Spin-Glass Behaviour and Magnetic Properties of Multi-Metallic Prussian Blue Compound Co0.25Mn1.25[Fe(CN)6]&middot;5.9H2O

Qing Lin; Kangling Huang; Haifu Huang; Yun He; Jianmei Xu

doi:10.14233/ajchem.2014.18121

Issue

Vol. 26 No. 17 (2014): Vol 26 Issue 17

Issue Published : August 27, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Spin-Glass Behaviour and Magnetic Properties of Multi-Metallic Prussian Blue Compound Co0.25Mn1.25[Fe(CN)6]·5.9H2O

https://doi.org/10.14233/ajchem.2014.18121

Qing Lin

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China ; Department of Information Technology, Hainan Medical College, Haikou 571101, P.R. China

Kangling Huang

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China

Haifu Huang

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China ; Department of Physics, Nanjing University, Nanjing 210093, P.R. China

Yun He

College of Physics and Technology, Guangxi Normal University, Guilin 541004, P.R. China

Jianmei Xu

Department of Information Technology, Hainan Medical College, Haikou 571101, P.R. China

Corresponding Author(s) : Yun He

hy@gxnu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 17 (2014): Vol 26 Issue 17
Article Published : August 12, 2014

Abstract

Multi-metal prussian blue compound Co_0.25Mn_1.25[Fe(CN)₆]·5.9H₂O has been synthesized.The temperature-dependent magnetic susceptibilities indicate that there exist a ferrimagnetic interaction in the compound and magnetic transition at 9.5 K. The Curie constant of C = 6.59 cm³ K mol^-1 and Curie temperature of q = -11.28 K were observed in fitting according to Curie-Weiss law. The observed value of coercive field and remanent magnetization at 4 K for the compound are 230 Oe and 0.072 μ_b. The presence of spin-glass behaviours in the compound is ascribed mainly to domain mobility or domain growth under different cooling conditions.The behaviour of c' and c" is typical of a spin glass statego through a maximum with strong frequency dependence. The observed values for the isomer shift, the quadrupole splitting is 0.41(9) mm/s, I.S. is -0.15(4) mm/s, values which are characteristic of low-spin Fe(III) (S = 1/2) ions. The Mössbauer spectroscopy study revealed the presence of low spin Fe(III) (S = 1/2).

Keywords

Prussian blue analogue Magnetic Spin glass Magetic transition Mössbauer spectroscopy

Lin, Q., Huang, K., Huang, H., He, Y., & Xu, J. (2014). Spin-Glass Behaviour and Magnetic Properties of Multi-Metallic Prussian Blue Compound Co0.25Mn1.25[Fe(CN)6]·5.9H2O. Asian Journal of Chemistry, 26(17), 5407–5411. https://doi.org/10.14233/ajchem.2014.18121

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References

S. Ohkoshi, T. Iyoda, A. Fujishima and K. Hashimoto, Phys. Rev. B, 56, 11642 (1997); doi:10.1103/PhysRevB.56.11642.
O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 272, 704 (1996); doi:10.1126/science.272.5262.704.
S. Ohkoshi, O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Inorg. Chem., 36, 268 (1997); doi:10.1021/ic960978q.
O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 271, 49 (1996); doi:10.1126/science.271.5245.49.
D. Zhang, Z. Zhao and X. Chen, Asian J. Chem., 25, 3509 (2013); doi:10.14233/ajchem.2013.13622.
S. Ohkoshi, T. Hozumi and K. Hashimoto, Phys. Rev. B, 64, 132404 (2001); doi:10.1103/PhysRevB.64.132404.
A. Kumar and S.M. Yusuf, Physica B, 362, 278 (2005); doi:10.1016/j.physb.2005.02.024.
O. Sato, Y. Einaga, A. Fujishima and K. Hashimoto, Inorg. Chem., 38, 4405 (1999); doi:10.1021/ic980741p.
O. Kahn, Molecular Magnetism, VCH Publishers, New York (1993).
W.E. Buschmann and J.S. Miller, Inorg. Chem., 39, 2411 (2000); doi:10.1021/ic991308y.
S.M. Holmes and G.S. Girolami, J. Am. Chem. Soc., 121, 5593 (1999); doi:10.1021/ja990946c.
A. Kumar, S.M. Yusuf and L. Keller, Physica B, 385-386, 444 (2006); doi:10.1016/j.physb.2006.05.147.
J.S. Miller and A.J. Epstein, Angew. Chem. Int. Ed. Engl., 33, 385 (1994); doi:10.1002/anie.199403851.
M. Gabay and G. Toulouse, Phys. Rev. Lett., 47, 201 (1981); doi:10.1103/PhysRevLett.47.201.
M. Ohba and H. Okawa, Coord. Chem. Rev., 198, 313 (2000); doi:10.1016/S0010-8545(00)00233-2.
H.Z. Kou, S. Gao and X. Jin, Synth. Inorg. Chem., 40, 6295 (2001); doi:10.1021/ic0103042.
C.A. Chugh and D. Bharti, Asian J. Chem., 24, 5879 (2012).
D. Sherrington and S. Kirkpatrick, Phys. Rev. Lett., 35, 1792 (1975); doi:10.1103/PhysRevLett.35.1792.
K. Chandra, D. Raj and S.P. Puri, J. Chem. Phys., 46, 1466 (1967); doi:10.1063/1.1840875.
Q. Lin, Z. Ye, C. Lei, H. Huang, R. Wang and Y. He, Mater. Res. Innov., 17(s1), s255 (2013); doi:10.1179/1432891713Z.000000000226.
S. Iijima, Z. Honda, S. Koner and F. Mizutani, J. Magn. Magn. Mater., 223, 16 (2001); doi:10.1016/S0304-8853(00)00594-1.

References

S. Ohkoshi, T. Iyoda, A. Fujishima and K. Hashimoto, Phys. Rev. B, 56, 11642 (1997); doi:10.1103/PhysRevB.56.11642.

O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 272, 704 (1996); doi:10.1126/science.272.5262.704.

S. Ohkoshi, O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Inorg. Chem., 36, 268 (1997); doi:10.1021/ic960978q.

O. Sato, T. Iyoda, A. Fujishima and K. Hashimoto, Science, 271, 49 (1996); doi:10.1126/science.271.5245.49.

D. Zhang, Z. Zhao and X. Chen, Asian J. Chem., 25, 3509 (2013); doi:10.14233/ajchem.2013.13622.

S. Ohkoshi, T. Hozumi and K. Hashimoto, Phys. Rev. B, 64, 132404 (2001); doi:10.1103/PhysRevB.64.132404.

A. Kumar and S.M. Yusuf, Physica B, 362, 278 (2005); doi:10.1016/j.physb.2005.02.024.

O. Sato, Y. Einaga, A. Fujishima and K. Hashimoto, Inorg. Chem., 38, 4405 (1999); doi:10.1021/ic980741p.

O. Kahn, Molecular Magnetism, VCH Publishers, New York (1993).

W.E. Buschmann and J.S. Miller, Inorg. Chem., 39, 2411 (2000); doi:10.1021/ic991308y.

S.M. Holmes and G.S. Girolami, J. Am. Chem. Soc., 121, 5593 (1999); doi:10.1021/ja990946c.

A. Kumar, S.M. Yusuf and L. Keller, Physica B, 385-386, 444 (2006); doi:10.1016/j.physb.2006.05.147.

J.S. Miller and A.J. Epstein, Angew. Chem. Int. Ed. Engl., 33, 385 (1994); doi:10.1002/anie.199403851.

M. Gabay and G. Toulouse, Phys. Rev. Lett., 47, 201 (1981); doi:10.1103/PhysRevLett.47.201.

M. Ohba and H. Okawa, Coord. Chem. Rev., 198, 313 (2000); doi:10.1016/S0010-8545(00)00233-2.

H.Z. Kou, S. Gao and X. Jin, Synth. Inorg. Chem., 40, 6295 (2001); doi:10.1021/ic0103042.

C.A. Chugh and D. Bharti, Asian J. Chem., 24, 5879 (2012).

D. Sherrington and S. Kirkpatrick, Phys. Rev. Lett., 35, 1792 (1975); doi:10.1103/PhysRevLett.35.1792.

K. Chandra, D. Raj and S.P. Puri, J. Chem. Phys., 46, 1466 (1967); doi:10.1063/1.1840875.

Q. Lin, Z. Ye, C. Lei, H. Huang, R. Wang and Y. He, Mater. Res. Innov., 17(s1), s255 (2013); doi:10.1179/1432891713Z.000000000226.

S. Iijima, Z. Honda, S. Koner and F. Mizutani, J. Magn. Magn. Mater., 223, 16 (2001); doi:10.1016/S0304-8853(00)00594-1.