Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Emulsion Stability and Steady Shear Characteristics of Concentrated Oil-in-Water Emulsion Stabilized by Gelatinized Bambara Groundnut Flour
Corresponding Author(s) : O. Adeyi
Asian Journal of Chemistry,
Vol. 26 No. 16 (2014): Vol 26 Issue 16
Abstract
Effect of sunflower oil and bambara groundnut flour concentrations on the stability and steady shear flow behaviour of concentrated sunflower oil-in-water (o/w) emulsion stabilized by gelatinized bambara groundnut flour dispersions was studied. Emulsion stability was studied using Turbiscan MA 2000 by observing changes in the average D-backscattering flux (%) at 20 °C. The steady shear flow behaviours were also modeled by two rheological equations. Both bambara groundnut flour and sunflower oil concentration affected the emulsion stability and rheological behaviour. Increase in oil phase fraction and bambara groundnut flour concentration improved emulsion creaming and led to increase in the emulsion viscosity. Kinetics of destabilization showed that increase in sunflower oil and bambara groundnut flour concentration has profound effect on emulsion destabilization. For the steady shear flow models, both of the rheological models tested were found to predict the rheological behaviour of the emulsions. Herschel-Bulkley (H-B) predicted an increase in consistency index, yield stress and decrease in flow behaviour index with increase in the oil and bambara groundnut flour concentrations while Casson model revealed that all emulsions studied possessed yield stress and plastic viscosity which increased as sunflower oil and bambara groundnut flour concentration increased. However, high value of coefficient of determination (R2) coupled with low root mean square error and standard error made Casson model a better predictor.
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References
D.J. McClements, Food Emulsions, Principles, Practice and Techniques. LLC: CRC Press (1999).
V. Samavati, Z. Emama-Djomeh, M.A. Mohammadifar, M. Omid and A.L.I. Mehdinia, J. Texture Stud., 1, 14 (2011).
R. Pal, Chem. Eng. Sci., 5, 3299 (1995).
R. Chanamai and D.J. McClements, Colloids Surf. A, 172, 79 (2000); doi:10.1016/S0927-7757(00)00551-3.
D.R. Izidoro, A. Scheer and M. Sierakowski, Braz. J. Biol., 52, 1516 (2009).
N. Georgiadis, C. Ritzoulis, G. Sioura, P. Kornezou, C. Vasiliadou and C. Tsioptsias, Food Hydrocoll., 25, 991 (2011); doi:10.1016/j.foodhyd.2010.09.014.
B. Wang, D. Li, L. Wang and N. Ozkan, J. Food Eng., 96, 555 (2010); doi:10.1016/j.jfoodeng.2009.09.001.
K.O. Adebowale and O.S. Lawal, Nahrung/food, 46, 311 (2002); doi:10.1002/15213803(20020901)46:5<311::AID-FOOD311>3.0.CO;2-Z.
N.H. Poulter and J.C. Caygill, J. Sci. Food Agric., 31, 1158 (1980); doi:10.1002/jsfa.2740311106.
O.M. Bamishaiye, J.A. Adeghola and E.I. Bamishaiye, Adv. Agric. Biotechnol., 1, 60 (2011).
J. Okpuzor, H.A. Oghunugafor, U. Okafor and M.O. Sofidiya, EXCLI J., 9, 17 (2010).
P. Sirivongpaisal, Songlanakarin J. Sci. Technolol, 30, 51 (2008).
A.A. Yusuf, H. Ayedun and L.O. Sanni, Food Chem., 111, 277 (2008); doi:10.1016/j.foodchem.2007.12.014.
D.J. McClements and J. Weiss, Lipid Emulsions (2005).
G. Lorenzo, N. Zaritzky and A. Califano, Food Res. Int., 41, 487 (2008); doi:10.1016/j.foodres.2008.02.005.
S. Kondaraju, H. Farhat and J.S. Lee, Soft Matter, 8, 1374 (2012); doi:10.1039/c1sm06193c.
S. Caubet, Y. Le Guer, B. Grassl, K. El Omari and E. Normandin, AlChe J., 57, 27 (2011); doi:10.1002/aic.12253.
F.A. Perrechil and R.L. Cunha, J. Food Eng., 97, 441 (2010); doi:10.1016/j.jfoodeng.2009.10.041.
P. Bellalta, E. Troncoso, R.N. Zuniga and J.M. Aguilera, LWT-Food Sci. Technol., 46, 375 (2012); doi:10.1016/j.lwt.2011.12.017.
R.E. Walpole, R.H. Myers, S.L. Myers and K. Ye, Probability and Statistics for Engineers and Scientists, Prentice Hall, New Jersey, edn 7 (2002).
N.L. Chin, S.M. Chan, Y.A. Yusof, T.G. Chuah and R.A. Talib, J. Food Eng., 93, 134 (2009); doi:10.1016/j.jfoodeng.2009.01.005.
C.I. Nindo, J. Tang, J.R. Powers and P.S. Takhar, LWT-Food Sci. Technol., 40, 292 (2007); doi:10.1016/j.lwt.2005.10.003.
S. Keshani, C. Luqman and A.R. Russly, Int. Food Res. J., 19, 553 (2012).
S.D. Holdsworth, Trans. Inst. Chem. E, 71, 139 (1993).
Y. Gu, E. Decker and D.J. McClements, Langmuir, 21, 5752 (2005); doi:10.1021/la046888c.
N. Camino and A.M.R. Pilosof, Food Hydrocoll., 25, 1051 (2011); doi:10.1016/j.foodhyd.2010.09.026.
G.G. Palazolo, D.A. Sorgentini and J.R. Wagner, Food Hydrocoll., 19, 595 (2005); doi:10.1016/j.foodhyd.2004.10.022.
A.L. Marquez, G.G. Palazolo and J.R. Wagner, Grasas y Aceites, 56, 59 (2005); doi:10.3989/gya.2005.v56.i1.135.
M.S. Álvarez Cerimedo, C.H. Iriart, R.J. Candal and M.L. Herrera, Food Res. Int., 43, 1482 (2010); doi:10.1016/j.foodres.2010.04.008.
W. Prinyawiwatkul, L.R. Beuchat, K.H. McWatters and R.D. Phillips, J. Agric. Food Chem., 45, 480 (1997); doi:10.1021/jf9603691.
M.A. Rao, P.E. Okechukwu, J.C. Da Silva and J.C. Oliveira, Carbohydr. Polym., 33, 273 (1997); doi:10.1016/S0144-8617(97)00025-8.
C.G. Mothé, A.D. Azevedo and R. Antoniassi, Rheological Characterization of Emulsions from Soymilk, 3rd International Symposium on Food Rheology and Structure, pp. 531-532 (2011).
M. Alpaslan and M. Hayta, J. Food Eng., 54, 89 (2002); doi:10.1016/S0260-8774(01)00197-2.
P. Sherman, Rheological Properties of Emulsions, Encyclopedia of Emulsion Technology, vol. 1, p. 405 (1983).
A.R. Taherian, P. Fustier and H.S. Ramaswamy, J. Food Eng., 77, 687 (2006); doi:10.1016/j.jfoodeng.2005.06.073.
U. Klinkesorn, P. Sophanodora, P. Chinachoti and D.J. McClements, Food Res. Int., 37, 851 (2004); doi:10.1016/j.foodres.2004.05.001.
C. Sun and S. Gunasekaran, Food Hydrocoll., 23, 165 (2009); doi:10.1016/j.foodhyd.2007.12.006.
J.E. Moros, J.M. Franco and C. Gallegos, Int. J. Food Sci. Technol., 37, 297 (2002); doi:10.1046/j.1365-2621.2002.00570.x.
O.H. Campanella, N.M. Dorward and H. Singh, J. Food Eng., 25, 427 (1995); doi:10.1016/0260-8774(94)00000-Y.
M. Khalil and B. Mohamed Jan, J. Appl. Polym. Sci., 124, 595 (2012); doi:10.1002/app.35004.
J. Ahmed, Int. J. Food Sci. Technol., 39, 325 (2004); doi:10.1111/j.1365-2621.2004.00789.x.
M.A. Rao and H.J. Cooley, J. Food Process Eng., 6, 159 (1983); doi:10.1111/j.1745-4530.1983.tb00289.x.
J.F. Steffe, Rheological Methods in Food Process Engineering, Freeman Press, East Lansing, MI, USA, edn 2 (1996).
T.G. Chuah, H. Hairul Nisah, S.Y. Thomas Choong, N.L. Chin and A.H. Nazimah Sheikh, J. Food Eng., 80, 423 (2007); doi:10.1016/j.jfoodeng.2006.04.051.