Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation and Properties of Chitosan/Nanocrystalline Cellulose Composite Films for Food Packaging
Corresponding Author(s) : Shujun Li
Asian Journal of Chemistry,
Vol. 26 No. 17 (2014): Vol 26 Issue 17
Abstract
Nanocrystalline cellulose was prepared from microcrystalline cellulose using the ultrasonication. Nanocrystalline cellulose reinforced chitosan films were prepared by solution casting. The incorporation of nanocrystalline cellulose significantly enhanced the mechanical properties.The dry and wet tensile strength of nanocomposite films were improved by 22.4 and 542 %, respectively, for the nanocomposite containing 30 wt % of nanocrystalline cellulose. The swelling behaviour was studied by analyzing the water uptake of the nanocomposite films. SEM of the nanocomposite films was found that 30 wt % of nanocrystalline cellulose was dispersed homogenously into chitosan matrix. Nanocrystalline cellulose played an important role in improving the mechanical and barrier properties of chitosan film.
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- M.A.S. Azizi Samir, F. Alloin, J.-Y. Sanchez and A. Dufresne, Polymer, 45, 4149 (2004); doi:10.1016/j.polymer.2004.03.094.
- N. Ljungberg, J.-Y. Cavaillé and L. Heux, Polymer, 47, 6285 (2006); doi:10.1016/j.polymer.2006.07.013.
- N.L. Garcia de Rodriguez, W. Thielemans and A. Dufresne, Cellulose, 13, 261 (2006); doi:10.1007/s10570-005-9039-7.
- X.D. Cao, H. Dong and C.M. Li, Biomacromolecules, 8, 899 (2007); doi:10.1021/bm0610368.
- A.N. Nakagaito and H. Yano, Appl. Phys., A Mater. Sci. Process., 78, 547 (2004); doi:10.1007/s00339-003-2453-5.
- H.M. Azeredo, L.H. Mattoso, R.J.A. Avena-Bustillos, G.C. Filho, M.L. Munford, D. Wood and T.H. McHugh, J. Food Sci., 75, N1 (2010); doi:10.1111/j.1750-3841.2009.01386.x.
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- Y. Habibi, L.A. Lucia and O.J. Rojas, Chem. Rev., 110, 3479 (2010); doi:10.1021/cr900339w.
- M.M. de Souza Lima and R. Borsali, Rapid Commun., 25, 771 (2004); doi:10.1002/marc.200300268.
- A.N. Nakagaito and H. Yano, Appl. Phys., A Mater. Sci. Process., 78, 547 (2004); doi:10.1007/s00339-003-2453-5.
- D.M. Bruce, R.N. Hobson, J.W. Farrent and D.G. Hepworth, Compos., Part A Appl. Sci. Manuf., 36, 1486 (2005); doi:10.1016/j.compositesa.2005.03.008.
- B. Wang and M. Sain, Polym. Int., 56, 538 (2007); doi:10.1002/pi.2167.
- W.S. Chen, H.P. Yu, Y.X. Liu, P. Chen, M.X. Zhang and Y.F. Hai, Carbohydr. Polym., 83, 1804 (2011); doi:10.1016/j.carbpol.2010.10.040.
- C.K.S. Pillai, W. Paul and C.P. Sharma, Prog. Polym. Sci., 34, 641 (2009); doi:10.1016/j.progpolymsci.2009.04.001.
- G. Crini and P.-M. Badot, Prog. Polym. Sci., 33, 399 (2008); doi:10.1016/j.progpolymsci.2007.11.001.
- B. Krajewska, Enzyme Microb. Technol., 35, 126 (2004); doi:10.1016/j.enzmictec.2003.12.013.
- M.N.V. Ravi Kumar, React. Funct. Polym., 46, 1 (2000); doi:10.1016/S1381-5148(00)00038-9.
- S. Senel and S.J. McClure, Adv. Drug Deliv. Rev., 56, 1467 (2004); doi:10.1016/j.addr.2004.02.007.
- F. Shahidi, J.K.V. Arachchi and Y.-J. Jeon, Trends Food Sci. Technol., 10, 37 (1999); doi:10.1016/S0924-2244(99)00017-5.
- W. Li, J. Yue and S. Liu, Ultrason. Sonochem., 19, 479 (2012); doi:10.1016/j.ultsonch.2011.11.007.
- J.M. Lagaro’n and A. Fendler, Film Sheeting, 25, 47 (2009); doi:10.1177/8756087909335712.
- Y.S. Lu, L.H. Weng and X.D. Cao, Carbohydr. Polym., 63, 198 (2006); doi:10.1016/j.carbpol.2005.08.027.
- A. Khan, R.A. Khan, S. Salmieri, C. Le Tien, B. Riedl, J. Bouchard, G. Chauve, V. Tan, M.R. Kamal and M. Lacroix, Carbohydr. Polym., 90, 1601 (2012); doi:10.1016/j.carbpol.2012.07.037.
- S. Kanagaraj, F.R. Varanda, T.V. Zhil’tsova, M.S.A. Oliveira and J.A.O. Simões, Compos. Sci. Technol., 67, 3071 (2007); doi:10.1016/j.compscitech.2007.04.024.
References
M.A.S. Azizi Samir, F. Alloin, J.-Y. Sanchez and A. Dufresne, Polymer, 45, 4149 (2004); doi:10.1016/j.polymer.2004.03.094.
N. Ljungberg, J.-Y. Cavaillé and L. Heux, Polymer, 47, 6285 (2006); doi:10.1016/j.polymer.2006.07.013.
N.L. Garcia de Rodriguez, W. Thielemans and A. Dufresne, Cellulose, 13, 261 (2006); doi:10.1007/s10570-005-9039-7.
X.D. Cao, H. Dong and C.M. Li, Biomacromolecules, 8, 899 (2007); doi:10.1021/bm0610368.
A.N. Nakagaito and H. Yano, Appl. Phys., A Mater. Sci. Process., 78, 547 (2004); doi:10.1007/s00339-003-2453-5.
H.M. Azeredo, L.H. Mattoso, R.J.A. Avena-Bustillos, G.C. Filho, M.L. Munford, D. Wood and T.H. McHugh, J. Food Sci., 75, N1 (2010); doi:10.1111/j.1750-3841.2009.01386.x.
X. Cao, Y. Chen, P.R. Chang, A.D. Muir and G. Falk, Polymer Lett., 2, 502 (2008); doi:10.3144/expresspolymlett.2008.60.
Y. Habibi, L.A. Lucia and O.J. Rojas, Chem. Rev., 110, 3479 (2010); doi:10.1021/cr900339w.
M.M. de Souza Lima and R. Borsali, Rapid Commun., 25, 771 (2004); doi:10.1002/marc.200300268.
A.N. Nakagaito and H. Yano, Appl. Phys., A Mater. Sci. Process., 78, 547 (2004); doi:10.1007/s00339-003-2453-5.
D.M. Bruce, R.N. Hobson, J.W. Farrent and D.G. Hepworth, Compos., Part A Appl. Sci. Manuf., 36, 1486 (2005); doi:10.1016/j.compositesa.2005.03.008.
B. Wang and M. Sain, Polym. Int., 56, 538 (2007); doi:10.1002/pi.2167.
W.S. Chen, H.P. Yu, Y.X. Liu, P. Chen, M.X. Zhang and Y.F. Hai, Carbohydr. Polym., 83, 1804 (2011); doi:10.1016/j.carbpol.2010.10.040.
C.K.S. Pillai, W. Paul and C.P. Sharma, Prog. Polym. Sci., 34, 641 (2009); doi:10.1016/j.progpolymsci.2009.04.001.
G. Crini and P.-M. Badot, Prog. Polym. Sci., 33, 399 (2008); doi:10.1016/j.progpolymsci.2007.11.001.
B. Krajewska, Enzyme Microb. Technol., 35, 126 (2004); doi:10.1016/j.enzmictec.2003.12.013.
M.N.V. Ravi Kumar, React. Funct. Polym., 46, 1 (2000); doi:10.1016/S1381-5148(00)00038-9.
S. Senel and S.J. McClure, Adv. Drug Deliv. Rev., 56, 1467 (2004); doi:10.1016/j.addr.2004.02.007.
F. Shahidi, J.K.V. Arachchi and Y.-J. Jeon, Trends Food Sci. Technol., 10, 37 (1999); doi:10.1016/S0924-2244(99)00017-5.
W. Li, J. Yue and S. Liu, Ultrason. Sonochem., 19, 479 (2012); doi:10.1016/j.ultsonch.2011.11.007.
J.M. Lagaro’n and A. Fendler, Film Sheeting, 25, 47 (2009); doi:10.1177/8756087909335712.
Y.S. Lu, L.H. Weng and X.D. Cao, Carbohydr. Polym., 63, 198 (2006); doi:10.1016/j.carbpol.2005.08.027.
A. Khan, R.A. Khan, S. Salmieri, C. Le Tien, B. Riedl, J. Bouchard, G. Chauve, V. Tan, M.R. Kamal and M. Lacroix, Carbohydr. Polym., 90, 1601 (2012); doi:10.1016/j.carbpol.2012.07.037.
S. Kanagaraj, F.R. Varanda, T.V. Zhil’tsova, M.S.A. Oliveira and J.A.O. Simões, Compos. Sci. Technol., 67, 3071 (2007); doi:10.1016/j.compscitech.2007.04.024.