:10.1038/378701a0.

A. Kumar and S.M. Yusuf, Physica B, 362, 278 (2005); doi:10.1016/j.physb.2005.02.024.

D. Gatteschi, O. Kahn, J.S. Miller and F. Palacio, NATO ASI Series E: Applied Science, p. 198 (1991).

D. Zhang, Z. Zhao and X. Chen, Asian J. Chem., 25, 3509 (2013); doi:10.14233/ajchem.2013.13622.

O. Sato, Y. Einaga, A. Fujishima and K. Hashimoto, Inorg. Chem., 38, 4405 (1999); doi:10.1021/ic980741p.

M. Ohba and H. Okawa, Coord. Chem. Rev., 198, 313 (2000); doi:10.1016/S0010-8545(00)00233-2.

A. Kumar, S.M. Yusuf and L. Keller, Physica B, 385–386, 444 (2006); doi:10.1016/j.physb.2006.05.147.

J.S. Miller, A.J. Epstein and W.M. Reiff, Chem. Rev., 88, 201 (1988); doi:10.1021/cr00083a010.

S.M. Holmes and G.S. Girolami, J. Am. Chem. Soc., 121, 5593 (1999); doi:10.1021/ja990946c.

J.S. Miller and A.J. Epstein, Angew. Chem. Int. Ed. Engl., 33, 385 (1994); doi:10.1002/anie.199403851.

S. Ohkoshi and K. Hashimoto, Phys. Rev. B, 60, 12820 (1999); doi:10.1103/PhysRevB.60.12820.

D. Sherrington and S. Kirkpatrick, Phys. Rev. Lett., 35, 1792 (1975); doi:10.1103/PhysRevLett.35.1792.

A. Kumar, S.M. Yusuf and L. Keller, Phys. Rev. B, 71, 054414 (2005); doi:10.1103/PhysRevB.71.054414.

K. Binder and A.P. Young, Rev. Mod. Phys., 58, 801 (1986); doi:10.1103/RevModPhys.58.801.

Issue

Vol. 26 No. 17 (2014): Vol 26 Issue 17

Magnetic Properties of Manganese-Iron Multi-Metal Cyanide Compound Ni1.15Mn0.35[Fe(CN)6]·6H2O

Corresponding Author(s) : Qing Lin

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents