Synthesis of Biogasoline from Used Palm Cooking Oil Through Catalytic Hydrocracking by Using Cr-Activated Natural Zeolite as Catalyst

Jujarama; Karna Wijaya; Mohammad Shidiq; Mohammad Fahrurrozi; Suheryanto

doi:10.14233/ajchem.2014.16299

Issue

Vol. 26 No. 16 (2014): Vol 26 Issue 16

Issue Published : July 28, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis of Biogasoline from Used Palm Cooking Oil Through Catalytic Hydrocracking by Using Cr-Activated Natural Zeolite as Catalyst

https://doi.org/10.14233/ajchem.2014.16299

Jujarama

Magister of Engineering System, Faculty of Engineering, Gadjah Mada University, Yogyakarta, Indonesia

Karna Wijaya

Chemistry Department, Faculty of Mathematics and Natural Sciences, Gadjah Mada University, Yogyakarta, Indonesia

Mohammad Shidiq

Chemical Engineering Department, Faculty of Engineering, Gadjah Mada University, Yogyakarta, Indonesia

Mohammad Fahrurrozi

Chemical Engineering Department, Faculty of Engineering, Gadjah Mada University, Yogyakarta, Indonesia

Suheryanto

Chemistry Department, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Indralaya, South Sumatera, Indonesia

Corresponding Author(s) : Karna Wijaya

karna_ugm@yahoo.com, karnawijaya@ugm.ac.id

Asian Journal of Chemistry, Vol. 26 No. 16 (2014): Vol 26 Issue 16
Article Published : August 4, 2014

Abstract

This study was concerning on production of biogasoline from used palm cooking oil through Cr-activated natural zeolite catalyzed hydrocracking. Natural zeolite was activated using 6M hydrochloric acid. The precursor Cr(NO₃)₃·9H₂O was impregnated on activated natural zeolite. Catalysts characterization including catalysts crystallinity using X-ray diffraction and catalysts porosity using the BET method. The used palm cooking oil was vaporized at 350 °C and then flowed into the batch reactor which temperature was set at 400, 450 and 500 °C. Hydrogen was feed into the batch reactor at a constant rate of 40 mL/min. The variation of reactor conditions was with no catalysts, with zeolite catalysts and with catalyst Cr-activated natural zeolite. The product was then condensed in a water cooled condensor. The condensed products was analyzed using GC, GC-MS, ASTM D 1298, ASTM D 130, ASTM D 323 and ASTM D 86/99a to determine the formed fraction. The results show that the acid activation and impregnation reaction at zeolite samples can improve it crystallinity, surface area and pore radius. Active natural zeolite sample has a specific surface area of 43.815 m²/g while Cr-activated natural zeolite has a specific surface area of 89.514 m²/g. The highest conversion was gained by using Cr-activated natural zeolite catalysts at 500 °C reactor temperature which produced 76.44 % liquid product and 23.25 % yield.

Keywords

Biogasoline Used palm cooking oil Catalysts Cr-activated natural zeolite Hydrocracking

Jujarama, ., Wijaya, K., Shidiq, M., Fahrurrozi, M., & Suheryanto, . (2014). Synthesis of Biogasoline from Used Palm Cooking Oil Through Catalytic Hydrocracking by Using Cr-Activated Natural Zeolite as Catalyst. Asian Journal of Chemistry, 26(16), 5033–5038. https://doi.org/10.14233/ajchem.2014.16299

Download Citation

References

B. Argeur and F.G. Landolt, J. Catal., 11, 145 (1972).
P. Cao, A.Y. Tremblay, M.A. Dube´ and K. Morse, Ind. Eng. Chem. Res., 46, 52 (2007); doi:10.1021/ie060555o.
B.C. Gates, I.R. Katzer and G.C.A. Schuit, Chemistry Catalytic Processes, McGraw Hill Book Co., New York (1979).
A. Wijanarko, D.A. Mawardi and M. Nasikin, Makara Technol., 10, 51 (2006).
K.V. Padmaja, N. Atheya and A.K. Bhatnagar, Biomass Bioenergy, 33, 1664 (2009); doi:10.1016/j.biombioe.2009.08.011.
S. Bhatia, A.R. Mohamed and N.A.A. Shah, Chem. Eng. J., 155, 347 (2009); doi:10.1016/j.cej.2009.07.020.
F.A.A. Twaiq, A.R. Mohamad and S. Bhatia, Fuel Process. Technol., 85, 1283 (2004); doi:10.1016/j.fuproc.2003.08.003.
B. Yoosuk, P. Udomsap, B. Puttasawat and P. Krasae, Bioresour. Technol., 101, 3784 (2010); doi:10.1016/j.biortech.2009.12.114.
H. Sun, J.X. Han, Y.Q. Ding, W. Li, J.Z. Duan, P. Chen, H. Lou and X.M. Zheng, Appl. Catal. A, 390, 26 (2010); doi:10.1016/j.apcata.2010.09.030.
J.X. Han, H. Sun, Y.Q. Ding, H. Lou and X.M. Zheng, Green Chem., 12, 463 (2010); doi:10.1039/b917690j.
S. Bezergianni and A. Kalogianni, Bioresour. Technol., 100, 3927 (2009); doi:10.1016/j.biortech.2009.03.039.
C.M.R. Prado and N.R. Antoniosi Filho, J. Anal. Appl. Pyrolysis, 86, 338 (2009); doi:10.1016/j.jaap.2009.08.005.

References

B. Argeur and F.G. Landolt, J. Catal., 11, 145 (1972).

P. Cao, A.Y. Tremblay, M.A. Dube´ and K. Morse, Ind. Eng. Chem. Res., 46, 52 (2007); doi:10.1021/ie060555o.

B.C. Gates, I.R. Katzer and G.C.A. Schuit, Chemistry Catalytic Processes, McGraw Hill Book Co., New York (1979).

A. Wijanarko, D.A. Mawardi and M. Nasikin, Makara Technol., 10, 51 (2006).

K.V. Padmaja, N. Atheya and A.K. Bhatnagar, Biomass Bioenergy, 33, 1664 (2009); doi:10.1016/j.biombioe.2009.08.011.

S. Bhatia, A.R. Mohamed and N.A.A. Shah, Chem. Eng. J., 155, 347 (2009); doi:10.1016/j.cej.2009.07.020.

F.A.A. Twaiq, A.R. Mohamad and S. Bhatia, Fuel Process. Technol., 85, 1283 (2004); doi:10.1016/j.fuproc.2003.08.003.

B. Yoosuk, P. Udomsap, B. Puttasawat and P. Krasae, Bioresour. Technol., 101, 3784 (2010); doi:10.1016/j.biortech.2009.12.114.

H. Sun, J.X. Han, Y.Q. Ding, W. Li, J.Z. Duan, P. Chen, H. Lou and X.M. Zheng, Appl. Catal. A, 390, 26 (2010); doi:10.1016/j.apcata.2010.09.030.

J.X. Han, H. Sun, Y.Q. Ding, H. Lou and X.M. Zheng, Green Chem., 12, 463 (2010); doi:10.1039/b917690j.

S. Bezergianni and A. Kalogianni, Bioresour. Technol., 100, 3927 (2009); doi:10.1016/j.biortech.2009.03.039.

C.M.R. Prado and N.R. Antoniosi Filho, J. Anal. Appl. Pyrolysis, 86, 338 (2009); doi:10.1016/j.jaap.2009.08.005.

Issue

Vol. 26 No. 16 (2014): Vol 26 Issue 16

Synthesis of Biogasoline from Used Palm Cooking Oil Through Catalytic Hydrocracking by Using Cr-Activated Natural Zeolite as Catalyst

Corresponding Author(s) : Karna Wijaya

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents